Changes of Distribution Coefficients of Cu, Cr, and As in Different Soil Matrix in a Laboratory Scale

  • Kang, Sung-Mo (Quality Control & Standardization Team, Korea Forest Research Institute) ;
  • Ra, Jong-Bum (Dept. of Interior material Engineering, College of Science and Engineering, Jinju National University) ;
  • Kim, Suk-Kuwon (Quality Control & Standardization Team, Korea Forest Research Institute)
  • Received : 2008.09.11
  • Accepted : 2008.12.19
  • Published : 2009.03.25

Abstract

Chromated copper arsenate (CCA), a long history of successful preservative, have raised environmental concerns. Adsorption characteristics of domestic soils for chromium, copper, and arsenic were assessed by measuring distribution coefficient ($K_d$) values of these metal components in a laboratory scale. The results revealed that $K_d$ values were higher in chromium, followed by arsenic and copper in soil matrix. Different soil matrixes resulted in varying mobilities of CCA components. The values of $K_d$ for all three metals increased with organic matter contents. The results suggest that the mobility of metal components may be very limited to the surface area adjacent to CCA-treated wood due to their fairly large distribution coefficient ($K_d$). However, the metal components would be persistent and accumulated in the soil, resulting in high chemical concentration in service area of treated wood.

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References

  1. Beder, S. 2003. Timber Leachates Prompt Preservative Review. Engineers Australia 75(6): 32-34
  2. Bloomfield, C. and G. Pruden. 1980. The behavior of Cr (III) in soil under aerobic and anaerobic conditions. Environmental Pollution Series. A. 103-114
  3. Chirenje, T., L. Q. Ma, C. Clark, and M. Reeves. 2003. Cu, Cr and As distribution in soils adjacent to pressure-treated decks, fences and poles. Environmental Pollution 124(2003): 407-417 https://doi.org/10.1016/S0269-7491(03)00046-0
  4. Griffin, R. A. and N. F. Shimp. 1978. Attenuation of pollutants in municipal landfill leachate by clay minerals. EPA-600/2-78-157
  5. Morrell, J. J. and J. Huffman. 2003. Copper, chromium, and arsenic levels in soils surrounding posts treated with chromated copper arsenate (CCA). Society of Wood Science and Technology. pp. 119-128
  6. Shin, S. 2005. Mobility of preservative components leached from CCA treated wood in soil. master’s thesis, Korea Univ., Seoul, Korea. p.126
  7. Solo-Gabriele, H. M., T. G. Townsend, and J. Schert. 2003. Environmental Impacts of CCAtreated wood: a summary from seven years of study focusing on the U.S. Florida environment. No. IRG/WP/03-50205. International Research Group on Wood Preservation. Stockholm, Sweden
  8. Stefanovic, S. and P. Cooper. 2003. Effects of soil physical and chemical characteristics on adsorption of leached CCA and ACQ preservative components. No. IRG/WP/03-50200. International Research Group on Wood Preservation. Stockholm,Sweden