Bulletin of the Korean Chemical Society

  • 제29권10호
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  • Pages.1993-1997
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  • 2008
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Diels-Alder Cycloaddition of Cyclopentadiene with Ethylacrylate Catalyzed by Mesoporous Al-MCM-48 and Al-MCM-41 Catalysts

  • Shon, Jeong-Kuk (Department of Chemistry and BK21 School of Chemical Materials Science, Sungkyunkwan University) ;
  • Sim, Jae-Yi (Department of Chemistry and BK21 School of Chemical Materials Science, Sungkyunkwan University) ;
  • Thakur, Santosh Singh (Department of Chemistry and BK21 School of Chemical Materials Science, Sungkyunkwan University) ;
  • Ko, Eun-Mi (Department of Chemistry and BK21 School of Chemical Materials Science, Sungkyunkwan University) ;
  • Kong, Soo-Sung (Department of Chemistry and BK21 School of Chemical Materials Science, Sungkyunkwan University) ;
  • Choi, Ji-Yun (Department of Chemistry and BK21 School of Chemical Materials Science, Sungkyunkwan University) ;
  • Kang, Min (Department of Chemistry and BK21 School of Chemical Materials Science, Sungkyunkwan University) ;
  • Senapati, Bidyut Kumar (Department of Chemistry and BK21 School of Chemical Materials Science, Sungkyunkwan University) ;
  • Choi, Doo-Seoung (Department of Chemistry and BK21 School of Chemical Materials Science, Sungkyunkwan University) ;
  • Ryu, Do-Hyun (Department of Chemistry and BK21 School of Chemical Materials Science, Sungkyunkwan University) ;
  • Kim, Ji-Man (Department of Chemistry and BK21 School of Chemical Materials Science, Sungkyunkwan University)
  • 발행 : 2008.10.20
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초록

In the present work, Diels-Alder reaction of cyclopentadiene with ethylacrylate has been carried out by using two types of mesoporous solid acid catalysts (Al-MCM-41, Al-MCM-48) with different pore structures. The specific topology of Al-MCM-48 (cubic Ia3d structure composed of two independent 3-D channel systems) exhibit higher activity and stereo-control than those of Al-MCM-41 (hexagonal packing of 1-D channels). The physical properties of Al-MCM-48 catalyst, such as high accessibility of reactants to the acid sites, spatial confinement in the nanoscopic reactors, and 3-D channel network structure that are effective adsorption and diffusion of reactants, play a crucial role in the present study.

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피인용 문헌

  1. Oxidation of anisole over MCM-48 materials modified by incorporation of transition and inner transition metals vol.2, pp.11, 2012, https://doi.org/10.1039/c2cy20198d
  2. ChemInform Abstract: Diels-Alder Cycloaddition of Cyclopentadiene with Ethylacrylate Catalyzed by Mesoporous Al-MCM-48 and Al-MCM-41 Catalysts. vol.40, pp.9, 2009, https://doi.org/10.1002/chin.200909068
  3. Stereoselective Synthesis of the Southern Domain of Tubelactomicin A by a Tandem Intramolecular Diels-Alder/Lactonization Reaction vol.30, pp.2, 2008, https://doi.org/10.5012/bkcs.2009.30.2.289