DOI QR코드

DOI QR Code

에폭시/유기적으로 변경된 층상실리케이트가 충진 된 나노콤포지트의 유전특성

Dielectric Properties of Epoxy/Organically Modified Layered Silicate Nanocomposites

  • 박재준 (중부대학교 전기전자공학과)
  • 발행 : 2008.02.01

초록

Epoxy/Organically Modified Layered Silicate Nanocomposites were prepared by dispersing synthetic layered silicate modified with alkyl ammonium ions. In the dispersing process, the organically modified layered silicate were mixed in epoxy resin with shearing, and aggregation of the silicate were removed by centrifugal separation after mixing epoxy resin and silicates. Micrographs taken by transmission electron microscopy(TEM) indicate that the nanocomposites have a mixed morphology including both parallel silicate layers and exfoliated silicate layers area, As the thermal properties, the glass transition temperature of the nanocomposites was shifted to a higher temperature($+6^{\circ}C$)than pure epoxy. Furthermore, dispersion of OMLS will prevented relative permittivity from increasing at a high temperature above the glass transition temperature.

키워드

참고문헌

  1. Y. Kojima, A. Usuki, M. Kawasumi, A. Okada, T. Kurauchi, and O. Kamigaito, 'One-spot synthesis nylon-6 clay hydrid', J. Polym. Sci, Part A, Vol. 31, p. 1755, 1993 https://doi.org/10.1002/pola.1993.080310714
  2. Saeed Saber-Samandari, Akbar Afaghi Khatibi, and Domagij Basic, 'An experiment study on clay/nanocomposites produced in a centrifuge', Composite: Part B, Vol. 38, p. 102, 2007 https://doi.org/10.1016/j.compositesb.2006.03.010
  3. T. J. Lewis, 'Nanometric dielectric', IEEE Trans. Dielectr. Insul., p. 812, 1994
  4. S. S. Ray and M. Okamoto, 'Polymer/layered silicate nanocomposites:a review from preparation to processing progress in polymer science, Vol. 28, p. 1539, 2003 https://doi.org/10.1016/j.progpolymsci.2003.08.002
  5. C. Zhang, R. Mason, and G. Stevens, 'Preparation, characterization and dielectric properties of epoxy and polyethylene nanocomposites', IEEJ Trans. FM, Vol. 126, No. 11, 2006
  6. E. M. Petrie, 'Epoxy Adhesive Formulations', McGraw-Hill Chemical Engineering, 2005
  7. T. Lmai, Y. Hirano, H. Hirai, S. Kojima, and T. Shimizu, 'Preparation and Properties of Epoxy-organically Modified Layered Silicate Nanocomposites', IEEE. Intern. Sympo. Electr. Insul.(ISEI), p. 379, 2002
  8. E. P. M. Williams, J. C. Seferis, and C. L. Wittman, G. A. Parker, J. H. Lee, J. D. Nam, 'Dielectric nanocapacitance effect of thermoset polymeric matrix nanocomposites', Journal of Polymer Science: Part B: Polymer Physics, Vol. 42, p. 1, 2004
  9. 迢秀, '誘電體論', オ-ム社, p. 121, 1983
  10. 박재준, '층상구조 실리케이트 고분자나노복합 체', 전기전자재료, 20권, 3호, p. 9, 2007

피인용 문헌

  1. Thermal Characteristics of Epoxy-Nanocomposites filled Several Types Nano Layered Silicate Particles vol.21, pp.8, 2008, https://doi.org/10.4313/JKEM.2008.21.8.749