Improvement of Whiteness of Glyoxal Treated Cotton Fabrics by Additives

글리옥살 처리 면직물의 첨가제에 의한 백도 증진

  • Shin, In-Soo (Department of Human Environmental Sciences, Won Kwang University) ;
  • Kim, Yong-Tae (Department of Textile Engineering, Inha University) ;
  • Lee, Eui-So (Department of Textile Engineering, Inha University)
  • 신인수 (원광대학교 생활과학부 패션디자인산업) ;
  • 김용태 (인하대학교 공과대학 섬유공학과) ;
  • 이의소 (인하대학교 공과대학 섬유공학과)
  • Published : 2008.10.31

Abstract

Cotton fabrics were treated with glyoxal for a nonformaldehyde durable-press finish by a pad-dry-cure method. $MgCl_{2}/citric$ acid mixture or $Al_{2}(SO_{4})_{3}$ were used as a catalyst. The effects of additives such as sodium tetraborate decahydrate (STB), sodium peroxoborate tetrahydrate (SPB), and sodium chlorite (SC) were examined. The additives improved the whiteness and strength retention of the treated fabrics. SPB was superior to STB for the whiteness and strength retention. SC was better than either SPB or STB in the wrinkle recovery angles (WRA) and strength retention while the whiteness was similar to that of SPB or STB. SC was more effective for improving the whiteness and strength retention when it was used together with sodium phosphate monobasic.

Keywords

References

  1. C. M. Welch, 'Tetracarboxylic Acids as Formaldehyde Free Durable Press Finishing Agents', Text Res J, 1988, 58, 480-486 https://doi.org/10.1177/004051758805800809
  2. S. H. Zeronian, G. Buschle-Diller, L. D. Fisher, K. W. Alger, S. A. Holmes, P. A. Slaven, and N. R. Bertoniere, 'Effect of Preswelling Treatments on the Properties of Cotton Fibers Crosslinked with 1,2,3,4 Butanetetracarboxylic Acid', Text Res J, 1993, 63, 488-493 https://doi.org/10.1177/004051759306300809
  3. I. S. Kang, C. Q. Yang, W. Wei, and G. C. Lickfield, 'Mechanical Strength of Durable Press Finished Cotton Fabrics. Part I. Effects of Acid Degradation and Crosslinking of Cellulose by Polycarboxylic Acids', Text Res J, 1998, 68, 865-870 https://doi.org/10.1177/004051759806801112
  4. J. R. Park, E. S. Lee, and S. W. Ko, 'Durable Press Finish of Cotton Fabrics with 1,2,3,4-Butanetetracarboxylic Acid', J Korean Fiber Soc, 1997, 33, 429-435
  5. J. N. Lim, E. S. Lee, and S. W. Ko, 'Durable Press Finish of Polyester/Cotton Fabrics with 1,2,3,4-Butanetetracarboxylic Acid', J Korean Fiber Soc, 1997, 34, 517-523
  6. S. N. Pandey and C. R. Raje, 'Highly Active Mixed Catalyst System for Producing Durable Press Cotton Textiles', Text Res J, 1987, 57, 265-269 https://doi.org/10.1177/004051758705700503
  7. K. W. Oh, E. J. Jung, and H. M. Choi, 'Nonformaldehyde Crease-Resistant Finishing of Ramie with Glyoxal in the Presence of a Swelling Agent', Text Res J, 2001, 71, 225-230 https://doi.org/10.1177/004051750107100307
  8. C. M. Welch, 'Glyoxal as a Formaldehyde Free Durable Press Reagent for Mild Curing Applications', Text Res J, 1983, 53, 181-186 https://doi.org/10.1177/004051758305300307
  9. C. M. Welch and G. F. Danna, 'Glyoxal as a Non-Nitrogenous Formaldehyde-Free Durable Press Agent for Cotton', Text Res J, 1982, 52, 149-157 https://doi.org/10.1177/004051758205200209
  10. E. S. Lee and S. I. Kim, 'Effect of Additives on Durable-Press Cotton Fabrics Treated with a Glyoxal/Glycol Mixture', J Appl Polym Sci, 2005, 96, 975-978 https://doi.org/10.1002/app.20751
  11. D. L. Worth, U.S. Patent, 4,269,603(1981)
  12. D. L. Worth and E. A. Freeman, U.S. Patent, 4,269,602 (1981)
  13. E. R. Trotman, 'Dyeing and Chemical Technology of Textile Fibres', 6th Ed., John Wiley and Sons, New York, 1984, p.205