Fuel Cell End Plates: A review

  • Kim, Ji-Seok (School of Mechanical and Aerospace Engineering, Seoul National University) ;
  • Park, Jeong-Bin (School of Mechanical and Aerospace Engineering, Seoul National University) ;
  • Kim, Yun-Mi (School of Mechanical and Aerospace Engineering, Seoul National University) ;
  • Ahn, Sung-Hoon (School of Mechanical and Aerospace Engineering, Seoul National University) ;
  • Sun, Hee-Young (Samsung Advanced Institute of Technology) ;
  • Kim, Kyung-Hoon (Samsung Advanced Institute of Technology) ;
  • Song, Tae-Won (Samsung Electronics Co., Ltd.)
  • Published : 2008.01.01

Abstract

The end plates of fuel cell assemblies are used to fasten the inner stacks, reduce the contact pressure, and provide a seal between Membrane-Electrode Assemblies (MEAs). They therefore require sufficient mechanical strength to withstand the tightening pressure, light weight to obtain high energy densities, and stable chemical/electrochemical properties, as well as provide electrical insulation. The design criteria for end plates can be divided into three parts: the material, connecting method, and shape. In the past, end plates were made from metals such as aluminum, titanium, and stainless steel alloys, but due to corrosion problems, thermal losses, and their excessive weight, alternative materials such as plastics have been considered. Composite materials consisting of combinations of two or more materials have also been proposed for end plates to enhance their mechanical strength. Tie-rods have been traditionally used to connect end plates, but since the number of connecting parts has increased, resulting in assembly difficulties, new types of connectors have been contemplated. Ideas such as adding reinforcement or flat plates, or using bands or boxes to replace tie-rods have been proposed. Typical end plates are rectangular or cylindrical solid plates. To minimize the weight and provide a uniform pressure distribution, new concepts such as ribbed-, bomb-, or bow-shaped plates have been considered. Even though end plates were not an issue in fuel cell system designs in the past, they now provide a great challenge for designers. Changes in the materials, connecting methods, and shapes of an end plate allow us to achieve lighter, stronger end plates, resulting in more efficient fuel cell systems.

