Environmentally Friendly Dyeing of PTT with Temporarily Solubilized Azo Diseperse Dyes

일시적 수용성 아조계 분산염료를 이용한 PTT 섬유의 환경친화형 염색

  • Jang, Hae-Kyoung (Fiber System Engineering Program, Division of Polymer System Engineering, Dankook University) ;
  • Kim, Hae-Rim (Fiber System Engineering Program, Division of Polymer System Engineering, Dankook University) ;
  • Lee, Jung-Jin (Fiber System Engineering Program, Division of Polymer System Engineering, Dankook University)
  • 장혜경 (단국대학교 고분자시스템공학부 파이버시스템) ;
  • 김혜림 (단국대학교 고분자시스템공학부 파이버시스템) ;
  • 이정진 (단국대학교 고분자시스템공학부 파이버시스템)
  • Published : 2008.08.30

Abstract

Temporarily solubilized azo disperse dyes containing ${\beta}$-sulfatoethylsulfonyl group were applied to PTT fabric and feasibility of dispersant-free dyeing was investigated. The color yields of the dyes on PTT fabric were found to be dependent on dye bath pH while not much on dyeing temperature. The optimum results were obtained at pH 5-6 and $110^{\circ}C-120^{\circ}C$. The dyes showed good build-up properties on PTT fabric. Washfastness were fair to moderate and lightfastness were somewhat poor. The COD levels of the dyeing effluent from the temporarily solubilized disperse dye were much smaller than those from commercial disperse dyes.

Keywords

References

  1. Y. Yang, H. Brown, and S. Li, 'Some Sorption Characteristics of Poly(trimethylene terephthalate) with Disperse Dyers', J Appl Polym Sci, 2002, 86, 223-229 https://doi.org/10.1002/app.10953
  2. Y. J. Hwang, M. G. McCord, and B. C. Kang, 'Helium/Oxygen Atmospheric Pressure Plasma Treatment on Poly (ethylene terephthalate) and Poly (trimethylene terephthalate) Knitted Fabrics', Fiber Polym, 2005, 6(2), 113-120 https://doi.org/10.1007/BF02875601
  3. S. Y. Lin, 'A New Lignosulfonate Dispersant for Dyes', Text Chem Color, 1981, 13(11), 261-265
  4. W. J. Lee and J. P. Kim, 'The Rate of Hydrolysis of Temporarily Solubilised Disperse Dyes', J Soc Dyers Colour, 1999, 115, 270-273
  5. W. J. Lee and J. P. Kim, 'Dispersant-free Dyeing of Polyester with Temporarily Solubilised Disperse Dyes', J Soc Dyers Colour, 1999, 115, 370-273
  6. J. J. Lee, N. K. Han, W. J. Lee, J. H. Choi, and J. P. Kim, 'Dispersant-free Dyeing of Polyester with Temporarily Solubilised Azo Disperse Dyes from 1-Substituted-2-hydroxypyrid-6-one Derivatives', Color Technol, 2002, 118, 154-158 https://doi.org/10.1111/j.1478-4408.2002.tb00093.x
  7. J. J. Lee, N. K. Han, W. J. Lee, J. H. Choi, and J. P. Kim, 'One-bath Dyeing of a Polyester/Cotton Blend with Reactive Disperse Dyes from 2-Hydroxypyrid-6-one Derivatives', Color Technol, 2003, 119, 134-139 https://doi.org/10.1111/j.1478-4408.2003.tb00163.x
  8. J. J. Lee, W. J. Lee, and J. P. Kim, 'Dispersant-free Dyeing of Polyester with Temporarily Solubilized Azo Disperse Dyes from Indole Derivatives', Fiber Polym, 2003, 4(2), 66-70 https://doi.org/10.1007/BF02875439
  9. J. J. Lee, W. J. Lee, J. H. Choi, and J. P. Kim, Synthesis and Application of Temporarily Solubilised Azo Disperse Dyes Containing ${\beta}$-sulphatoethylsulphonyl Group', Dyes Pigments, 2005, 65, 75-81 https://doi.org/10.1016/j.dyepig.2004.06.017
  10. Y. Yang, S. Li, H. Brown, and P. Casey, 'Dyeing Behavior of 100% Poly(trimethylene terephthalate) (PTT) Textiles', Text Chem Color Am D, 1999, 1(3), 50-54
  11. S. Yoon, T, Kim, Y. Lim, and K. Cho, 'The Interpretation of Dyeing Behavior of Poly(trimethylene terephthalate) Fiber with a Disperse Dye', J Koean Soc Dyers Finishers, 2001, 13(4), 23-29
  12. P. F. Gordon and P. Gregory, 'Organic Chemistry in Colour', Springer-Verlag, NY, 1987, pp.294-297