대한환경공학회지 (Journal of Korean Society of Environmental Engineers)

  • 제31권3호
  • /
  • Pages.208-216
  • /
  • 2009
  • /
  • 1225-5025(pISSN)
  • /
  • 2383-7810(eISSN)
대한환경공학회 (Korean Society of Environmental Engineers)
권호 표지

토지 이용형태별 잔류성유기오염물질의 오염특성

Characteristics of Contamination for Persistent Organic Pollutants in Soil by Land Use

  • 이민진 (국립환경과학원 토양지하수연구과) ;
  • 김경수 (청주대학교 환경조경토목공학부) ;
  • 윤정기 (국립환경과학원 토양지하수연구과) ;
  • 김태승 (국립환경과학원 토양지하수연구과) ;
  • 김종국 (전북대학교 화학물질안전관리연구센터)
  • Lee, Min-Jin (Soil and Groudwater Division, National Institute of Environmental Research) ;
  • Kim, Kyoung-Soo (Division of Environmental, Landscape Architecture & Civil Engineering, Cheongju University) ;
  • Yoon, Jeong-Ki (Soil and Groudwater Division, National Institute of Environmental Research) ;
  • Kim, Tae-Seung (Soil and Groudwater Division, National Institute of Environmental Research) ;
  • Kim, Jong-Guk (Center for Chemical Safety Management, Chonbuk National University)
  • 투고 : 2009.02.03
  • 심사 : 2009.03.27
  • 발행 : 2009.03.31
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

본 연구에서는 토양 중 POPs 오염수준을 토지이용형태별로 구분 조사하여 오염특성을 규명하고 효율적인 토양 중 POPs 오염물질 관리방안 마련에 필요한 자료를 제공하였다. 농약류 중 Heptachlor, Aldrin, Endrin, Mirex, Toxaphene이 모든 지역에서 검출되지 않았고 Dieldrin은 N.D.-12.08 ${\mu}g$/kg, Chlordane은 N.D.-16.08 ${\mu}g$/kg, ${\Sigma}$DDT는 N.D.-38.19 ${\mu}g$/kg, HCB는 N.D.-1.32 ${\mu}g$/kg의 범위를 나타냈다. PCBs는 N.D.-172.12 ${\mu}g$/kg의 범위로 절연유오염지역이 높게 나타났으며, PCDD/Fs는 N.D.-6.68 pg I-TEQ/g으로 공단지역이 비교적 높게 나타났다.

This study was performed to investigate levels of POPs in soil by land use and identify congener profiles of PCBs, PCDD/Fs in soil in Korea. Heptachlor, Aldrin, Endrin, Mirex, Toxaphene were not found in all areas. The concentrations of Diedrin, Chlordane, ${\Sigma}$DDT, HCB in soil samples were in ranged from N.D. to 12.08 ${\mu}g$/kg, from N.D. to 16.08 ${\mu}g$/kg, from N.D. to 38.19 ${\mu}g$/kg and from N.D. to 1.32 ${\mu}g$/kg. In case of PCBs, concentration were in ranged from N.D. to 172.12 ${\mu}g$/kg, and PCBs contaminated area was higher than other areas. The concentrations of PCDD/Fs were in ranged from 0 to 6.68 pg I-TEQ/g. In addition, the ${\Sigma}$PCDFs concentration in the industry area soil was higher than ${\Sigma}$PCDDs.

