보류시스템, 고분자 전해질 분자량과 약품투입순서에 따른 보류, 탈수, 지합, 파괴인성의 변화

Retention, Drainage, Formation, and Fracture Toughness Depending on Retention System, Molecular Weights of Polyelectrolytes and Dosage Sequences

  • 채희재 (충북대학교 농업생명환경대학 목재.종이과학과) ;
  • 김문성 (충북대학교 농업생명환경대학 목재.종이과학과) ;
  • 박창순 (충북대학교 농업생명환경대학 목재.종이과학과) ;
  • 박종문 (충북대학교 농업생명환경대학 목재.종이과학과)
  • Chae, Hee-Jae (Chungbuk National University, College of Agriculture, Life & Environment Sciences, Dept. of Wood and Paper Science) ;
  • Kim, Mun-Sung (Chungbuk National University, College of Agriculture, Life & Environment Sciences, Dept. of Wood and Paper Science) ;
  • Park, Chang-Soon (Chungbuk National University, College of Agriculture, Life & Environment Sciences, Dept. of Wood and Paper Science) ;
  • Park, Jong-Moon (Chungbuk National University, College of Agriculture, Life & Environment Sciences, Dept. of Wood and Paper Science)
  • 발행 : 2009.06.30

초록

In order to produce high quality paper at the lowest cost in high speed, typically various polyelectrolytes as retention aids were used. Retention systems such as single polymer system, dual polymer system, and microparticle system were used. The objective of this study was to analyze the changes of retention, drainage, formation and fracture toughness depending on types of retention system, molecular weight of C-PAM and dosage sequences of agents. When single polymer system was applied, retention was increased with poor formation and drainage. When common microparticle system(C-PAM/bentonite) was used, high molecular weight PAM gave high retention and fast drainage, but poor formation. When the microparticle system with reverse dosage sequence(bentonite/C-PAM) was used, low molecular weight PAM gave high retention, fast drainage and good formation. When various retention agents were applied, fracture toughness was increased than that of blank. When using high molecular weight PAM and consequently causing excessive flocculation, fracture toughness was decreased.

키워드

참고문헌

  1. Didato, D. T., The use of single polyacrylamide retention system, 1991, Papermakers Conference Proceedings, TAPPI PRESS, Atlanta, pp. 445-448
  2. Moore, E. E., Drainage and retention mechanism of papermaking systems treated with cationic polymers, Tappi J. 58(1):99-101(1975)
  3. Moore, E. E., Charge relationships of dual polymer retention aids, Tappi J. 59(6):120-122(1976)
  4. McCourt, A. M., Food P. A and Cauley. T. A., A practical view of a micropaticle system in supercalendered paper, Tappi J. 76(10):165-168(1993)
  5. Liu, J. T., The role of cationic polyacrylamide as a dewatering aid in reed pulp, Tappi J. 69(2):86-89 (1986)
  6. Andersson, K. Nordic., Pulp and paper Research J. No.4, pp. 243-259(1986)
  7. Lindstrom, T., 1989, In Fundamentals of Papermaking, Mechanical Engineering Publications LDT., London, pp. 311
  8. Duffy B. P., 1993, A micropaticle retention approach to papermaking, Papermakers Conference Proceedings, TAPPI PRESS, Atlanta, pp. 171-175
  9. Moberg, K., 1993, A visual perspective on micropaticles, Papermakers Conference Proceedings, TAPPI PRESS, Atlanta, pp. 115-127
  10. Krogerus, B., 1994, Impact of retention polymers on flocculation, retention, drainage and sheet formation, Papermakers Conference Proceedings, TAPPI PRESS, Atlanta, pp. 445-452
  11. Bernier E. Dorion., 1996, Retention Aid System, TAPPI PRESS, pp. 174-176
  12. Hedborg F., Nordic Pulp and Paper Research J., No.4, pp. 254-259(1996)
  13. Wagberg, L., Bjorklund, M., Asell, L. and Swerin, A., On the mechanism of flocculation by microparticle retention aids system, Tappi J. 79(6):157-164(1996)
  14. Andersson, K. and Lindgren E., Important properties of colloidal silica in microparticulate systems, Nordic Pulp Paper Research J. 12(1), pp. 15-22(1997)
  15. Swerin, A., Sjodin, U. and Odberg, L., Flocculation of cellulosic fiber suspensions by model micropaticle retention aids systems, Nordic Pulp and Paper Journal No.1, pp. 22-29(1997)
  16. 이학래 외, 1996, 제지과학, 광일문화사, pp. 199-232
  17. 조현정 외, 1995, 펄프.제지공학, 선진문화사, pp. 254-265
  18. Leo Neimo, 1999, Papermaking Science and Technology, Book 4
  19. 편집실, 1995, 마이크로파티클 시스템을 이용한 보류 및 탈수 향상기술, 제지기술 제2호, pp. 26-34
  20. 윤혜정, 신동소, 고해와 압착처리가 종이의 파괴인성에 미치는 영향, 펄프.종이기술 (J. of KTAPPI) 32(4):1-9(2000)
  21. 이진호, 박종문, 고해와 압착에 의한 파괴 인성과 파괴신장률의 변화, 펄프․종이기술 (J. of KTAPPI) 36(4):9-15(2004)
  22. 이지영, 이학래, 윤혜정, 백수의 수질이 양이온성 PAM의 흡착에 미치는 영향, 펄프.종이기술 (J. of KTAPPI) 37(1):1-9(2005)