DOI QR코드

DOI QR Code

인광 발광 물질을 이용한 백색 유기 발광 다이오드에서의 혼합된 스페이서의 영향에 관한 연구

A Hybrid Spacer Effect on White Organic Light-Emitting Diodes with Phosphorescent Emitters

  • 서지훈 (홍익대학교 정보디스플레이공학과) ;
  • 박정선 (홍익대학교 정보디스플레이공학과) ;
  • 형건우 (홍익대학교 신소재공학과) ;
  • 서지현 (홍익대학교 정보디스플레이공학과) ;
  • 이금희 (성균관대학교 화학과) ;
  • 윤승수 (성균관대학교 화학과) ;
  • 김영관 (홍익대학교 정보디스플레이공학과)
  • 발행 : 2009.03.30

초록

본 논문에서는 청색 인광 발광 물질인 bis(3,5-Difluoro-2-(2-pyridyl)phenyl-(2-carboxypyridyl) iridium (III) (Flrpic)과 녹색 인광 발광 물질인 fac-tris(2-phenypyridine) irdium(III) ($Ir(ppy)_3$)와 적색 인광 발광 물질인 his(5-benzoyl-2-phenylpyridinato-C,N)iridium(III) (acetylacetonate) ($(Bzppy)_{2}Ir(acac)$)를 각각 적층하여 백색 유기 발광 다이오드를 제작하였고, 각각의 발광층 사이에 혼합된 스페이서인 4,4'-N,N'-dicarbazole-biphenyl (CBP):4,7-diphenyl-1,10-phenanthroline (BPhen)을 적층하여 그 때의 영향에 대하여 연구하였다. 최적화된 구조에서의 전력 효율은 $0.014\;mA/cm^2$에서의 19.7 lm/w를 나타내었으며, $0.127\;mA/cm^2$에서의 11.5%의 외부 양자 효율을 나타내었고, 8 V에서 Commission Internationale do I'Eclairage ($CIE_{x,y}$) coordinates (x=0.36, y=0.44)의 색좌표를 나타내었다.

키워드

참고문헌

  1. C.W. Tang and S.A VanSlyke, Organicelectroluminescent diodes, Appl, Phys,Lett. 51, 913 (1987) https://doi.org/10.1063/1.98799
  2. T. Aimono, Y. Kawamura, K. Goushi, H.Yamamoto, H. Sasabe, and C. Adachi,100% fluorescence efficiency of4,4-bis[(N-carbazole)styryl]biphenyl in asolid film and the very low amplifiedspontaneous eIDlSSlon threshold, Appl.Phys. Lett. 86, 071110 (2005) https://doi.org/10.1063/1.1867555
  3. H. K. Lee, j. H. Seo, j. H. Kim, j. R.Koo, K. H. Lee, S. S. Y oon, and Y. K.Kim, Investigation ofLight-Emitting DiodesBlue Organic(OLEDs) withVarious Hosts, J Korean Phys. Soc. 49,1052 (2006)
  4. V. A. Montes, G. Li, R. Pohl, j. Shinar,and P. Anzenbacher, Effective Colortuning in Organic Light-Emitting DiodesBased on Aluminum Tris(5-aryl-8-hydroxyquinoline) Complexes, Adv. Mater.16, 2001 (2004) https://doi.org/10.1002/adma.200401155
  5. J. H. Lee, j. I. Lee, K. L. Song, S. j. Lee,and H. Y. Chu, Influence of doping profileon the efficiency of blue phosphorescentorganic light-emitting diodes, Appl. Phys.Lett. 92, 133304 (2008) https://doi.org/10.1063/1.2904632
  6. J. H. Seo, j. H. Kim, j. H. Seo, G. W.Hyung, j. H. Park, K. H. Lee, S. S. Y oon,and Y. K. Kim, Highly efficient whiteorganic light-emitting diodes using twoemitting materials for three primary colors(red, green, and blue), Appl. Phys. Lett.90, 203507 (2007) https://doi.org/10.1063/1.2740191
  7. B. W. D'Andrade and S. R. Forrest,White Organic Light-Emitting Devices forSolid-State Lighting, Adv. Mater. 16,1585 (2004) https://doi.org/10.1002/adma.200400684
  8. R. F. Service, Science 273, 878 (1996) https://doi.org/10.1126/science.273.5277.878
  9. E. L. Williams, K. Haavisto, j. Li, and G.E. Jabbour, Excimer-Based WhitePhosphorescent Organic Light-EmittingDiodes with Nearly 100 % InternalQuantum Efficiency, Adv. Mater. 19, 197(2007) https://doi.org/10.1002/adma.200602174
  10. G. Schwartz, T. H. Ke, C. C. Wu, and K.Walzer, and K. Leo, Balanced ambipolarcharge carrier mobility in mixed layers forapplication in hybrid white organiclight-emitting diodes, Appl. Phys. Lett.93, 073304 (2008) https://doi.org/10.1063/1.2973151
  11. X. Qi, M. Slootsky, and S. Forrest,Stacked white organic light emittingdevices consisting of separate red, green,and blue elements, Appl. Phys. Lett. 93,193306 (2008) https://doi.org/10.1063/1.3021014
  12. S. j. Su, E. Gonrnori, H. Sasabe, and j.Kido, Highly Efficient Organic Blue-andWhite-Light-Emitting Devices Having aCarrier- and Exciton-Confining Structurefor Reduced Efficiency Roll-Off, Adv.Mater. 20, 4189 (2008)
  13. Y. Sun, N. C. Giebink, H. Kanno, B. Ma,M. E. Thompson and S. R. Forrest,Management of singlet and tripletexcitons for efficient white organiclight-emitting devices, Nature, 440, 908(2006) https://doi.org/10.1038/nature04645
  14. J. H. Seo, I. H. Park, G. Y. Kim, K. H.Lee, M. K. Kim, S. S. Y oon, and Y. K.Kim, Hybrid spacer for high-efficiencywhite organic light-emitting diodes, Appl.Phys. Lett. 92, 183303 (2008) https://doi.org/10.1063/1.2907190
  15. A detailed mechanism of Dexter energytransfer from blue and green to red EMLwill be reported elsewhere [J. H. Seo, G.W. Hyung, and Y. K. Kim (unpublished)]