Macromolecular Research

  • 제16권3호
  • /
  • Pages.194-199
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  • 2008
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  • 1598-5032(pISSN)
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  • 2092-7673(eISSN)
한국고분자학회 (The Polymer Society of Korea)
권호 표지

Synthesis and Characterization of Novel Polyurethanes Based on 4-{(4-Hydroxyphenyl)iminomethyl} phenol

  • Raghu, A.V. (Department of Chemistry, University of Ulsan) ;
  • Jeong, Han-Mo (Department of Chemistry, University of Ulsan) ;
  • Kim, Jae-Hoon (Department of Chemistry, University of Ulsan) ;
  • Lee, Yu-Rok (Department of Chemistry, University of Ulsan) ;
  • Cho, Youn-Bok (Department of Chemistry, University of Ulsan) ;
  • Sirsalmath, Kiran (Center for Liquid Crystal Research)
  • 발행 : 2008.04.30
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초록

Four novel polyurethanes were prepared from 4-{(4-hydroxyphenyl)iminomethyl} phenol by reactions with two aromatic diisocyanates, 4,4'-diphenylmethane diisocyanate and toluene 2,4-diisocyanate, and two aliphatic diisocyanates, isophorone diisocyanate and hexamethylene diisocyanate. The polyurethanes formed were characterized by UV-vis, fluorescence, FT-IR, $^1H$-NMR, $^{13}C$-NMR, differential scanning calorimetry, thermogravimetry, and X-ray diffraction. The polymers were semi-crystalline and all polymers were soluble in polar aprotic solvents.

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