Textile Science and Engineering (한국섬유공학회지)

The Korean Fiber Society (한국섬유공학회)
권호 표지

Synthesis of Multi-Walled Carbon Nanotubes through Functionalization with Poly(L-lysine) and Biomineralization on Carbon Nanotubes

Poly(L-lysine)로 기능화한 다중벽 탄소나노튜브의 합성과 탄소나노튜브에의 Biomineralization

  • So, Hyang-Hwa (Department of Textile Engineering, Konkuk University) ;
  • Cho, Jae-Whan (Department of Textile Engineering, Konkuk University)
  • Published : 2007.08.30
⟨ Previous Next ⟩

Abstract

Multi-walled carbon nanotubes (MWNTs) were functionalized with poly(L-lysine)(PLL) and used to prepare the silica-MWNT nanocomposites via biomineralization route in the presence of PLL by a sol-gel reaction of tetramethyl orthosilicate. The MWNT-graft-PLL (MWNT-g-PLL) could be synthesized, and it was evidenced by FT-IR spectroscopy and TEM measurement. In TEM observation, the morphology of PLL molecules covered on MWNTs was clearly shown. The formation of silica on MWNT and MWNT-PLL was carried out in two methods called as solution phase and solid phase. The presence of PLL in biomineralization affected dominantly an amount of silica formed in both solution phase and solid phase, which was evidenced in the EDS image measurements.

