Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Gallium(III) Ion Hydrolysis under Physiological Conditions

  • Hacht, Brahim (Laboratoire de Speciation et de Surveillance de la Pollution en Mediterranee. University Mohammed 1st, Faculty of Sciences, Department of Chemistry)
  • Published : 2008.02.20
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Abstract

The hydrolysis of gallium(III) has been studied using potentiometric techniques under physiological conditions of temperature 37 C and ionic strength 0.15 moldm-3 NaCl and at different metal ion concentrations. Changes in pH were monitored with a glass electrode calibrated daily in hydrogen ions concentrations. The titration data within the pH range of 2.5-9.99 were analyzed to determine stability constants of hydroxide species using the SUPERQUAD program. Several different species were considered during the calculation procedure and the following hydroxides have been characterized: Ga(OH)3, Ga(OH)4- Ga3(OH)112-, Ga4(OH)11+ and Ga6(OH)153+. Speciation calculations based on the determined constants were then used to simulate the species distribution.

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