Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Anion Recognition by a Simple Colorimetric Benzthiazole-Based Receptor

  • Kang, Sung-Ok (Department of Applied Chemistry and Center for Functional Nano Fine Chemicals, Chonnam National University) ;
  • Nguyen, Quynh Pham Bao (Department of Applied Chemistry and Center for Functional Nano Fine Chemicals, Chonnam National University) ;
  • Kim, Taek-Hyeon (Department of Applied Chemistry and Center for Functional Nano Fine Chemicals, Chonnam National University)
  • Published : 2009.11.20
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Abstract

A simple colorimetric anion chemosensor based on 2-amino-6-nitrobenzothiazole was synthesized. The addition of tetrabutylammonium (TBA) salts of $F^-,\;{CH_3COO}^-,\;and\;{H_2PO_4}^-$ to the solution of receptor 3 caused dramatic and clearly observable color changes from light to dark yellow due to the deprotonation process which is totally different from previously reported receptors based on the same motif. According to the basicity of the anions, the sensitivity of receptor 3 towards various anions decreased in the following order: ${CH_3COO}^-\;>\;F^-\;>\;{H_2PO_4}^-$.

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