공업화학 (Applied Chemistry for Engineering)
- 제20권2호
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- Pages.201-207
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- 2009
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- 1225-0112(pISSN)
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- 2288-4505(eISSN)
분산액에서의 Copper Chromite 합성 및 Methyl Dodecanoate의 수소화반응
Hydrogenation of Methyl Dodecanoate Using Copper Chromite
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강호철
(한국화학연구원 그린화학연구단 산업바이오화학연구센터) ;
- 이상훈 (한국화학연구원 그린화학연구단 산업바이오화학연구센터) ;
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박종목
(한국화학연구원 그린화학연구단 산업바이오화학연구센터) ;
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김동표
(충남대학교 공과대학 바이오응용화학과) ;
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이병민
(한국화학연구원 그린화학연구단 산업바이오화학연구센터)
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Kang, Ho-Cheol
(Green Chemical Technologies, Industrial Biotechnology Research Center, Korea Research Institute of Chemical Technology) ;
- Lee, Sang-Hoon (Green Chemical Technologies, Industrial Biotechnology Research Center, Korea Research Institute of Chemical Technology) ;
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Park, Jong-Mok
(Green Chemical Technologies, Industrial Biotechnology Research Center, Korea Research Institute of Chemical Technology) ;
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Kim, Dong-Pyo
(Department of Fine Chemical Engineering & Chemistry, Chungnam National University) ;
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Lee, Byung Min
(Green Chemical Technologies, Industrial Biotechnology Research Center, Korea Research Institute of Chemical Technology)
- 투고 : 2009.01.19
- 심사 : 2009.02.10
- 발행 : 2009.04.10
초록
Dodecanol 합성을 위한 methyl dodecanoate의 수소화반응을 위하여 copper chromite를 세라믹법, 공침법 및 개량된 공침법으로 합성하였다. 입자의 형상은 SEM 및 XRD로 확인하였으며 수소화 반응후 얻어진 생성물은 GC, GC/MSD 및 NMR로 분석하였다. 합성된 입자는 (1) 3.2에서
The hydrogenation reaction of methyl dodecanoate for the synthesis of 1-dodecanol has been carried out in the presence of a copper chromite catalyst. The catalysts were synthesized by ceramic method, co-precipitation, and improved co-precipitation method and the particles were characterized by SEM and XRD. Also, the products of the reaction were assigned by GC, GC/MSD and NMR. The particles synthesized by each method showed (1) a spherical shape with the size of 3.2 to