A Study on the Characteristics of $TiO_2$ thin Film in Dye-sensitized Solar Cells using Electrospray Method

정전분무법을 이용한 염료감응형 태양전지의 $TiO_2$ 박막 특성에 관한 연구

  • Published : 2009.11.01

Abstract

Dye sensitized solar cells(DSCs) have been very economical and easy method to convert solar energy to electricity. DSC can reach low costs in future outdoor power applications. However, to commercialize the DSC, there are still many shortages to overcome such a low efficiency in a large size DSC. In this study, DSCs were fabricated by an electrospray coating method for the $TiO_2$ thin film. They were compared with DSCs prepared by conventional coating methods. We conducted an experiment to obtain the optimized parameters of voltage, flow rate, incident angle and distance in the electrospray method. After we fabricated $TiO_2$ film using that way, we investigated the characteristics of DSC through I-V Curve, SEM and EIS. This novel method shows stable performance with an energy conversion efficiency of 3.44 % under 1 sun illumination (AM 1, $P_{in}$ of $100\;mW/cm^2$).

Keywords

References

  1. B. O'Regan, M. Gratzel, 1991, 'Optical electrochemistry I: steady-state spectroscopy of conduction band electrons in a metal oxide semiconductor electrode', Chemical Physics Letters https://doi.org/10.1016/0009-2614(91)85104-5
  2. S.Ngamsinlapasathian, S.kulkhaemaruethai, 2004, 'Highly efficient dye-sensitized solar cell using nanocrystalline titania containing nanotube structure', Journal of Photochemistry and Photobiology A: Chemistry, Vol.164,pp 145-151 https://doi.org/10.1016/j.jphotochem.2003.11.016
  3. K. Okada, H. Matsui, T. Kawashima, T. Ezure,2004, '100 mm $\times$ 100 mm large-sized dye sensitized solar cells', Journal of Photochemistry and Photobiology A: Chemistry, Vol.164,pp 193-198 https://doi.org/10.1016/j.jphotochem.2004.01.028
  4. Zhaoyue Liu, Kai Pan, Min Liu, Qinglin Zhang, Jun Li, Yang Liu,2005, 'Influence of the binder on the electron transport in the dye-sensitized $TiO_2$ electrode', Thin Solid Films, Vol.484,pp 346-351 https://doi.org/10.1016/j.tsf.2005.02.003
  5. C.J. Barbe, F. Arendse, P. Comte, M. Jirousek, F. Lenzmann, V. Shklover, M. Gratzel, J. Am. Ceram. Soc. 80 (1997) 3157-3171 https://doi.org/10.1111/j.1151-2916.1997.tb03245.x
  6. 김상수, 'Characteristics of the Grooved-nozzle for High Flow Rate Electrospray', 대한기계학회 춘계학술 대회 논문집, 2005
  7. Shuzi Hayase, 'Dye-Sensitized Solar Cells Fabricated by Electrospray Coating Using $TiO_2$ Nanocrystal Dispersion Solution', Journal of The Electrochemical Society, 153 5 A826-A829 2006 https://doi.org/10.1149/1.2179368
  8. A. Jaworek, A.T. Sobczyk, 'Electrospraying route to nanotechnology: An overview', Journal of Electrostatics 66: Vol.66, pp 197–19, 2008 https://doi.org/10.1016/j.elstat.2007.10.001
  9. A. Jaworek, 'Micro- and nanoparticle production by electrospraying', Powder Technology, Vol.176, pp 18-35, 2007 https://doi.org/10.1016/j.powtec.2007.01.035
  10. Liyuan Han, Naoki Koide, Yasuo Chiba, and Takehito Mitate, 'Modeling of an equivalent circuit for dye-sensitized solar cells', Applied Physics Letters, Vol. 84, 2433, March 2004 https://doi.org/10.1063/1.1690495
  11. Motonari Adachi, Masaru Sakamoto, Jinting Jiu, Yukio Ogata, and Seiji Isoda, 'Determination of parameters of electron transport in dye-sensitized solar cells using electrochemical impedance spectroscopy', Journal of Physical Chemistry B, Vol. 110, Iss. 28, pp. 13872-13880, July 2006 https://doi.org/10.1021/jp061693u
  12. Anneke Hauch, Andreas Georg, 'Diffusion in the electrolyte and charge-transfer reaction at the platinum electrode in dye-sensitized solar cells', Electrochimica Acta, Vol. 46, Iss. 22, pp. 3457-3466, August 2001 https://doi.org/10.1016/S0013-4686(01)00540-0
  13. Chung-Yi Huana, Ying-Chan Hsu, Jian-Ging Chen, Vembu Suryanarayanan, Kun-Mu Lee, Kuo-Chuan Ho, 'The effects of hydrothermal temperature and thickness of $TiO_2$ film on the performance of a dye-sensitized solar cell', Solar Energy Materials & Solar Cells, Vol. 90, pp. 2391-2397, April 2006 https://doi.org/10.1016/j.solmat.2006.03.012