Textile Science and Engineering (한국섬유공학회지)

The Korean Fiber Society (한국섬유공학회)
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Photovoltaic Properties of Polymer with Fluorene and Imine Groups in the Main Chain

이민기와 플루오렌기를 주쇄에 함유하는 고분자의 광기전 성질

  • Kim, Hyung-Jun (Organic and Optoelectronic Materials Laboratory, Department of Advanced Organic Materials and Textile System Engineering, Chungnam National University) ;
  • Lee, Jung-Hyo (Organic and Optoelectronic Materials Laboratory, Department of Advanced Organic Materials and Textile System Engineering, Chungnam National University) ;
  • Kwak, Chan-Kyu (Organic and Optoelectronic Materials Laboratory, Department of Advanced Organic Materials and Textile System Engineering, Chungnam National University) ;
  • Jin, Sung-Ho (Department of Chemistry Education and Interdisciplinary Program of Advanced Information and Display Materials, Pusan National University) ;
  • Lee, Taek-Seung (Organic and Optoelectronic Materials Laboratory, Department of Advanced Organic Materials and Textile System Engineering, Chungnam National University)
  • 김형준 (충남대학교 공과대학 바이오응용화학부) ;
  • 이정효 (충남대학교 공과대학 바이오응용화학부) ;
  • 곽찬규 (충남대학교 공과대학 바이오응용화학부) ;
  • 진성호 (부산대학교 화학교육과) ;
  • 이택승 (충남대학교 공과대학 바이오응용화학부)
  • Published : 2008.02.29
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Abstract

New polyimine derivative containing fluorene group in the main chain was synthesized via Suzuki cross-coupling polymerization, reduction, and imine formation reaction, consecutively. The synthesized polymer was characterized and explored as organic photovoltaic cell device. The imine polymer P3 in diluted chloroform solution emitted red light (582 nm), whereas its precursor polymers P1 and P2 showed green (about 530 nm) and blue fluorescence (477 nm), respectively. Bulk heterojunction photovoltaic cells fabricated by blending P3 with the fullerene derivative PCBM was found to have a power conversion efficiency of upto 0.0005%, while cells from blending P3 with MEH-PPV yielded 0.0008% of power conversion efficiency.

Keywords

References

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