키워드

참고문헌

  1. 최종우, “환경 중 잔류성유기오염물질의 측정 및 분석 -POPs 공정시험방법-,” 한국환경농학회 추계워크샵 자료집, 15-27(2008)
  2. Secretariat of the Stockholm Convention, “Stockholm Convention on Persistent Organic Pollutants,” (2001)
  3. 박정규, 이희선, “잔류성유기오염물질의 관리현황과 대응 방향-부산물을 중심으로,” 한국환경정책평가연구원, (2000)
  4. 환경부, “토양환경보전법령집,” (2007)
  5. 국립환경과학원, “잔류성유기오염물질공정시험방법,” (2007)
  6. 국립환경과학원, “내분비계장애물질 측정분석방법,” (2002)
  7. Van den Berg, M., Birnbaum, L., Bosveld, A. T., Brunstrlim, B., Cook, P., Feeley, M., Giesy, J. P., Hanberg, A., Hasegawa, R., Kennedy, S. W., Kubiak, T., Larsen, J. C., Van Leeuwen, FXR., Liem, AKD., Nolt, C., Peterson, R. E., Poellinger, L., Safe, S., Schrenk, D., Tillitt, D., Tysklind, M., Younes, M., Waern, F., Zacharewski, T., 'Toxic equivalency factors (TEFs) for PCBs, PCDDs, PCDFs, for humans and wildlife. Environ,' Health Perspect., 106, 775-792(1998) https://doi.org/10.2307/3434121
  8. 식품의약품안전청, “식품의 농약 잔류허용기준,” (2005)
  9. 환경부, “스특홀름협약 국가이행계획서 작성을 위한 전략마련 연구,” (2007)
  10. 농업과학기술원, “농약의 사용현황과 안전성,” (1996)
  11. 환경부, 국립환경과학원, “내분비계장애물질조사연구 결과,” 1999-2005
  12. Athanasios, K. and Constantini, S., “Persistent organic pollutants in the sewage treatment plant of Thessaloniki, northern Greece: occurrence and removal,” Water Res., 38, 2685-2698(2004) https://doi.org/10.1016/j.watres.2004.03.027
  13. Elliott, J. E., Martin, P. A., Arnold, T. W., Sinclair, P. H., “Organochlorines and reproductive success of birds in orchard and non-orchard areas of central British Columbia, Canada, 1990-91,” Archives of Environ. Contam. Toxicol., 26, 435-443(1994) https://doi.org/10.1007/BF00214144
  14. Strandberg, B., Bandh, C., Van Bavel, B., Bergqvist, P. A., Bromand, D., Naf, C., Pettersen, H., Rappe, C., “Concentrations, biomagnification and spatial variation of organochlorine compounds in a pelagic food web in the northern part of the Baltic Sea,” The Science of the Total Environ., 217, 143-154(1998) https://doi.org/10.1016/S0048-9697(98)00173-9
  15. Yang, R. Q., Jiang, G. B., Zhou, Q. F., Yuan, C. G., Shi, J. B., “Occurrence and distribution of organochlorine pesticides (HCH and DDT) in sediments collected from East China Sea,” Environ. Inter., 31, 799-804(2005) https://doi.org/10.1016/j.envint.2005.05.027
  16. Bommanna, G. L. and Kannan, K., “Global organochlorine contamination trends: an overview,” Ambio., 23(3), 187-191(1994)
  17. Schmid, P., Erika, G., Markus, Z., Bucheli Thomas, D., Andre, D., “Correlation of PCDD/F and PCB concentrations in soil samples from the Swiss soil monitoring network (NABO) to specific parameters of the observation sites,” Chemosphere, 58, 227-234(2005) https://doi.org/10.1016/j.chemosphere.2004.08.045
  18. Liu, G. Y., Chen, Z. S, Shi, Y. H., Wang, G. Y., Li., W., Li, G. Q., “The levels and compositions of PCBs in Beijing soil,” Acta. Sci. Circumst., 26, 2013-2017(2006)
  19. 환경부, “토지 이용 용도별 토양오염기준 및 복원기준 마련을 위한 연구,” (2003)
  20. 김경수, 송병주, 박석운, 김종국, “공단지역 대기 중 PCBs의 오염농도 및 발생원 추정,” 대한환경공학회지, 27(4), 385-389(2005)
  21. Kim, K. S., Hirai, Y., Kato, M., Urano, K., Masunaga, S., “Detailed PCB congener patterns in incinerator flue gas and commercial PCB formulations (Kanechlor),” Chemosphere, 55(4), 539-553(2004) https://doi.org/10.1016/j.chemosphere.2003.11.056
  22. Wilson, S. C., Duarte-davidson, R., Jones, K. C., “Screening the environmental fate of organic contaminants in sewage sludges applied to agricultural soils: 1. The potential for downward movement to groundwaters,” The Science of the Total Environ., 185, 59-70(1996) https://doi.org/10.1016/0048-9697(96)05042-5
  23. 오정은, “배출원 주위 대기/토양에서의 다이옥신 분포와 거동 연구,” 포항공과 대학교 박사학위논문(2001)
  24. Hassanin, A., Lee, R. G. M., Steinnes, E., Jones, K. C., “PCDD/Fs in Norwegian and UK soils: implications for sources and environmental cycling,” Environ. Sci. Technol., 39(13), 4784-4792(2005) https://doi.org/10.1021/es0505189
  25. Bacci, E., Cerejeira, M. J., Gaqqi, C., Chemello, G., Calamari, D., Viqhi, M., “Chlorinated dioxins : volatilization from soils and bioconcentration in leaves,” Bull. Environ. Contam. Toxicol., 48(3), 401-408(1992)