Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Twist Boat Conformation of Thiane S-Oxide Both in Solid State and in Solution

  • Jeon, Dong-Ju (Center for Medicinal Chemistry, Korea Research Institute of Chemical Technology) ;
  • Kim, Ikyon (Center for Medicinal Chemistry, Korea Research Institute of Chemical Technology)
  • Published : 2008.07.20
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Abstract

A stable twist boat conformation of thiane S-oxide 1a in solid state and in solution was unambiguously determined by single crystal X-ray crystallography and solution NMR analyses. On the contrary, the thiane Sdioxide 2 which was obtained from the oxidation of corresponding thiane S-oxide 1a was confirmed to adopt a regular chair conformation.

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References

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