The growth of zinc oxide particles by coagulation in aerosol reactor

에어로졸 반응기에서 산화아연 입자의 응집 성장

  • Lee, Jong Ho (Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology) ;
  • Song, Shin Ae (Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology) ;
  • Park, Seung Bin (Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology)
  • Received : 2008.10.16
  • Accepted : 2008.11.24
  • Published : 2008.12.30

Abstract

Nanosize ZnO particles were prepared by oxidation of zinc vapor and the particle growth was modeled by a coagulation model by assuming that the characteristic time for reaction was much shorter than coagulation time and residence time (${\tau}_{reaction}{\ll}{\tau}_{coagulation}{\ll}{\tau}_{residence}$). Experimental measurement of zinc oxide particles diameter was consistent with the predicted result from the coagulation model. For practical purpose of predicting zinc oxide size in areosol reactor, the constant kernel solution is concluded to be sufficient, Uniqueness of nano-scale property of zinc oxide was confirmed by the higher photocatalytic activity of zinc oxide than nanosize titania particles.

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