전기학회논문지 (The Transactions of The Korean Institute of Electrical Engineers)

  • 제57권9호
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  • Pages.1599-1605
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  • 2008
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  • 1975-8359(pISSN)
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  • 2287-4364(eISSN)
대한전기학회 (The Korean Institute of Electrical Engineers)
권호 표지

플라즈마 반응기의 수소발생에 미치는 $TiO_2$, Cu, Ni 촉매제 영향

The co-effect of $TiO_2$, Cu and Ni Powders for Enhancing the Hydrogen Generation Efficiency using Plasma Technology

  • 발행 : 2008.09.01
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초록

The research was conducted in order to improve the hydrogen generation efficiency of the electrical plasma technology from tap water by using $TiO_2$ photocatalyst, mixed Cu - $TiO_2$ powder, and mixed Ni - $TiO_2$ powder as the catalysts. Experiments were performed with the pulsed power and nitrogen carrier gas. The result has shown that the hydrogen concentration with the presence of $TiO_2$ powder was created higher than that of without using photocatalyst. The hydrogen concentration with using $TiO_2$ was 3012ppm corresponding to the applied voltage of 16kV, while it without using the $TiO_2$ was 1464ppm at the same condition . The effect of $TiO_2$ powder was strongly detected at the applied voltages of 15kV and 16kV. This phenomena might be resulted from the co-effect of the pulsed power discharge and the activated state of $TiO_2$ photocatalyst. The co-effect of the mixed catalysts such as Cu-$TiO_2$ and Ni-$TiO_2$ (the mixed photocatalyst $TiO_2$ and transition metals) were also investigated. The experimental results showed that, Cu and Ni powder dopants were greatly enhancing the activity of the $TiO_2$ photocatalyst. Under these experimental conditions the extremely high hydrogen concentrations at the optimal point were produced as 4089ppm and 6630ppm, respectively.

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참고문헌

  1. M. Deminsky, V.Jivotov, B. Potapkin, and V. Rusanov. "Plasma assisted production of hydrogen from hydrocarbons". Pure Appl. Chem., Vol.74, No.3, pp. 423-418, 2002 https://doi.org/10.1351/pac200274030423
  2. Kathleen Mc Hugh, "Hydrogen Production Methods". MPR-WP-0001, Associates Inc., February, 2005
  3. S.Z. Baykara " Hydrogen production by direct solar thermal decomposition of water, possibilities for improvement of process efficiency". International Journal of Hydrogen Energy 29 (2004) pp. 1451 - 1458
  4. Wu NL, Lee MH. "Enhanced TiO2 photocatalysis by Cu in hydrogen production from aqueous methanol solution. International Journal Hydrogen Energy, in press (doi: 10.1016/j.ijhydrene. 2004.02.13)
  5. Li Y, Lu G, Li S "Photocatalytic production of hydrogen in single component and mixture systems of electron donors and monitoring adsorption of donors by in situ infrared spectroscopy. Chemosphere 2003; 52 (5): 843 -50 https://doi.org/10.1016/S0045-6535(03)00297-2
  6. Kida T. Guan GQ, Yamada N, Ma TL, Kimura K, Yoshida A "Hydrogen production from sewage sludge solubilized in hot-compressed water using photocatalyst under light irradiation" International Journal Hydrogen Energy 2004; 29 (3): 269 -74 https://doi.org/10.1016/j.ijhydene.2003.08.007
  7. Abe T, Suzuli E, Nagoshi K, Miyashita K, Kaneko M "Electron source in photo induced hydrogen production on Pt- supported TiO2 particles. Journal Phys Chem B 1999; 103(7): 1119-23 https://doi.org/10.1021/jp983265x
  8. Linsebigler AL, Lu G, Yates Jr. JT "Photocatalysis on TiO2 surfaces: principle, mechanism, and selected results" Chem. Rev 1995; 95 (3): 735-58 https://doi.org/10.1021/cr00035a013
  9. Mills A, Le Hunte S "An overview of semiconductor photocatalysis". Journal Photochem Phtobiol A: Chem 1997; 108 (1): 1-35 https://doi.org/10.1016/S1010-6030(97)00118-4
  10. Legrini O, Oliveros E, Braun AM "Photochemical processes for water treatment". Chem Rev 1993; 93 (2): 671-98 https://doi.org/10.1021/cr00018a003
  11. Hoffman MR, Martin ST, Choi W, Bahneman DW."Environmental applications of semiconductor photocatalysis". Chem Rev 1995; 95(1): 69-96 https://doi.org/10.1021/cr00033a004
  12. Thammanoon S, Yoshikazu S, Susumu Y. "Photocatalytic evolution of hydrogen over mesoporous TiO2 supported NiO photocatalyst prepared by single-step sol-gel process with surfactant template". International Journal. Hydrogen Energy, 2004
  13. M.A. Rosen. "Energy and analyses of electrolytic hydrogen production". International Journal Hydrogen Energy, Vol.20, No.7,pp.547-553, 1995 https://doi.org/10.1016/0360-3199(94)00102-6
  14. Lekha N.M, Kanetoshi S, Hiroaki I, Noboru Y and Yasushi N. "Conversion of Methane to Hydrogen via Pulsed Corona Discharge", Journal of Natural Gas Chemistry 13, 2004
  15. T.Yamamoto, K.Ramanthan, P.A.Lawless, D.S. Ensor, J.Rnewsome, N.Plaks and G.H.Ramsey "Control of volatile organic compounds by an ac energized ferroelectric pellet reactor and pulsed corona reactor" IEEE Ind. Appl. Vol. 28,No 3, pp 528-534
  16. A.A. Nada, M.H. Barakat, H.A. Hamed, N.R.Mohamed, T.N. Veziroglu. "Study on the photocatalystic hydrogen production using suspended modified TiO2 photocatalyst". International Journal Hydrogen Energy Vol.30 (2005) pp. 687-691 https://doi.org/10.1016/j.ijhydene.2004.06.007
  17. S.Kodaira, Y.Sakisaka, T.Maruyama, Y.Haruyama, Y. Aiura, H.Kato, Solid state commune. 89 (1994) 9, and references therein
  18. Bahnemann, D. W.; Bockelmann, D.; Goslich, R. Solar Energy Materials 1991, 24, 564 https://doi.org/10.1016/0165-1633(91)90091-X
  19. M. R. Hoffman, S. T. Martin, W. Choi, and D. W. bahneman, Chem. Rev. 95, 69 (1995)][K. Kominami, J. Kato, Y. takada, y. Doushi, and B. Ohtani, Catal. Lett. 46, 235 (1997) https://doi.org/10.1023/A:1019022719479
  20. Jing D, Zhang Y, Guo L. "Study on the synthesis of Ni doped mesoporous TiO2 and its photocatalytic activity for hydrogen evolution in aqueous methanol solution". Chem. Phys. Letters 415 (2005) 74-78 https://doi.org/10.1016/j.cplett.2005.08.080
  21. N.Nakajima, H.Kato, T.Okazaki, Y.Sakisaka "Photoemission study of the modification of the electronic structure of transition-metal over layers on TiO2 surfaces III. Ni on TiO2 (001) and Cu on TiO2 (110)". Surface Science 561 (2004) 93-100 https://doi.org/10.1016/j.susc.2004.04.049