Journal of Integrative Natural Science (통합자연과학논문집)

The Basic Science Institute Chosun University (조선대학교 기초과학연구원)
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Synthesis and Characterization of Bis(silyl) Palladinum and -Platinum(II) Complexes

비스실릴팔라듐(II) 및 백금(II)착물의 합성 및 확인

  • Cho, Jun-Churl (Department of Chemistry, Gangneung-Wonju National University) ;
  • Kim, Yong-Joo (Department of Chemistry, Gangneung-Wonju National University)
  • 최준철 (강릉원주대학교 화학신소재학과) ;
  • 김용주 (강릉원주대학교 화학신소재학과)
  • Received : 2009.09.01
  • Accepted : 2009.09.21
  • Published : 2009.09.30
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Abstract

Bis(silyl)palladinum(II) and -platinum(II) complexes are key intermediates for the synthesis of organic silyllated compounds by the Pd or Pt-catalyzed reactions. Reactions of dialkylpalladinum and -platinum complexes with diphenylsilane gave the bis(silyl)palladinum and -platinum complexe in moderate to good yields. Isolated complexes were characterized by $^1H$, $^{13}C$ and $^{31}P$-NMR spectroscopy and elemental analyses. Some of the complexes were determined by X-ray crystallographic studies.

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