Macromolecular Research

  • 제17권6호
  • /
  • Pages.417-423
  • /
  • 2009
  • /
  • 1598-5032(pISSN)
  • /
  • 2092-7673(eISSN)
한국고분자학회 (The Polymer Society of Korea)
권호 표지

Effects of PP-g-MAH on the Mechanical, Morphological and Rheological Properties of Polypropylene and Poly(Acrylonitrile-Butadiene-Styrene) Blends

  • Lee, Hyung-Gon (Department of Chemical and Biological Engineering, Korea University) ;
  • Sung, Yu-Taek (Department of Chemical and Biological Engineering, Korea University) ;
  • Lee, Yun-Kyun (Department of Chemical and Biological Engineering, Korea University) ;
  • Kim, Woo-Nyon (Department of Chemical and Biological Engineering, Korea University) ;
  • Yoon, Ho-Gyu (Department of Materials Science and Engineering, Korea University) ;
  • Lee, Heon-Sang (Department of Chemical Engineering, Dong-A University)
  • Published : 2009.06.25
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

Abstract

The effects of maleic anhydride-grafted polypropylene (PP-g-MAH) addition on polypropylene (PP) and poly(acrylonitrile-butadiene-styrene) (ABS) blends were studied. Blends of PP/ABS (70/30, wt%) with PP-g-MAH were prepared by a twin-screw extruder. From the results of mechanical testing, the impact, tensile and flexural strengths of the blends were maximized at a PP-g-MAH content 3 phr. The increased mechanical strength of the blends with the PP-g-MAH addition was attributed to the compatibilizing effect of the PP and ABS blends. In the morphological studies, the droplet size of ABS was minimized (6.6 ${\mu}m$) at a PP-g-MAH content of 3 phr. From the rheological examination, the complex viscosity was maximized at a PP-g-MAH content of 3 phr. These mechanical, morphological and rheological results indicated that the compatibility of the PP/ABS (70/30) blends is increased with PP-g-MAH addition to an optimum blend at a PP-g-MAH content of 3 phr.

