Korean Chemical Engineering Research

  • 제47권2호
  • /
  • Pages.185-189
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  • 2009
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  • 0304-128X(pISSN)
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  • 2233-9558(eISSN)
한국화학공학회 (The Korean Institute of Chemical Engineers)
권호 표지

교반셀에서 측정한 아민첨가 암모니아수 흡수제의 이산화탄소 흡수 반응 속도 측정

Absorption Rate of Carbon Dioxide into Blended Ammonia Solution with Amine Additives in a Stirred Cell Reactor

  • 박호석 (한국과학기술원 생명화학공학과) ;
  • 유정균 (한국과학기술원 생명화학공학과) ;
  • 홍원희 (한국과학기술원 생명화학공학과) ;
  • 김종남 (한국에너지기술연구원)
  • Park, HoSeok (Department of Chemical and Biomolecular Engineering, Kaist) ;
  • You, Jong Kyun (Department of Chemical and Biomolecular Engineering, Kaist) ;
  • Hong, Won Hi (Department of Chemical and Biomolecular Engineering, Kaist) ;
  • Kim, Jong Nam (Chemical Research Center, Korea Institute Energy Research)
  • 투고 : 2008.06.19
  • 심사 : 2009.02.18
  • 발행 : 2009.04.30
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초록

10 wt% 암모니아수 흡수제에서 이산화탄소 흡수속도를 교반셀 반응기를 이용하여 293~337 K 범위에서 측정하였다. 암모니아 흡수제와 이산화탄소의 반응속도를 아레니우스 식으로 나타내었으며 활성화에너지는 50.42 kJ/mol였다. 2-Amino-2-methyl-1-propanol(AMP), 2-amino-2-methyl-1,3-propandiol(AMPD), 2-amino-2-ethyl-1,3-propandiol(AEPD)의 입체장애아민 첨가제가 1 wt% 함유된 흡수제에서의 이산화탄소 흡수속도를 측정하였다. 아민 첨가제들은 흡수속도에 영향을 주었으며 1 wt%의 AMP를 첨가한 경우 반응속도 상수는 약 53% 증가하였다.

Absorption rate of carbon dioxide into aqueous ammonia absorbent(10 wt%) was measured in the temperature range from 293 K to 337 K using a stirred-cell reactor. The reaction rate constant was correlated with the Arrehnius equation and the activation energy was 50.42 kJ/mol. $CO_2$ absorption rate into modified ammonia absorbent was also investigated. For the modified ammonia absorbent, 1 wt% sterically hindered amines of 2-amino-2-methyl-1-propanol(AMP), 2-amino-2-methyl-1,3-propandiol(AMPD) and 2-amino-2-ethyl-1,3-propandiol(AEPD) were used as additives. The $CO_2$ absorption rate increased by adding 1 wt% of the amine additive, in the case of AMP additive, the absorption rate enhanced by about 53%.

키워드

과제정보

연구 과제 주관 기관 : 이산화탄소 저감 및 처리기술 개발사업단(CDRS, Carbon Dioxide Reduction and Sequestration R&D Center)

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