Evaluation of Affecting Factors on the Ferrous Catalyzed Sodium Persulfate Oxidation for the Destruction of Organic Pollutant

과황산나트륨을 이용한 유기 오염물 산화와 영향인자 평가

  • Yun, Yeobog (Department of Civil Engineering, Kyunghee University) ;
  • Park, Haimi (Department of Civil Engineering, Kyunghee University) ;
  • Ko, Sunghwan (Ecophile CO., LTD.) ;
  • Ko, Seokoh (Department of Civil Engineering, Kyunghee University)
  • Received : 2008.06.29
  • Accepted : 2009.01.05
  • Published : 2009.01.30

Abstract

The objective of this study was to determine on optimum ratio of oxidant and catalyst and to evaluate affecting factors such as anions and cations on persulfate oxidation of organic pollutant. Fe(II) activated the persulfate anion to produce a sulfate free radicals and thus effectively used to degrade the target organic pollutant in aqueous system. The chloride ions reacted with sulfate radical produced the $Cl^{\cdot}$ atom and had positive effects on the oxidation of organic pollutant at the initial stage. However, it was observed that chloride ions had the scavenging effects on the rate of oxidation of organic pollutant. Cations and some heavy metals were partly able to activate the persulfate anion to generate a sulfate free radical. However, high levels of cations inhibited the oxidation of organic pollutant.

Keywords

Acknowledgement

Supported by : 환경부, 경희대학교

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