Bulletin of the Korean Chemical Society

  • 제29권1호
  • /
  • Pages.187-190
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  • 2008
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Bis(imino)aryl Complex of Nickel(II): N,C,N-Pincer Type Complex, (2,6-(2,6-Et2PhN=CH)2C6H3)NiBr

  • 발행 : 2008.01.20
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초록

The synthesis of a novel N,C,N-type pincer, bis(N-aryl)-2-bromoisophthalaldimine 2,6-(2,6-Et2PhN = CH)2C6H3Br (1) and Ni(1)Br (2) is described. They were characterized by elemental analysis and spectroscopic techniques (IR and 1H NMR). Attempted ethylene polymerization catalyzed by 2 has been futile, leading only to the formation of a small amount of oily oligomers.

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피인용 문헌

  1. Nickelation of PCP- and POCOP-Type Pincer Ligands: Kinetics and Mechanism vol.31, pp.17, 2012, https://doi.org/10.1021/om3003784
  2. Ni(ii) and Fe(ii) complexes based on bis(imino)aryl pincer ligands: synthesis, structural characterization and catalytic activities vol.41, pp.32, 2012, https://doi.org/10.1039/c2dt30778b
  3. Synthesis, Structure, and Reactivity of Iridium(III) Complexes Containing a 4,6-Dimethyl-1,3-benzenediphenylimine Pincer Ligand vol.52, pp.1, 2013, https://doi.org/10.1021/ic302589b
  4. Classification and synthesis of nickel pincer complexes vol.67, pp.3, 2018, https://doi.org/10.1007/s11172-018-2086-7