Keywords

References

  1. D. R. Paul and C. B. Bucknall, Polymer Blends, John Wiley & Sons, New York, 1999, Vol. 1&2
  2. Y. T. Sung, Y. S. Kim, Y. K. Lee, W. N. Kim, H. S. Lee, J. Y. Sung, and H. G. Yoon, Polym. Eng. Sci., 47, 1671 (2007) https://doi.org/10.1002/pen.20868
  3. J.-K. Yun, H.-J. Yoo, and H.-D. Kim, Macromol. Res., 15, 22 (2007) https://doi.org/10.1007/BF03218748
  4. J. Seo, W. Jang, and H. Han, Macromol. Res., 15, 10 (2007) https://doi.org/10.1007/BF03218746
  5. T. Das, A. K. Banthia, B. Adhikari, H. Jeong, C.-S. Ha, and S. Alam, Macromol. Res., 14, 261 (2006) https://doi.org/10.1007/BF03219081
  6. K.-J. Hwang, J.-W. Park, I. Kim, and C.-S. Ha, Macromol. Res., 14, 179 (2006) https://doi.org/10.1007/BF03218506
  7. S. Lee, Y. Lee, and J. W. Lee, Macromol. Res., 15, 44 (2007) https://doi.org/10.1007/BF03218751
  8. H. S. Park, J. H. Lee, J. D. Park, S. J. Seo, Y. K. Lee, Y. S. Oh, and H. C. Jung, Macromol. Res., 14, 430 (2006) https://doi.org/10.1007/BF03219106
  9. J. H. Hong, K. H. Song, H. G. Lee, M. S. Han, Y. H. Kim, and W. N. Kim, Macromol. Res., 15, 520 (2007) https://doi.org/10.1007/BF03218825
  10. J. Y. Lee and J. Y. Han, Macromol. Res., 12, 94 (2004) https://doi.org/10.1007/BF03219000
  11. J. K. Lee, J. E. Im, and K. H. Lee, Macromol. Res., 12, 172 (2004) https://doi.org/10.1007/BF03218385
  12. S. Park, C. Yim, B. H. Lee, and S. Choe, Macromol. Res., 13, 243 (2005) https://doi.org/10.1007/BF03219059
  13. U. Sundararaj and C. W. Macosko, Macromolecules, 28, 2647 (1995) https://doi.org/10.1021/ma00112a009
  14. Y. T. Sung, M. S. Han, J. C. Hyun, W. N. Kim, and H. S. Lee, Polymer, 44, 1681 (2003) https://doi.org/10.1016/S0032-3861(02)00920-5
  15. S. W. Kim, J. H. Park, D. J. Kim, H. S. Lim, and K. S. Seo, Polymer(Korea), 29, 557 (2006)
  16. H. M. Jeong, M. Y. Choi, and Y. T. Ahn, Macromol. Res., 14, 312 (2006)
  17. M. Choi, B. Lim, and J. Jang, Macromol. Res., 16, 200 (2008)
  18. J. O. Song, M. Y. Jeon, and C. K. Kim, Macromol. Res., 15 640 (2007) https://doi.org/10.1007/BF03218944
  19. B. Y. Shin, G. S. Jo, K. S. Kang, T. J. Lee, B. S. Kim, S. I. Lee, and J. S. Song, Macromol. Res., 15, 291 (2007) https://doi.org/10.1007/BF03218790
  20. H. T. Chiu and Y. K. Hsiao, Polym. Eng. Sci., 44, 2340 (2004) https://doi.org/10.1002/pen.20262
  21. S. Jose, B. Francis, S. Thomas, and J. Karger-Kocsis, Polymer, 47, 3874 (2006) https://doi.org/10.1016/j.polymer.2006.03.046
  22. A. Tedesco, R. V. Barbosa, S. M. B. Nachtigall, and R. S. Mauler, Polym. Test., 21, 11 (2002) https://doi.org/10.1016/S0142-9418(01)00038-1
  23. H. Liu, T. Xie, L. Hou, Y. Ou, and G. Yang, J. Appl. Polym. Sci., 99, 3300 (2006) https://doi.org/10.1002/app.23006
  24. L. T. Yan and J. Sheng, Polymer, 47, 2894 (2006) https://doi.org/10.1016/j.polymer.2006.02.048
  25. C. C. Bohn, Jr., S. C. Manning, and R. B. Moore, J. Appl. Polym. Sci., 79, 2398 (2001) https://doi.org/10.1002/1097-4628(20010328)79:13<2398::AID-APP1047>3.0.CO;2-3
  26. S. Balakrisnan and N. R. Neelakantan, Polym. Int., 45, 347 (1998) https://doi.org/10.1002/(SICI)1097-0126(199804)45:4<347::AID-PI940>3.0.CO;2-R
  27. S. Balakrisnan N. R. Neelakantan, D. N. Saheb, and J. P. Jog, Polymer, 39, 5765 (1998) https://doi.org/10.1016/S0032-3861(98)00088-3
  28. X. Zhang, Y. Chen. Y. Zhang, Z. Peng, Y. Zhang, and W. Zhou, J. Appl. Polym. Sci., 81, 831 (2001) https://doi.org/10.1002/app.1502
  29. F. Elmaghor, L. Zhang, R. Fan, and H. Li, Polymer, 45, 6719 (2004) https://doi.org/10.1016/j.polymer.2004.07.022
  30. K. H. Song, J. H. Hong, Y. T. Sung, Y. H. Kim, M. S. Han, H. G. Yoon, and W. N. Kim, Polymer(Korea), 31, 283 (2007)
  31. S. George, R. Joseph, S. Thomas, and K. T. Varughese, Polymer, 36, 4405 (1995) https://doi.org/10.1016/0032-3861(95)96846-Z
  32. S. George, N. R. Neelakantan, K. T. Varughese, and S. Thomas, J. Polym. Sci. Part B: Polym. Phys., 35, 2309 (1997) https://doi.org/10.1002/(SICI)1099-0488(199710)35:14<2309::AID-POLB11>3.0.CO;2-G
  33. S. George, K. T. Varughese, and S. Thomas, Polymer, 41, 5485 (2000) https://doi.org/10.1016/S0032-3861(99)00719-3
  34. C. Nakason, S. Saiwari, and A. Kaesaman, Polym. Test., 25, 413 (2006) https://doi.org/10.1016/j.polymertesting.2005.11.006
  35. Y. T. Sung, M. S. Han, J. C. Hyun, W. N. Kim, and H. S. Lee, Polymer, 44, 1681 (2003) https://doi.org/10.1016/S0032-3861(02)00920-5
  36. D. Herrara, J.-C. Zamora, A. Bello, M. Grimau, E. Laredo, A. J. Muller, and T. P. Lodge, Macromolecules, 38, 5109 (2005) https://doi.org/10.1021/ma050481c
  37. J. H. Park, H. M. Lee, I.-J. Chin, H. J. Choi, H. K. Kim, and W. G. Kang, J. Phys. Chem. Solids, 6, 1375 (2008)
  38. C. Markin and H. L. Williams, J. Appl. Polym. Sci., 25, 2451 (1980) https://doi.org/10.1002/app.1980.070251101
  39. A. K. Gupta, A. K. Jain, B. K. Ratnam, and S. N Maiti, J. Appl. Polym. Sci., 39, 515 (1990) https://doi.org/10.1002/app.1990.070390303
  40. A. C. Patel, R. B. Brahmbhatt, and S. Devi, J. Appl. Polym. Sci., 88, 72 (2003) https://doi.org/10.1002/app.11554
  41. C. K. Kum, Y. T. Sung, Y. S. Kim, H. G. Lee, W. N. Kim, H. S. Lee, and H. G. Yoon, Macromol. Res., 15, 308 (2007) https://doi.org/10.1007/BF03218792