DOI QR코드

DOI QR Code

Photoluminescence Characteristics of ZnO Nano Needle-like Rods grown by the Hot Wall Epitaxy Method

  • Published : 2007.10.31

Abstract

We investigated photoluminescence characteristics of ZnO nano needle-like rods grown on a c-plane $AL_2O_3$ substrate by the hot wall epitaxy method. The nano-rods were vertically well aligned along the ZnO c-axis. The diameters of the ZnO nano-rods ranged from 20 nm to 30 nm and their lengths were between 600 and 700 nm. In the photoluminescence spectrum at 10 K, the exciton emission bound to the neutral donor dominated while defect related emission was weakly observed. With a further increase of temperature, the free exciton emission appeared and eventually became dominant at room temperature.

Keywords

References

  1. D. C. Look, 'Recent advances in ZnO materials and devices', Mater. Sci. Eng., Vol. B 80, p. 383, 2001
  2. P. Zu, Z. K. Tang, G. K. L. Wong, M. Kawasaki, A. Ohtomo, H. Koinuma, and Y. Segawa, 'Ultraviolet spontaneous and stimulated emissions from ZnO micro crystallite thin films at room temperature', Solid-State Commun., Vol. 103, p. 459, 1997
  3. D. M. Bagnall, Y. R. Chen, Z. Zhu, T. Yao, S. Koyama, M. Y. Shen, and T. Goto, 'Optically pumped lasing of ZnO at room temperature', Appl. Phys. Lett., Vol. 70, p. 2230, 1997
  4. D.-I. Suh, S.-K. Lee, and B.-G. Ahn, 'Synthesis and characterization of branched-structure ZnO nanowires grown by using a two-step seeding method', Sae Mulli(The Korean Physical Society), Vol. 54, No.4, p. 351, 2007
  5. H.-J. Jin, S.-J. So, and C.-B. Park, 'Defect analysis via photoluminescence of p-type ZnO:N thin film fabricated by RF magnetron sputtering', J. of KlEEME(in Korean), Vol. 20, No.3. p. 202, 2007 https://doi.org/10.4313/JKEM.2007.20.3.202
  6. E. S. Shim, H. S. Kang, J. S. Kang, S. S. Pang, and S. Y. Lee, 'p-n heterojunction composed of n-ZnO/p-Zn-doped InP', Trans. EEM, Vol. 3, No.1, p. 1, 2002
  7. B. H. Kong, T. E. Park, and H. K. Cho, 'Shape control and characterization of one-dimensional ZnO nanostructures through the synthesis procedure', J. of KlEEME(in Korean), Vol. 19, No. 1. p. 13, 2006 https://doi.org/10.4313/JKEM.2006.19.1.013
  8. Y. G. Wang, S. P. Lau, H. W. Lee, S. F. Yu, B. K. Tay, X. H. Zhang, and H. H. Hng, 'Photoluminescence study of ZnO films prepared by thermal oxidation of Zn metallic films in air', J. Appl. Phys., Vol. 94, p. 354, 2003
  9. D. B. Yang, Y. F. Chan, and N. Wang, 'Formation of ZnO nanostructures by a simple way of thermal evaporation', Appl. Phys, Lett., Vol. 81, p. 757, 2002 https://doi.org/10.1063/1.1507611
  10. K. Ogata, T. Kawanishi, K. Maejima, K. Sakurai, S. Fujita, and S. Fujita, 'Improvements of ZnO qualities grown by metal-organic vapor phase epitaxy using a molecular beam epitaxy grown ZnO layer as a substrate', Jpn. J. Appl. Phys., Vol. 40, p. L657, 2001
  11. A. Lopez-Otero, 'Hot-wall epitaxy', Thin Solid Films, Vol. 49, No.1, p. 3, 1978
  12. H. Yuan and Y. Zhang, 'Preparation of wellaligned ZnO whiskers on glass substrate by atmospheric MOCVD', J. Cryst. Growth, Vol. 263, p. 119, 2004 https://doi.org/10.1016/j.jcrysgro.2003.11.084
  13. Y. Sun, G. M. Fuge, and M. N. R. Ashfold, 'Growth of aligned ZnO nanorod arrays by catalyst-free pulsed laser deposition methods', Chem. Phys. Lett., Vol. 396, p. 21, 2004 https://doi.org/10.1016/j.cplett.2004.07.110
  14. R. A. Laudise, E. D. Kolb, and A. J. Caporaso, 'Hydrothermal growth of large sound crystals of zinc oxide', J. Am. Ceram. Soc., Vol. 47, p. 9, 1964
  15. W. I. Park, G.-C. Yi, M. Kim, and S. J. Pennycook, 'ZnO nanoneedles grown vertically on Si substrates by non-catalytic vapor-phase epitaxy', Adv. Mater., Vol. 14, p. 1841, 2002
  16. M. H. Huang, Y. Wu, H. Feick, N. Tran, E. Weber, and P. Yang, 'Catalytic growth of Zinc Oxide nanowires by vapor transport', Adv. Mater., Vol. 13, p. 113, 2001
  17. B. D. Yao, Y. F. Chan, and N. Wang, 'Formation of ZnO nanostructures by a simple way of thermal evaporation', Appl. Phys. Lett., Vol. 81, p. 757, 2002 https://doi.org/10.1063/1.1507611
  18. Y. P. Varshni, 'Temperature dependence of the energy gap in semiconductors', Physica, Vol. 34, p. 149, 1967
  19. D. W. Hamby, D. A. Lucca, M. J. Klopfstein, and G. Cantwell, 'Temperature dependent exciton photoluminescence of bulk ZnO', J. Appl. Phys., Vol. 93, p. 3214, 2003 https://doi.org/10.1063/1.1545157