DOI QR코드

DOI QR Code

Comparison of Volatile Components in $\hat{O}yuk-jang$ and Commercial Sauce

어육장과 시판 소스의 휘발성 향기 성분 비교

  • Lim, Chae-Lan (Department of Food Science and Technology, Seoul Women’s University) ;
  • Lee, Jong-Mee (Department of Food and Nutritional Sciences, Ewha Womans University) ;
  • Kim, Ji-Won (Department of Food and Nutritional Sciences, Ewha Womans University) ;
  • You, Min-Jung (Department of Food and Nutritional Sciences, Ewha Womans University) ;
  • Kim, Young-Suk (Department of Food Science and Technology, Ewha Womans University) ;
  • Noh, Bong-Soo (Department of Food Science and Technology, Seoul Women’s University)
  • 임채란 (서울여자대학교식품공학과) ;
  • 이종미 (이화여자대학교식품영양학과) ;
  • 김지원 (이화여자대학교식품영양학과) ;
  • 유민정 (이화여자대학교식품영양학과) ;
  • 김영석 (이화여자대학교식품공학과) ;
  • 노봉수 (서울여자대학교식품공학과)
  • Published : 2007.09.30

Abstract

Volatile components of six commercial $sauces(A{\sim}F)$ and $\hat{O}yuk-jang$(G, H), a Korean traditional fermented sauce, were analyzed by electronic nose based on GC with surface acoustic wave(SAW) sensor. The obtained data were used for pattern recognition and a visual pattern called a $VaporPrint^{TM}$, derived from the frequency and chromatogram of the GC-SAW sensor. Volatile components of sauces and $\hat{O}yuk-jang$ were well discriminated with the direct use of $VaporPrint^{TM}$. Commercial sauces and $\hat{O}yuk-jang$ showed different volatile patterns, respectively, due to different major material, which meju, beef extract, pickled anchovies, and Katsuobushi were used. Volatile components of Oyuk-jang were decreased drastically during the fermentation time. After boiling $\hat{O}yuk-jang$, new several peaks were found. The responses by electronic nose were used for principal component analysis. The PCA plot showed that volatile components pattern were well discriminated by first principal component score(proportion: 96.8%), and first principal component score of $\hat{O}yuk-jang$ was between soy sauce of the liquid extracted from beef and sauce of pickled anchovies.

어육장과 시중 판매되는 소스의 휘발성 향기 성분들을 GC-SAW 전자코를 이용하여 분석하였다. 어육장은 담그고 1년 동안 발효${\cdot}$숙성 하면서 2개월 간격으로 액체부분만 취해서 분석하였고 숙성 1년이 지난 후에는 가열을 하였다. 소스는 주 원료가 다른 6종을 구입하여 시료로 이용하였다. 발효${\cdot}$숙성이 진행됨에 따라 어육장의 휘발성 향기 성분은 감소하였으며 숙성 후 가열 처리 한 결과 초기 머무름 시간에서 새로운 peak가 여러 개 생성 또는 증가함을 보였다. 쇠고기 추출물, 가쓰오부시, 멸치액젓이 주원료인 소스는 전자코 분석 결과 주 원료에 따라 peak의 분포와 면적의 크기가 서로 다른 패턴을 보였으며, 이는 어육장의 최종 시료와도 달랐다. 어육장과 소스의 향기 성분을 머무름 시간에 따라 주성분 분석을 하여 원료에 따른 향기 패턴에 차이가 있음을 나타내었으며 어육장은 제조 시 사용된 재료로 인하여 쇠고기와 멸치액젓이 주 원료인 소스 사이에 제 1주성분값이 나타났다. 이는 식품의 복잡하고 미묘한 향만을 객관적으로 관찰 한 것으로 향후 맛의 차이에 대한 연구도 병행되어야 할 듯 하다.