Keywords

References

  1. A. Hirsch, 'Functionalization of Single-walled Carbon Nanotubes', Angewandte Chemie International Edition, 2002,41, 1853-1859 https://doi.org/10.1002/1521-3773(20020603)41:11<1853::AID-ANIE1853>3.0.CO;2-N
  2. T. Saito, K. Matsushige, and K. Tanaka, 'Chemical Treatment and Modification of Multi-walled Carbon Nanotubes', Physica B: Condensed Matter, 2002, 323, 280-283 https://doi.org/10.1016/S0921-4526(02)00999-7
  3. Y. Zhang, Z. Shi, Z. Gu, and S. Ijirna, 'Structure Modification of Single-wall Carbon Nanotubes', Carbon, 2000, 38, 2055-2059 https://doi.org/10.1016/S0008-6223(00)00047-6
  4. X. L. Xie, Y. W. Mai, and X. P. Zhou, 'Dispersion and Alignment of Carbon Nanotubes in Polymer Matrix: A Review', Mat Sci Eng R: Reports, 2005, 49, 89-112 https://doi.org/10.1016/j.mser.2005.04.002
  5. B. Z. Tang and H. Xu, 'Preparation, Alignment, and Optical Properties of Soluble Poly(phenylactylene)-wrapped Carbon Nanotubes', Macromolecules, 1999, 32, 2569-2576 https://doi.org/10.1021/ma981825k
  6. D. Tasis, N. Tagmatarchis, A. Bianco, and M. Prato, 'Chemistry of Carbon Nanotubes', Chern Rev, 2006, 106, 1105-1136 https://doi.org/10.1021/cr050569o
  7. R. J. Chen, Y. Zhang, D. Wang, and H. Dai, 'Noncovalent Sidewall Functionalization of Single-walled Carbon Nanotubes for Protein Immobilization', J Am Chern Soc, 2001, 123, 3838-3839 https://doi.org/10.1021/ja010172b
  8. M. J. O'Connell, P. Bou!' L. M. Ericson, C. Huffman, Y. Wang, E. Haroz, C. Kuper, J. Tour, K. D. Ausman, and R. E. Smalley, 'Reversible Water-solubilization of Singlewalled Carbon Nanotubes by Polymer Wrapping', Chern Phys Lett, 2001, 342, 265-271 https://doi.org/10.1016/S0009-2614(01)00490-0
  9. M. Yang, V. Koutsos, and M. Zaiser, 'Interactions between Polymers and Carbon Nanotubes: A Molecular Dynamics Study', J Phys Chern B, 2005, 19, 10009-10014
  10. D. Baskaran, J. W. Mays, and M. S. Bratcher, 'Noncovalent and Nonspecific Molecular Interactions of Polymers with Multiwalled Carbon Nanotubes', Chern Mater, 2005, 17, 3389-3397 https://doi.org/10.1021/cm047866e
  11. A. Eitan, K. Jiang, D. Dukes, R. Andrews, and L. S. Schadler, 'Surface Modification of Multiwalled Carbon Nanotubes: Toward the Tailoring of Interface in Polymer Composites', Chemistry of Materials, 2003, 15, 3198-3201 https://doi.org/10.1021/cm020975d
  12. K. H. Yoon, M. B. Polk, J. H. Park, B. G. Min, and D. A. Schiraldi, 'Properties of Poly(ethylene terephthalate) Containing Epoxy-Functionalized Polyhedral Oligomeric Silsequioxane', Polymer International, 2005, 54, 47-53 https://doi.org/10.1002/pi.1661
  13. Y. Sato, T. Ogawa, K. Motomiya, K. Shinoda, B. Jeyadevan, K. Tohji, A. Kasuya, and Y. Nishina, 'Purification of MWNTs Combining Wet Grinding Hydrothermal Treatment and Oxidation', J Phys Chern B, 2001, 105, 3387-3392 https://doi.org/10.1021/jp002817k
  14. A. V. Okotrub, N. F. Yudanai, A. L. Chuvilin, J. P. Asanov, Yu, V. Shubin, L. G. Bulusheva, A. V. Guselriikov, and J. S. Fyodrov, 'Fluorinated Cage Multiwall Carbon Nanoparticles', Chern Phys Lett, 2000, 322, 231-236 https://doi.org/10.1016/S0009-2614(00)00405-X
  15. J. D. Hartgerink, E. Beniash, and S. J. Stupp, 'Self-Assembly and Mineralization of Peptide-Amphiphile Nanofibers', Science, 2001, 294, 1684-1688 https://doi.org/10.1126/science.1063187
  16. M. Kokuchi, S. Itoh, S. Ichinose, K. Shynomiya, and J. Tanaka, 'Self-Organization Mechanism in a Bone-Like Hydroxyapoatite/Collagen Nanocomposite Synthesized in Vitro and Its Biological Reaction in Vivo', Biomaterials, 2001, 22, 1705-1711 https://doi.org/10.1016/S0142-9612(00)00305-7
  17. Y. Yang, J. L. Magnay, L. Cooling, and A. 1. Elhaj, 'Development of a 'Mechano-active' Scaffold for Tissue Engineering', Biornaterials, 23, 2119-2126
  18. S. N. Park, J. C. Park, H. O. Kim, M. J. Song, and H. Suh, 'Characterization of Porous Collagen/Hyaluronic Acid Scaffold Modified by l-ethy 1-3(3-dimethylaminopropyl) Carbodiimide Crosslinking', Biornaterials, 2002, 23, 1205-1212
  19. B. Zhao, H. Hu, K. M. Swadhin, and C. Robert, 'A Bone Mimic Based on the Self-Assembly of Hydroxyapatite on Chemically Functionalized Single-Walled Carbon Nanotubes', Chern Mater, 2005, 17,3235-3241 https://doi.org/10.1021/cm0500399
  20. Y. Zang, J. Li, Y. Shen, and M. Wang, 'Poly-L-lysine Functionalization of Single-Walled Carbon Nanotubes', J Phys Chern B, 2004, 108, 15343-15346 https://doi.org/10.1021/jp0471094
  21. C. J. Brinker and G. W. Scherer, 'Sol-Gel Science', Academic Press, 1990
  22. E. Pope, S. Sakka, and L. Klein, 'Sol-Gel Science and Technology', Am Ceramic Soc, 1995, 55, 299-306
  23. J. O. Park, 'Organic-Inorganic Polymer Hybrids by Sol-Gel Process', Polym Sci Technol, 1997,8,261-268
  24. S. H. Lee and J. W. Cho, 'Influence of Silica on Shape Memory Effect and Mechanical Properties of PoJyurethanesilica Hybrids', Eur Polym J, 2004,40, 1343-1348 https://doi.org/10.1016/j.eurpolymj.2004.01.041
  25. D. M. Shin, K. H. Yoon, O. H. Kwon, B. G. Min, and C. J. Hwang, 'Surface Resistivity and Rheological Behaviour of Carboxylated Multiwall Carbon Nanoutbe-filled PET Composite Film', J Appl Polym Sci, 2006, 99, 900-904 https://doi.org/10.1002/app.21982
  26. Y. Qin, J. Shi, W. Wu, X. Li, Z. X. Guo, and D. Zhu, 'Concise Route to Functionalized Carbon Nanotubes', J Phys Chern B, 2003, 107, 12899-12901 https://doi.org/10.1021/jp036512s
  27. M. Muller, R. Buchet, and U. P. Fringeli, '2D-FTIR ATR Spectroscopy of Thermo-Induced Periodic Secondary Structural Changes of Poly-(I)-lysine: A Cross-Correlation Analysis of Phase-Resolved Temperature Modulation Spectra', J Phys Chern, 1996, 100, 10810-10825 https://doi.org/10.1021/jp9602843
  28. K. Nitinai and B. Virote, 'Suppression of Arsenopyrite Surface Oxidation by Sol-Gel Coatings', J Biosci Bioeng, 2005, 3, 277-284
  29. T. Akasaka, F. Watari, Y. Sato, and K. Tohji, 'Apatite Formation on Carbon Nanotubes', Mat Sci Eng C, 2006, 26, 675-678 https://doi.org/10.1016/j.msec.2005.03.009