Journal of the Korean institute of surface engineering (한국표면공학회지)

The Korean Institute of Surface Engineering (한국표면공학회)
권호 표지
DOI QR코드

DOI QR Code

Synthesis of Nonionic Sorbitan Monostearate Using High Purity 1,4-sorbitan

고순도 1,4-솔비탄을 이용한 비이온 솔비탄 모노스테아르산 합성

  • Yu, Hwa-Yeal (Division of Applied Chemical Engineering, Pukyong National University) ;
  • Ju, Chang-Sik (Division of Applied Chemical Engineering, Pukyong National University) ;
  • Moon, Bu-Hyun (R & D Center, Hwasung Chemical Co., Ltd.) ;
  • Kim, Young-Seok (Korea Institute of Industrial Technology, Busan Research Center, Advanced Energy Resource Development Team) ;
  • Lee, Ju-Dong (Korea Institute of Industrial Technology, Busan Research Center, Advanced Energy Resource Development Team) ;
  • Lee, Man-Sig (Korea Institute of Industrial Technology, Busan Research Center, Advanced Energy Resource Development Team)
  • 류화열 (부경대학교 화학공학부) ;
  • 주창식 (부경대학교 화학공학부) ;
  • 문부현 (화성케미칼㈜ 기술연구소) ;
  • 김영석 (한국생산기술연구원 부산연구센터 차세대자원개발팀) ;
  • 이주동 (한국생산기술연구원 부산연구센터 차세대자원개발팀) ;
  • 이만식 (한국생산기술연구원 부산연구센터 차세대자원개발팀)
  • Published : 2008.04.30
Download PDF
⟨ Previous Next ⟩

Abstract

Nonionic sorbitan monostearate have been successfully prepared by esterification using 1,4-sorbitan and stearic acid. 1,4-sorbitan were prepared using D-sorbitol and acid catalyst at solvent-free conditions. The synthesized surfactants were characterized by NMR and FT-IR. We also investigated the effect of temperature, pressure and catalyst on the synthesis of nonionic sorbitan monostearate. The yields of 1,4-sorbitan were 90% at $160^{\circ}C$ under 160 mmHg vacuum, and the yields of nonionic sorbitan monostearate were 92% at $230^{\circ}C$ under 60 mmHg vacuum.

Keywords

References

  1. N. S. Jung, S. S. Kim, New Technology Investigation Report, 2th., The Korean Intellectual Property Office (2001)
  2. K. J. Nam, W. H. Huh, Synthesis of Surfactant and the Application Technique, (2006)
  3. G. G. Lim, M. S. Dissertation, Dissertation, Chunnam National University, Kwang-Ju, Korea (2002)
  4. S. Jan, C. Radka, F. Vladimir, Eur. J. Lipid Sci. Technol., 106 (2004) 851-855 https://doi.org/10.1002/ejlt.200401003
  5. D. H. Park, G. G. Lim, G. T. Jeong, K. Y. Byun, I. H. Kim, K. Y. Lee, H. S. Kim, Korean J. Biotechnol. Bioeng, 18(3) (2003) 222-228
  6. J. Ellis, H. Morgan, J. J. Lewis, R. J. Beattie, Manufacture of Fatty Acid Esters of Sorbitan as Surfactants, A.U. Patent, 3702997 (1998)
  7. G. Jasminka, M. Cedomila, W. Nikola, G. Fabio, J. Agric. Food Chem., 44 (1996) 3950-3954 https://doi.org/10.1021/jf950314j
  8. S. Ropuszynski, E. Sczesna, Polish Pat. Appl., 133 (1985) 768
  9. K. R. Brown, Monoesters of Inner Ethers of hexahydric alcohols, Patent U.S. 2 322 820(1944)
  10. H. Stuehler, Carboxylic Acid Esters of Hexitols, D.E. Patent 3 240 892(1984)
  11. J. Giacometti, C. Milin, N. Wolf, F. Giacometti, J. Agric. Food Chem., 44 (1996) 3950-3954 https://doi.org/10.1021/jf950314j