낮은 오일 농도에서 $CO_2$-PEC9 혼합물의 밀도와 점성 예측

Prediction of Density and Viscosity for $CO_2$-PEC9 Mixture at Low Oil Concentration

  • 윤린 (한밭대학교 기계공학과)
  • Yun, Rin (Department of Mechanical Engineering, Hanbat National University)
  • 발행 : 2008.11.10

초록

Due to environmental concerns $CO_2$ has been reintroduced as a potential candidate to replace HFCs in refrigeration systems. Oils are always required in a vapor-compression cycle, and thus it is necessary to precisely estimate the thermodynamic mixture properties of $CO_2$-lubricant oil. In the present study, the density and the viscosity of the mixture was calculated by the Redlich and Kwong type EoS and the modified Peng and Robinson type viscosity EoS, respectively. The viscosity model was based on the similarity between P-v-T and T-$\mu$-P relationships. The predicted results were compared with the experimental data of Pens ado et al. whose test conditions were 100$\sim$650 bar of pressure and 303 K$\sim$353 K of temperature with the $CO_2$-POEs mixtures under 92.2 wt.% and 83.3 wt.% of $CO_2$ concentration. The mean deviations of the mixture density were 7.93% and 8.32% for 92.2 wt.% and 83.3 wt.% of $CO_2$ concentration, respectively. Concerning the viscosity, the mean deviations were 4% and 10% for 92.2 wt.% and 83.3 wt.% of $CO_2$ concentration under the Pensado et al.'s test conditions.

키워드

참고문헌

  1. Kang, B. H., 2008, Characteristics of the $CO_2$-oil mixture, Journal of KSME, Vol. 48, No. 1, pp. 53-58
  2. Yun. R., Hwang, Y. and Radermacher, R., 2007, Convective gas cooling heat transfer and pressure drop characteristics of supercritical $CO_2$/oil mixture in a minichannel tube, International Journal of Heat and Mass Transfer, Vol. 50, pp. 4796-4804 https://doi.org/10.1016/j.ijheatmasstransfer.2007.03.018
  3. Pensado, A. S., Pádua, A. A. H., Comunas, J. and Fernandez, M. J. P., 2008, Viscosity and density measurements for carbon dioxide + pentaerythritol ester lubricant mixtures at low lubricant concentration, J. of Supercrictical Fluids, Vol. 44, pp. 172-185 https://doi.org/10.1016/j.supflu.2007.10.004
  4. Yokozeki, A., 2007, Solubility correlation and phase behaviors of carbon dioxide and lubricant oil mixtures, Applied energy, Vol. 84, pp. 159-175 https://doi.org/10.1016/j.apenergy.2006.05.003
  5. Park, K. S., Kang, B. H., Park, K. K. and Kim, S., 2007, Correlations of oil concentration prediction during in-line flow of $CO_2$/Oil mixtures, Korean Journal of Air-Conditioning and Refrigeration Engineering, Vol. 19, No. 10, pp. 718-725
  6. Teodorescu, M., Lugo, L. and Fernández, 2003, Modeling of Gas Solubility Data for HFCs-Lubricant Oil Binary Systems by Means of the SRK Equation of state, International Journal of Thermophysics, Vol. 24, No. 4, pp. 1043-1060 https://doi.org/10.1023/A:1025005018310
  7. Guo, X.-Q., Sun, C.-Y., Rong, S.-X., Chen, G.-J. and Guo, T.-M., 2001, Equation of state analog correlations for the viscosity and thermal conductivity of hydrocarbons and reservoir fluids, Journal of Petroleum Science and Engineering, Vol. 30, pp. 15-27 https://doi.org/10.1016/S0920-4105(01)00098-5
  8. Guo, X.-Q., Wang, L.-S., Rong, S.-X. and Guo, T.-M., 1997, Viscosity model based on equations of state for hydrocarbon liquids and gases, Fluid Phase Equilibria, Vol. 139, pp. 405-421 https://doi.org/10.1016/S0378-3812(97)00156-8
  9. Fan, T.-B. and Wang, L.-S., 2006, A viscosity model based on Peng-Robinson equation of state for light hydrocarbon liquids and gases, Fluid Phase Equilibria, Vol. 247, pp. 59-69 https://doi.org/10.1016/j.fluid.2006.06.008
  10. Al-Syabi, Z., Danesh, A., Tohidi, B., Todd, A. C. and Tehrani, D. H., 2001, A residual viscosity correlation for predicting the viscosity of petroleum reservoir fluids over wide ranges of pressure and temperature, Chemical Engineering Science, Vol. 56, pp. 6997-7007 https://doi.org/10.1016/S0009-2509(01)00334-7
  11. Reid, R. C., Prausnitz, J. M. and Poling, B. E., 1988, The properties of gases and liquids, Mcgraw-hill, pp. 388-473