Applied Chemistry for Engineering (공업화학)
- Volume 20 Issue 2
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- Pages.201-207
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- 2009
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- 1225-0112(pISSN)
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- 2288-4505(eISSN)
Hydrogenation of Methyl Dodecanoate Using Copper Chromite
분산액에서의 Copper Chromite 합성 및 Methyl Dodecanoate의 수소화반응
- Kang, Ho-Cheol (Green Chemical Technologies, Industrial Biotechnology Research Center, Korea Research Institute of Chemical Technology) ;
- Lee, Sang-Hoon (Green Chemical Technologies, Industrial Biotechnology Research Center, Korea Research Institute of Chemical Technology) ;
- Park, Jong-Mok (Green Chemical Technologies, Industrial Biotechnology Research Center, Korea Research Institute of Chemical Technology) ;
- Kim, Dong-Pyo (Department of Fine Chemical Engineering & Chemistry, Chungnam National University) ;
- Lee, Byung Min (Green Chemical Technologies, Industrial Biotechnology Research Center, Korea Research Institute of Chemical Technology)
- 강호철 (한국화학연구원 그린화학연구단 산업바이오화학연구센터) ;
- 이상훈 (한국화학연구원 그린화학연구단 산업바이오화학연구센터) ;
- 박종목 (한국화학연구원 그린화학연구단 산업바이오화학연구센터) ;
- 김동표 (충남대학교 공과대학 바이오응용화학과) ;
- 이병민 (한국화학연구원 그린화학연구단 산업바이오화학연구센터)
- Received : 2009.01.19
- Accepted : 2009.02.10
- Published : 2009.04.10
Abstract
The hydrogenation reaction of methyl dodecanoate for the synthesis of 1-dodecanol has been carried out in the presence of a copper chromite catalyst. The catalysts were synthesized by ceramic method, co-precipitation, and improved co-precipitation method and the particles were characterized by SEM and XRD. Also, the products of the reaction were assigned by GC, GC/MSD and NMR. The particles synthesized by each method showed (1) a spherical shape with the size of 3.2 to
Dodecanol 합성을 위한 methyl dodecanoate의 수소화반응을 위하여 copper chromite를 세라믹법, 공침법 및 개량된 공침법으로 합성하였다. 입자의 형상은 SEM 및 XRD로 확인하였으며 수소화 반응후 얻어진 생성물은 GC, GC/MSD 및 NMR로 분석하였다. 합성된 입자는 (1) 3.2에서