한국섬유공학회지 (Textile Science and Engineering)

  • 제45권3호
  • /
  • Pages.173-178
  • /
  • 2008
  • /
  • 1225-1089(pISSN)
  • /
  • 2288-6419(eISSN)
한국섬유공학회 (The Korean Fiber Society)
권호 표지

무수말레산과 에틸렌 메타크릴산 공중합체를 이용한 폴리프로필렌의 개질

Modification of Polypropylene by Grafting of Maleic Anhydride with EMAA Copolymer

  • 김진훈 (영남대학교 섬유패션학부) ;
  • 김석훈 (영남대학교 섬유패션학부) ;
  • 홍원표 (영남대학교 섬유패션학부) ;
  • 김준호 (영남대학교 섬유패션학부)
  • 발행 : 2008.06.30
⟨ 이전 논문 다음 논문 ⟩

초록

Polypropylene (PP) was modified by grafting of maleic anhydride(MAH) and blending of ethylene-methacrylic acid (EMAA) copolymer in biphenyl solution at $170^{\circ}C$. The films were examined by $^{13}C$ NMR, FT-IR, contact angle measurement and adhesion test in various MAH and EMAA copolymer compositions. The transition temperatures of the films remained constant irrespectively of MAH and EMAA copolymer compositions. From NMR and FTIR spectra the grafting of MAH onto PP backbone was checked. With contact angle measurements, it could be confirmed that the grafting of MAH and adding of EMAA copolymer onto PP made its surface more polar. Through the adhesive force evaluations, the value of peeling strength gave the maximum at the 1wt% of MAH and 0.5 wt% of EMAA copolymer.

키워드

참고문헌

  1. Y. C. Kim and K. C. Park, 'Application for Package Material of Polyester Film', Polym Sci Technol, 2001, 12(2), 197-207
  2. J. R. Whinfield, 'Chemistry of 'Terylene'', Nature, 1946, 158, 930-931 https://doi.org/10.1038/158930a0
  3. E. B. Parker, 'PE Polar Copolymer and Their Application', SPC'97, 1997, p.255
  4. J. S. Gong and S. Y. Han, 'Polyethylene for Food Packaging', Polym Sci Technol, 2001, 12(2), 183-196
  5. K. W. Cho and D. H. Lee, 'Science and Technology of Adhesion', Polym Sci Technol, 1995, 6(6), 545-555
  6. C. K. Samios and N. K. Kalfoglou, 'Compatibilization of Poly(ethylene-co-vinyl alcohol) (EVOH) and EVOH/HDPE Blends with Isomers, Structure and Properties', Polymer, 1998, 39, 3863-3870 https://doi.org/10.1016/S0032-3861(97)10093-3
  7. K. M. Finlayson, 'High Barrier Plastic Films for Packaging', Technomic Publishing, Lancaster, PA, 1989
  8. B. M. Dorscht and C. Tzoganakis, 'Reactive Extrusion of Polypropylene with Supercritical Carbon Dioxide: Free Radical Grafting of Maleic Anhydride', J Appl Polym Sci, 2003, 87, 1116-1122 https://doi.org/10.1002/app.11561
  9. X. Zheng, D. D. Jiang, and C. A. Wikie, 'Polystyrene Nanocomposites Based on an Oligomerically-modified Clay Contaning Maleic Anhydride', Polymer Degradation and Stability, 2006, 91, 108-113 https://doi.org/10.1016/j.polymdegradstab.2005.04.020
  10. R. Zhang, X. Q. Lu, H. Gao, G. Gui, and Q. Wu, 'Effect of the Initial Maleic Anhydride Content on the Grafting of Maleic Anhydride onto Isotatic Polypropylene', J Polym Sci, Part A, Polym Chem, 2005, 43, 5529-5534 https://doi.org/10.1002/pola.21038
  11. Y. Tamai, K. Makuuchi, and M. Suzuki, 'Experimental Analysis of Interfatial Forces at the Plane Surface of Solid', J Phys Chem, 1969, 71, 4176-4179 https://doi.org/10.1021/j100872a002
  12. D. K. Owens and R. C. Wendt, 'Estimation of Surface Free Energy of Polymers', J Appl Polym Sci, 1969, 13, 1741- 1747 https://doi.org/10.1002/app.1969.070130815
  13. W. Heinen, C. H. Rosenmoller, C. B. Wenzel, H. J. M. de Groot, J. Lugtenburg, and M. van Duin, '13C NMR Study of the Grafting of Maleic Anhydride onto Polyethylene, Polypropylene, and Ethen-propene', Macromolecules, 1996, 29, 1151-1157 https://doi.org/10.1021/ma951015y
  14. Y. T. Zhu, L. J. An, and W. Jiang, 'Monte Carlo Simulation of the Grafting of Maleic Anhydride onto Polypropylene at High Temperature', Macromolecules, 2003, 36, 3714-3720 https://doi.org/10.1021/ma0342168
  15. W. Heinen, S. W. Erkens, M. Van Duin, and J. Lugtenburg, 'Model Compounding and 13C NMR Increments for the Charicterization of Maleic Anhydride Grafted Polyolefins', J Polym Sci, Part A, Polym Chem, 1999, 37, 4368-4385 https://doi.org/10.1002/(SICI)1099-0518(19991201)37:23<4368::AID-POLA14>3.0.CO;2-R
  16. W. Qiu, T. Endo, and T. Hirotsu, 'A Novel Technic for Preparing of Maleic Anhydride Grafted Polyolefins', Euro Polym J, 2005, 41, 1979-1984 https://doi.org/10.1016/j.eurpolymj.2005.03.016
  17. F. R. Zhang, T. Endo, R. Kitakawa, H. Kabeya, and T. Hirotsu, 'Synthesis and Charicterization of a Novel Blend of Polypropylene with Chlorella', J Mater Chem, 2000, 10, 2666-2672 https://doi.org/10.1039/b004489j
  18. B. De Roover, M. Sclavons, V. Carlier, J. Devaux, R. Legras, and A. Momtaz, 'Molecular Characterization of Maleic Anhydride-Functionalized Polypropylene', J Polym Sci, Polym Chem, 1995, 33, 829-842 https://doi.org/10.1002/pola.1995.080330509
  19. M. Sclavons, V. Carlier, B. De Roover, P. Franquinet, J. Devaux, and R. Legras, 'Maleic Anhydride Grafted Polypropylene: FT-IR Study of a Model Polymer Grafted by Ene-reaction', J Appl Polym Sci, 1996, 62, 1205-1210 https://doi.org/10.1002/(SICI)1097-4628(19961121)62:8<1205::AID-APP10>3.0.CO;2-6