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Solubility and density of p-dioxanone in organic solvent systems

  • Lee, Sang-Won (Department of Chemical Engineering, Chung Nam National University) ;
  • Kim, Sung-Il (R&D center, Samchun Pure Chemical Ind. Co., LTD) ;
  • Park, So-Jin (Department of Chemical Engineering, Chung Nam National University)
  • 발행 : 2008.12.31

초록

The p-dioxanone can be used to make a variety of commercially useful products particularly where biodegradability is desired, such as fibers, sutures, molded articles, containers, medical devices and surgical clips, film and compostable trash bags. The mole fraction solubility of p-dioxanone in various solvents such as acetone, ethylacetate, tetrahydrofuran, methanol, ethanol, 1-propanol, 1-butanol and 1-pentanol were measured over the temperature range from 263.05 K to 288.45 K. The solubility of p-dioxanone increases with increasing polarity of the solvents.

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참고문헌

  1. J. H. Lee, H. R. Kim, Y. H. Han, S. J. Jeong, Y. J. Seo and B. R. Choi, Korean Patent KR 2003-0050471, (2003)
  2. C. U. Kim, K. J. Kim and Y. H. Cheon, Korean Patent KR 2004-0033122, (2004)
  3. C. G. Moyers and M. P. Farr, US Patent Number 5,675,022, (1997)
  4. A. Mersmann, 'Crystallization Technology Handbook', Marcel Dekker, Inc., New York, (1994)
  5. J. A. Riddick, W. B. Bunger and T. K. Sakano, 'Techniques of Chemistry, Organic Solvents', 4th ed.; John Wiley and Sons: New York, 1, 190 (1986)
  6. K. J. Kim, M. J. Kim, J. M. Lee, H. S. Kim and B. S. Park, Experimental Solubility and Density for 3-Nitro-1,2,4-Triazol-5-One + C1 to C7 1-Alkanols, Fluid Phase Equilib., 146, 261 (1998) https://doi.org/10.1016/S0378-3812(98)00182-4
  7. K. J. Kim, M. J. Kim, J. M. Lee, S. H. Kim, H. S. Kim and B. S. Park, Solubility, Density and Metastable Zone Width of the 3-Nitro-1,2,4-triazol-5-one+Water System, J. Chem. Eng. Data, 43, 65 (1998) https://doi.org/10.1021/je970155v
  8. K. J. Kim, C. H. Lee and S. K. Ryu, 'Solubility of Thiourea in $C_1-C_6$ 1-Alcohols', J. Chem. Eng. Data, 39(2), 228 (1994) https://doi.org/10.1021/je00014a008
  9. J. Gmehling and B. Kolbe, 'Thermodynamics', VCH: Weinheim, (1992)
  10. A. Jakob, R. John, C. Rose and J. Gmehling, Solid-Liquid Equilibria in Binary Mixtures of Organic Compounds, Fluid Phase Equilib., 113, 117 (1995) https://doi.org/10.1016/0378-3812(95)02807-X
  11. J. M. Prausnitz, R. N. Lichtenthaler and E. G. Azevedo, 'Molecular Thermodynamics of Fluid-Phase Equilibria', Prentice-Hall, Inc.: Englewood Cliffs, NJ, Chapter 9 (1986)