Bulletin of the Korean Chemical Society

  • 제30권7호
  • /
  • Pages.1603-1606
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  • 2009
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Synthesis, Structure, and Magnetic Properties of 1D Nickel Coordination Polymer Ni(en)(ox)·2H2O (en = ethylenediamine; ox = oxalate)

  • Chun, Ji-Eun (Department of Chemistry, Konkuk University) ;
  • Lee, Yu-Mi (Department of Chemistry, Konkuk University) ;
  • Pyo, Seung-Moon (Department of Chemistry, Konkuk University) ;
  • Im, Chan (Department of Chemistry, Konkuk University) ;
  • Kim, Seung-Joo (Department of Chemistry, Division of Energy Systems Research, Ajou University) ;
  • Yun, Ho-Seop (Department of Chemistry, Division of Energy Systems Research, Ajou University) ;
  • Do, Jung-Hwan (Department of Chemistry, Konkuk University)
  • 발행 : 2009.07.20
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초록

A new 1D oxalato bridged compound Ni(en)(ox)-2$H_2$O, (ox = oxalate; en = ethylenediamine) has been hydrothermally synthesized and characterized by single crystal X-ray diffraction, IR spectrum, TG analysis, and magnetic measurements. In the structure the Ni atoms are coordinated with four oxygen atoms in two oxalate ions and two nitrogen atoms in one ethylenediamine molecule. The oxalate anion acts as a bis-bidentate ligand bridging Ni atoms in cis-configuration. This completes the infinite zigzag neutral chain, [Ni(en)(ox)]. The interchain space is filled by water molecules that link the chains through a network of hydrogen bonds. Thermal variance of the magnetic susceptibility shows a broad maximum around 50 K characteristic of one-dimensional antiferromagnetic coupling. The theoretical fit of the data for T > 20 K led to the nearest neighbor spin interaction J = -43 K and g = 2.25. The rapid decrease in susceptibility below 20 K indicate this compound to be a likely Haldane gap candidate material with S = 1.