Keywords

References

  1. 빙허각(憑虛閣) 이씨(李氏), 규합총서(閨閤叢書), 1809
  2. Benjamin H, Storkson J, Tallas P.G, Pariza M.W. 1991. Inhibition of benzo(a)pyrene-induced mouse forestomach meoplasia by dietary soy sauce. Cancer Res., 51:2940-2942
  3. Benjamin H, Storkson J, Tallas P.G, Pariza M.W. 1998. Reduction of benzo(a)pyrene-induced forestomach neoplasms in mice given intrite and dietary soy sauce. Food Chem. Toxic., 26:671-678 https://doi.org/10.1016/0278-6915(88)90066-X
  4. Cho HJ, Kim SJ. 1995. A study on the contents of fatty acid and amino acid of Oyuk-jang. J. the Natural Sci., 12:119-126
  5. Cho YS, Noh BS. 2002. Quality evaluation of dried laver(Porphyra yezoensis Ueda) using electronic nose based on metal oxide sensor or GC with SAW sensor during storage. Korean. J. Food Sci. Technol., 34(6):947-953
  6. Choi KS, Choi JK, Cjung HC, Kwon KI, Im MH, Kim YH, Kim WS. 2000, Effects of mashing proportion of soybean to salt brine on kanjang(soy sauce) quality, Korean J. Food Sci. Technol., 32(1):174-180
  7. Han KY. 2006. Quality evaluation and prediction of shelf-life of food by using the electronic nose. Doctoral thesis, Seoul Women's University. pp 1-20
  8. Im MH, Choi JD, Chung HC, Lee SH, Lee CW, Choi C, Choi KS. 1998. Improvement of meju preparation method for the production of Korean traditional kanjang (soy sauce). Korean J. Food Sci. Technol., 30(3):608-614
  9. Ji WD, Lee EJ, Kim SY, Kim JK. 1992. Characteristic volatile components of traditional Korean soy sauce. J. Korean. Agric. Chem. Soc., 35(5):346-350
  10. Joo MS, Sohn KH, Park HK. 1997a. Changes in taste characteristics of traditional Korean soy sauced with ripening period(I), Korean J. Dietary Culture, 12(2):183-188
  11. Joo MS, Sohn KH, Park HK. 1997b. Changes in taste characteristics of traditional Korean soy sauced with ripening period(II), Korean J. Dietary Culture, 12(4):383-389
  12. Kim DH, Kang SW, Kim SH. 1999. Production of Korean traditional soy sauce from Phizopus stolonifer inoculated grain type meju, Korean J. Food Sci. Technol., 31(3):757- 763
  13. Kim GY, Lee KJ, Choi KH, Choi KS, Son JR, Kang S, Chang YC. 2004. Odor analysis for beef freshness estimation with electronic nose. J. of Biosystems Eng., 29(4):317-322 https://doi.org/10.5307/JBE.2004.29.4.317
  14. Kim JH, Park HJ, Kim MJ, Ahn HJ, Byun MW. 2003. Survey of biogenic amine contents in commercial soy sauce, Korean J. Food Sci. Technol., 35(2):325-328
  15. Kim JK, Chang JK, Lee BK. 1984. Statistical analysis for relationship between gas chromatographic profiles of Korean ordinary soy sauce and sensory evaluation. Korean J. Food Sci. Technol., 16(2):242-250
  16. Lee BY, Yuk JS, Oh SR, Lee HK. 2000. Aroma pattern analysis of various extracts of Agastache rugosa O. Kuntice by electronic nose. Korean J. Food Sci. Technol., 32(1):9-16
  17. Moon GS, Cheigh HS. 1987. Antioxidative characteristics of soybean sauce in lipid oxidation process. Korean J. Food Sci. Technol., 19(6):537-542
  18. Nagahara A, Nenjamin H, Storkson J. Krewson J, Sheng K, Liu W, Pariza M.W. 1992. Inhibition of benzo(a)pyrene-induced mouse forestamach meoplasia by a principal flavor component of Japanese style fermented soy sauce. Cancer Res., 52:1754-1756
  19. Noh BS, Yang YM, Lee TS, Hong HK, Kwon CH, Sung YK. 1998. Prediction of fermentation time of Korean style soybean paste by using the portable electronic nose. Korean J. Food Sci. Technol., 30(2):356-362
  20. Park HK, Sohn KH, Park OJ. 1997a. Analysis of significant factors in the flavor of traditional Korean soy sauce(I). Korean J. Dietary Culture, 12(1):53-61
  21. Park HK, Sohn KH, Park OJ. 1997b. Analysis of significant factors in the flavor of traditional Korean soy sauce(III). Korean J. Dietary Culture, 12(2):173-182
  22. Park KY, Moon SH, Baik HS, Cheigh HS. 1990. Antimutagenic Effect of Doenjang(Korean Fermented Soy Paste) toward aflatoxin. J. Korean Soc. Food Nutr., 19(2): 156-162
  23. Park KY. 1997. Stability of carcinogenesis, function of antimutation and anticancer of Korean traditional foods(Deonjang, Kimchi). Food Sci. Ind., 30(2):89-102
  24. Park OJ, Sohn KH, Park HK. 1996. Anaysis of taste compounds in traditional Korean soy sauce by two different fermentation jars, Korean J. Dietary Culture, 11(2):229-233
  25. Yoon MK, Choi A, Cho IH, Cho MS, Lee JM, Kim YS. 2007. Characterization of volatile components in Ôyuk-jang. Korean J. Food Sci. Technol. In press
  26. Youn AR, Noh BS. 2007. Analysis for cyclodextrins to entrap with hexanal using electronic nose. Korean. J. Food Sci. Technol., 39(1):1-6
  27. Youn AR. 2006. Ability of various cyclodextrin to entrap volatile beany flavor compounds in soymilk by using electronic nose. Masters degree thesis. Seoul Women's University. pp 27
  28. Zhu L, Seburg RA, Tsai E, Puech S, Mifsud J-C. 2004. Flavor analysis in a pharmaceutical oral solution formulation using an electronic-nose. J. Pharm. Biomed. Analysis, 34:453-461 https://doi.org/10.1016/S0731-7085(03)00651-4