Variation of Carbonization Pattern and Crystal Structure of Polyvinyl Chloride Wire Under the Thermal Stresses

열 스트레스에 의한 비닐절연전선의 탄화 패턴 및 결정 구조의 변화

  • 최충석 (전주대학교 소방안전공학과) ;
  • 김향곤 (전기안전연구원 재해예방연구그룹)
  • Published : 2008.09.01

Abstract

We analyzed carbonization pattern and crystal structure of polyvinyl chloride wire by thermal stress. Copper that is oxidized at normal temperature is a reddish brown. If under the thermal stress range of 500 to 700 [$^{\circ}C$], carbonization and exfoliation occurrence. Section structure of electric wire is same as arrangement of particle in metallograph analysis. But, as thermal stress increases, size of particle is enlarged. Electric wire displays elongation structure in SEM image analysis and elongation structure collapses when receive thermal stress at 300 [$^{\circ}C$]. In EDX analysis, we get the spectra of CuL, CuK, OK, and ClK. FT-IR analysis was shown new spectra with in range of $1,440{\sim}1,430\;[cm^{-1}]$, 1,340 [$cm^{-1}$], 1,240 [$cm^{-1}$].

Keywords

References

  1. David R. Lide, "Handbook of Chemistry and Physics", CRC press, 76th Edition, pp.12-46-48, 1996
  2. 한국사전연구사, "이화학사전", pp.112-113, 1996
  3. 최충석 외 5, "전기화재공학", 동서출판 동화기술, pp.193-216, 2004
  4. 최충석 외 5, "열 열화 온도에 따른 IV의 수축률 및 조 직 분석", 대한전기학회하계학술지, pp.1416-1418, 2003
  5. 한국전기안전공사, "전기재해통계분석", pp.7-16, 2007
  6. 三橋 信雄, 橫井 良秀, 長田 正義, 伊坂 勝生, "絶緣被覆 電線の劣化履歷と火災危險について", 火災, Vol.31, No.1, pp.11-19, 1981
  7. 石橋 良男, 岸田 順次, "電線の一次, 二次熔融痕 鑑定方 法に關する硏究(その1),(その2)", 日本火災學會硏究發表 會槪要集, pp.83-90, 1990
  8. Bruce V. Ettling, "Electrical Wiring in Building Fires", Fire Technology, Vol.14, No.4, pp.317-325, 1978 https://doi.org/10.1007/BF01998391
  9. D. W. Levinson, "Copper Metallurgy as a Diagnostic Tool for Analysis of the Origin of Building Fires", Fire Technology, Vol.19, No.1, pp.211-222, 1983
  10. KS C 3302, 3325, "한국산업규격", 1992
  11. KS C 3004, "한국산업규격", 1992
  12. The Infrared Spectroscopy Committee, "An Infrared Spectroscopy Atlas for the Coatings Industry Federation of Societies for Coatings Technology", Philadelphia, 1980
  13. 一般分析化學編, 高分子分析ハンドブック, 朝倉書店, 1985
  14. P. J. Flory, "Statistical Thermodynamics of Rodlike Particles, 6. Rods Connected by Flexible Joints", Macromolecules, vol. 11, pp.1141-1144, 1978 https://doi.org/10.1021/ma60066a016
  15. W. Wrasidlo, "Transitions and Relaxations in Aromatic Polymers", J. Polymer Sci., Vol.A-2, No.9, pp.1603-1627, 1971