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참고문헌

  1. Yu, J.-H.; Xu, J.-Q.; Zhang, L.-J.; Lu, J.; Zhang, X.; Bie, H.-Y. J. Mol. Struct. 2005, 743, 243 https://doi.org/10.1016/j.molstruc.2005.02.034
  2. Jiang, Y.-C.; Wang, S.-L.; Lee, S.-F.; Lii, K.-H. Inorg. Chem. 2003, 42, 6154 https://doi.org/10.1021/ic030019d
  3. Fang, F.-Y.; Guo, X.-X.; Song, W.-D. Acta Crystallogr. 2007, E63, m1031
  4. Coronado, E.; Giménez, M. C.; Gómez-García, C. J.; Romero, F. M. Polyhedron 2003, 22, 3115 https://doi.org/10.1016/S0277-5387(03)00462-5
  5. Román, P.; Guzmán-Miralles, C.; Luque, A.; Beitia, J. I.; Cano, J.; Lloret, F.; Julve, M.; Alvarez, S. Inorg. Chem. 1996, 35, 3741 https://doi.org/10.1021/ic951081g
  6. Wang, L.-M.; Chu, D.-Q.; Pan, C.-L. Mendeleev Commun. 2002, 12, 235 https://doi.org/10.1070/MC2002v012n06ABEH001677
  7. Yu, J.-H.; Hou, Q.; Bi, M.-H.; Lü, Z.-L.; Zhang, X.; Qu, X.-J.; Lu, J.; Xu, J.-Q. J. Mol. Struct. 2006, 800, 69 https://doi.org/10.1016/j.molstruc.2006.03.079
  8. García-Terán, J. P.; Castillo, O.; Luque, A.; García-Couceiro, U.; Román, P.; Lloret, F. Inorg. Chem. 2004, 43, 5761 https://doi.org/10.1021/ic049569h
  9. Ghost, S. K.; Savitha, G.; Bharadwaj, P. K. Inorg. Chem. 2004, 43, 5495 https://doi.org/10.1021/ic049490c
  10. Castillo, O.; Luque, A.; Román, P.; Lloret, F.; Julve, M. Inorg. Chem. 2001, 40, 5526 https://doi.org/10.1021/ic0103401
  11. Oshio, H.; Nagashima, U. Inorg. Chem. 1992, 31, 3295 https://doi.org/10.1021/ic00041a025
  12. Xia, S. Q.; Hu, S. M.; Dai, J. C.; Wu, X. T.; Fu, Z. Y.; Zhang, J. J.; Du, W. X. Polyhedron 2004, 23, 1003 https://doi.org/10.1016/j.poly.2003.12.021
  13. Hernández-Molina, M.; Lorenzo-Luis, P. A.; Ruiz-Pérez, C. Cryst. Eng. Commun. 2001, 16, 1
  14. Lu, J. Y.; Schroeder, T. J.; Babb, A. M.; Olmstead, M. Polyhedron 2001, 20, 2445. https://doi.org/10.1016/S0020-1693(01)00401-7
  15. Lu, J. Y.; Babb, A. Inorg. Chim. Acta 2001, 318, 186 https://doi.org/10.1016/S0020-1693(01)00401-7
  16. Van Albada, G. A.; Mohamadou, A.; Mutikainen, I.; Turpeinen, U.; Reedijk, J. Acta Crystallogr. 2004, E60, m1160
  17. Ferjani, J.; Graia, M.; Jouini, T. Acta Crystallogr. 2005, C61, m237 https://doi.org/10.1016/j.inoche.2005.01.004
  18. Hong, C. S.; Yoon, J. H.; You, Y. S. Inorg. Chem. Commun. 2005, 8, 310 https://doi.org/10.1016/j.inoche.2005.01.004
  19. Sheldrick, G. M. SHELXS 97; Program for Crystal Structure Solution: University of Gottingen, Germany, 1997
  20. Brese, N. E.; O'Keeffe, M. Acta Crystallogr. 1991, B47, 192
  21. Meyer, A.; Gleizes, A.; Girerd, J.-J.; Verdaguer, M.; Kahn, O. Inorg. Chem. 1982, 21, 1729 https://doi.org/10.1021/ic00135a006
  22. Yamashita, M.; Ishii, T.; Matsuzaka, H. Coord. Chem. Rev. 2000, 198, 347 https://doi.org/10.1016/S0010-8545(99)00212-X
  23. Takeuchi, T.; Ono, M.; Hori, H.; Tosida, T.; Yamagishi, A.; Date, M. J. Phys. Soc. 1992, 61, 3255 https://doi.org/10.1143/JPSJ.61.3255
  24. Haldane, D. M. Phys. Lett. 1983, 93A, 464
  25. Haldane, D. M. Phys. Rev. Lett. 1983, 50, 1153 https://doi.org/10.1103/PhysRevLett.50.1153
  26. Renard, J. P.; Verdageuer, M.; Regnault, L. P.; Erkelens, W. A. C.; Rossat-Mignod, J.; Ribas, J.; Stirling, W. G.; Vettier, C. J. Appl. Phys. 1988, 63, 3538 https://doi.org/10.1063/1.340736
  27. Ma, S.; Broholm, C.; Reich, D. H.; Sternlieb, B. J.; Erwin, R. W. Phys. Rev. Lett. 1992, 69, 357
  28. Takeuchi, T.; Yosida, T.; Inoue, K.; Yamashita, M.; Kumada, T.; Kindo, K.; Merah, S.; Verdaguer, M.; Renard, J. P. J. Mag. Mater. 1995, 140, 1633 https://doi.org/10.1016/0304-8853(94)01094-3
  29. Kikuchi, H.; Ajiro, Y.; Mori, N.; Goto, T.; Aruga, H. Solid State Comm. 1990, 76, 999 https://doi.org/10.1016/0038-1098(90)90072-J
  30. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 5th ed.; John Wiley & Sons: New York, 1997

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