Keywords

References

  1. Zhou, P., Wu, C.W. and Ma, G. J., 'Contact resistance prediction and structure optimization of bipolar plates,' Journal of Power Sources, Vol. 159, Issue 2, pp.1115-1122, 2006 https://doi.org/10.1016/j.jpowsour.2005.12.080
  2. Fu, Y., Hou, M., Yan, X., Hou, J., Luo, X., Shao, Z. and Yi, B., ' Research progress of aluminium alloy endplates for PEMFCs,' Journal of Power Sources, Vol. 166, Issue 2, pp.435-440, 2007 https://doi.org/10.1016/j.jpowsour.2007.01.018
  3. Pozio, A., Silva, R.F., De Francesco, M. and Giorgi, L., 'Nafion degradation in PEFCs from end plate iron contamination,' Electrochimica Acta, Vol. 48, Issue 11, pp. 1543-1549, 2003 https://doi.org/10.1016/S0013-4686(03)00026-4
  4. Hatoh, K., Kusakabe, H., Ohara, H., Kobayashi, S., Yamazaki, T., Sugou, M., Hase, N. and Takeguchi, S., 'Polymer electrolyte fuel cell,' US Patent No: 0152819, 2003
  5. Morrow, A.W., 'Fuel cell stack having an improved pressure plate and current collector,' WO Patent No: 96447, 2003
  6. Mok, Y. D., Mok, S. Y., 'End plates and current collector plates for fuel cells,' KR Patent No: 7012006, 2002
  7. Patermarakis, G. and Papadreadis, N., 'Effect of the structure of porous anodic Al2O3filmsonthemechanismoftheirhydrationandporeclosureduringhydrothermaltreatment', Electrochimica Acta, Vol. 38, Issue 10, pp.1413-1420, 1993 https://doi.org/10.1016/0013-4686(93)80078-E
  8. Thompson, G. E., 'Porous anodic alumina: fabrication, characterization and applications,' Thin Solid Films, Vol. 297, Issue 1-2, pp. 192-201, 1997 https://doi.org/10.1016/S0040-6090(96)09440-0
  9. Muller, B. and Fischer, S., 'Epoxy ester resins as corrosion inhibitors for aluminum and zinc pigments,' Corrosion Science, Vol. 48, pp. 2406-2416, 2006 https://doi.org/10.1016/j.corsci.2005.10.002
  10. Cho, S. H., 'The product method and end plate of fuel cell,' KR Patent No: 0034038, 2005
  11. Hatoh, K., Kusakabe, H., Ohara, H., Kobayashi, S., Yamazaki, T., Hase, N. and Takeguchi, S., 'Polymer electrolyte fuel cell,' EP Patent No: 291951, 2003
  12. Takashita, M., Nakano, Y. and Fujieda, S., 'Separator for fuel cell, end plate for fuel cell, and fuel cell power generation apparatus,' US Patent No: 0048347, 2005
  13. Kim, S. H., Lee, K. C. and Cho, K. T., 'End plate for fuel cell stack,' KR Patent No: 0039467, 2001
  14. Kindler, A., 'Low cost, lightweight fuel cell elements,' WO Patent No: 27601, 1999
  15. Guthrie, R. J., 'Polymeric Header for fuel cell pressure plate assembles,' US Patent No: 6048635, 2000
  16. Groover, M. P., 'Fundamentals of modern manufacturing,' John Wiley & Sons, pp.213-232, 2002
  17. Hatoh, K., Kusakabe, H., Ohara, H., Kobayashi, S., Yamazaki, T., Hase, N. and Takeguchi, S., 'Fuel Cell,' KR Patent No: 0054434., 2002
  18. Agizy, A. E., Sheridan, D. M. and Hanson, R. G., 'Injection molded fuel cell endplate,' US Patent No: 0182470, 2002
  19. Ahn, B. K., 'A New Concept of Pressure Plates for PEMFC Stacks Using Sandwich Plate Structures,' 2004.
  20. Kim, S. J., Hong, B. S. and Shin, M. N., 'Assembling structure for the PEM fuel cell stacks,' KR Patent No: 0036394, 2005
  21. Cho, K.T., Kim, S.H., Hwang, W.B. and Chun J.H., 'Compression structure for fuel cell stack,' KR Patent No: 0043005, 2005
  22. Ronald, H. D. and Barrett, M., 'End plates and current collector plates for fuel cells,' EP Patent No: 511105, 2005
  23. Tawfik, H. and Hung, Y., 'Fuel cell stack,' WO Patent No: 049493, 2004
  24. Uchimura, N., Chiba, N., Nakamura, Y. and Kano, M., 'Fuel cell separator, fuel cell stack, fuel cell vehicle, and method of manufacturing the fuel cell separator,' WO Patent No: 101555, 2005
  25. Kwon, H. J. and Lee, D. H., 'Stack for fuel cell and fuel cell system,' KR Patent No: 0116438, 2005
  26. Yoon, H. S., Kim, I. K., Kim, H. D., Park, I. K., Park, M. S., Lee, S. H., Lee, M. H. and Hwang, Y. J., 'Apparatus for engaging stack of fuel cell,' KR Patent No: 0056186, 2002
  27. Inagaki, T., 'Fuel cell,' EP Patent No: 601041, 2005
  28. Son, I. H. and Han, S. I., 'Flat plate clamp structure for fuel cell stack,' KR Patent No: 0036485, 2007
  29. Wariishi, Y. and Sugita, N., 'Fuel cell stack,' EP Patent No: 526599, 2004
  30. Han, S. I., Son, I. H., Shin, C. K. and Seo, J.W., 'Method and apparatus for tie up fuel cell stack using shape memory alloy,' KR Patent No: 0036482, 2007
  31. Sung, Y. E., Cho, Y. H., Cho, Y. H. and Bae, J. M., 'Fastening structure of a fuel cell stack,' KR Patent No: 0133474, 2005
  32. Evertz, J. and Günthart, M., 'Structural concepts for lightweights and cost-effective end plates for fuel cell stacks,' International conference with exhibition in 2nd European PEFC forum, pp. 469-482, 2003