$TiO_2$ 촉매를 이용한 플라즈마반응에 의한 NOx의 분해

Reduction and Decomposition of Hazardous NOx by Discharge Plasma with $TiO_2$

  • 박성국 (인천대학교 안전공학과 대학원) ;
  • 우인성 (인천대학교 안전공학과) ;
  • 황명환 (인천대학교 안전공학과)
  • Park, Sung-Gug (Department of Safety Engineering, Graduate School of Incheon University) ;
  • Woo, In-Sung (Department of Safety Engineering, Incheon University) ;
  • Hwang, Myung-Whan (Department of Safety Engineering, Incheon University)
  • 발행 : 2008.10.31

초록

The objective of this study is to obtain the optimal process condition and the maximum decomposition efficiency by measuring the decomposition efficiency, electricity consumption, and voltage in accordance with the change of the process variables such as the frequency, maintaining time period, concentration, electrode material, thickness of the electrode, the number of windings of the electrode, and added materials etc. of the harmful atmospheric contamination gases such as NO, $NO_2$, and $SO_2$ etc. with the plasma which is generated by the discharging of the specially designed and manufactured $TiO_2$ catalysis reactor and SPCP reactor. The decomposition efficiency of the NO, the standard samples, is obtained with the plasma which is being generated by the discharge of the combination effect of the $TiO_2$ catalysis reactor and SPCP reactor with the variation of those process variables such as the frequency of the high voltage generator($5{\sim}50kHz$), maintaining time of the harmful gases($1{\sim}10.5sec$), initial concentration($100{\sim}1,000ppm$), the material of the electrode(W, Cu, Al), the thickness of the electrode(1, 2, 3mm), the number of the windings of the electrode(7, 9, 11turns), basic gases($N_2$, $O_2$, air), and the simulated gas($CO_2$) and the resulting substances are analyzed by utilizing FT-IR & GC.

키워드

참고문헌

  1. 국립환경과학원 대기오염물질 배출용어 정의, 2007
  2. I.S. Woo, M.Y. Hwang, S. Yamaguma, "Decomposition of Hazardous gaseous Substances by Discharge Plasma", J. of the KIIS, Vol, 11, No. 4, pp. 79-83, 1996
  3. S.Masuda, "Destruction of Gaseous Pollutants and Air Toxics by Surface Discharge Induced Plasma Chemical Process(SPCP) and Pulse Corona Induced Plasma Chemical Process(PPCP)", Non-Thermal Plasma Techniques for Pollution Control. NATOASI Series G. Ecologic Sciences. Vol. 34. pp. 1-105. Part B 1993
  4. J. Sidney clements, Akira Mizuno, Wright C Finney, Robort F, Davis, "Combined Removal of SOX NOx and Fly ash from Simulated flue Gas using Pulsed Steamer Corona", IEEE Translation on industry Applications, Vol. 25, No. 1, pp. 62-69, 1989 https://doi.org/10.1109/28.18870
  5. Senichi Masuda, Hidyuki Nakao, "Control of NOx by positive and negative Pulsed Corona Discharges", IEEE Transaction on Industry Application. Vol. 26, No. 2, pp. 374-383, 1990 https://doi.org/10.1109/28.54266
  6. 강현춘, 방전 Plasma에 의한 유해가스의 분해, 명지대학교 박사학위논문, 1998
  7. T. Takahashi, K. Tada, and T. Oda, "Atmospheric Pressure Dicharge Plasma Decomposition for Gaseous Air Contaminants-Trichloroethylene", 靜電氣學會講演論文集, 15a, B4, pp. 11-14, 1997
  8. K. Shimizu and T. Oda, "NOx Treatment Using Non- Themal Plasma Catalyst and Addition of Hydrocarbons", Proc. of NEDO Symp. on Non-Thermal Discharge Plasma Technology for Air Pollution Control, pp. 122-131, 1997
  9. T. Kawasaki, S. Tanaka, T. Ohkubo, S. Akamine, S. Kanazawa, and Y. Nomoto, "The Effect of Sintering Temperarture of BaTiO3 Pellets on NOx Removal in a Packed-bed Plasma Reactor", 靜電氣學會講演論文集, 16a, B9, pp. 7-248, 1997
  10. G. E. Vogtlin and B. M. Penetrante, "Pulsed corona discharge for removal of NOx form flue gas", NATO ASI Series, G34, Part A, pp. 187-198, 1993
  11. 淸水一男, 放電 プラズマによる 窒素酸化物 の 除去, 豊橋技科大 석사학위논문, 1993
  12. T. Oda, T. Takhashi, R. Yamashita, and T. Ohno, "Non-Thermal Plasma for VOCs Decomposition and NOx Removal in Flue Gas", Proc. of Nedo Symp. on Non-Thermal Discharge Plasma Technology for Air Pollution Control, 1-14, 1996