Textile Science and Engineering (한국섬유공학회지)

The Korean Fiber Society (한국섬유공학회)
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Synthesis of Sulfadiazine Type Antibacterial Reactive Dyes

설파디아진계 항균성 반응 염료의 합성

  • Cha, Hee-Cheol (Digital Dyeing and Finishing Technology Team, Korea Institute of Industrial Technology) ;
  • Ko, Jae-Hoon (Department of Organic Materials and Fiber Engineering, Soongsil University) ;
  • Kim, Young-Ho (Department of Organic Materials and Fiber Engineering, Soongsil University)
  • 차희철 (한국생산기술연구원 디지털가공팀) ;
  • 고재훈 (숭실대학교 유기신소재.파이버공학과) ;
  • 김영호 (숭실대학교 유기신소재.파이버공학과)
  • Published : 2007.08.30
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Abstract

Novel reactive dyes having antibacterial properties were synthesized by introducing sulfase, -$NHSO_2$-, which is well known as antibiotics to reactive dyes. An intermediate compound was prepared by a coupling reaction of the diazonium salt of sulfadiazine with the condensation product of 8-amino-1-naphthol-3,6-disulfonic acid (H-acid) and cyanuric chloride. A reaction of the intermediate compound and sodium 4-aminophenyl-${\beta}$-sulfatoethyl sulphonate (p-Base) afforded a new reactive red dye of monochlorotriazine type. To synthesize reactive blue dyes of vinyl sulfone type, another intermediate compound was prepared by a coupling reaction of the diazonium salt of p-Base with H-acid, followed by the second coupling reaction of the diazonium salt of sulfadiazine or silver sulfadiazine with the intermediate compound. The synthesized dyes were characterized using a high performance liquid chromatography and various spectroscopic analyses such as UV/Vis, FT-IR, energy dispersive X-Ray, and inductively coupled plasma.

Keywords

References

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