Journal of environmental and Sanitary engineering (환경위생공학)

Korean Society for Environmental Sanitary Engineers (대한환경위생공학회)
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Annual Cycle of PCBs Concentration in the Atmosphere

  • Kang, Byung-Wook (Division of Environmental Engineering, Chungju National University) ;
  • Shin, Eun-Sang (Department of Environmental Health, DongNam Health College) ;
  • Yeo, Hyun-Gu (Technical Support Department, Gangwon Regional Small and Medium Business Administration)
  • Published : 2007.06.30
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Abstract

PCBs의 대기 중 농도는 고용량 PUF sampler를 이용하여 2000년부터 2002년까지 주 1회 수도권 인근지역인 경기도 안성에서 측정하였다. 본 논문은 비선형 회귀모델을 이용하여 대기 중 가스상 PCBs의 연간, 월간 사이클을 평가 하고자 한다. Clausius-Clepeyron 식을 이용한 가스상 PCBs의 기울기는 고분자로 갈수록 증가하는 경향이었다. 이는 고분자 PCBs는 저분자 PCBs에 비해 온도 의존성이 크다는 것을 의미한다. 다시 말해, 고분자 PCBs는 다른 지역에서 장거리 이송되어 오는 오염물질의 영향 보다는 지역적인 오염원(예, 토양, 수계 등)에 의해 영향을 크게 받고 있다는 것을 시사한다. Lorentzian 모델을 이용한 총 PCBs의 일별, 월별 회귀식의 결정계수($R^2$)는 각각 0.62(p<0.0001), 0.88(p<0.0001)로 나타나 유의한 결과를 보였다. 또한, 비선형 회귀식 모델을 활용하여 구한 가스상 PCBs의 일별, 월별 싸이클을 모사한 방정식도 매우 유의한 결과(p<0.0001)를 나타내었다.

Keywords

References

  1. Vallack, H. W., Bakker, D. J., Brandt, I., Brostrom-Lunden, Bruwer, A., Bull, K. R., Gough, C., Guardans, R., Holoubek, I., J, Jansson, B., Koch, R., Kuylenstierna, J., Lecloux, A., Mackay, D., McCutcheon, P., Mocarelli, P., and Taalman, R. D. F. : Controlling persistent organic pollutants what next, Environ. Toxicol. Pharamacol., 6, 143-175, 1998 https://doi.org/10.1016/S1382-6689(98)00036-2
  2. Allsopp, M., Santillo, D., Johnston, P., and Stringer, R. : The tip of the iceberg. In: State of Knowledge on Persistent Organic Pollutants in Europe and the Arctic, Greenpeace, Amsterdam, 1999
  3. UN-ECE : Protocol to the 1979 convention on long range transboundary air pollution on persistent organic pollutions and executive body decision 1998/2 on information to be submitted and the procedure for adding substances to annexes I, II, or III to the procedure on persistent organic pollutants, ECE/EB.AIR/60, United Nation, New York and Geneva, 1998
  4. Manchester-Neesvig, J. B., Andren, A. W. Seasonal Variation in the Atmosphere Concentration of Polychlorinated Biphenyls congeners, Environ. Sci. Technol., 23, 1138-1148, 1989 https://doi.org/10.1021/es00067a012
  5. Hoff, R. M., Muir, D. C. G., and Grift, N. P. : Annual Cycle of Polychlorinated Biphenyls and Organohalogen Pesticides in Air in Southern Ontario 2. Atmospheric Transport and Sources, Environ. Sci. Technol., 26, 276-283, 1992 https://doi.org/10.1021/es00026a006
  6. Halsall, C. J., Lee, R. G. M., Coleman, P. J., Burnett, V., P., and Jones, K. C. : PCBs in UK Urban Air, Environ. Sci. Technol., 29, 2368-2376, 1995 https://doi.org/10.1021/es00009a032
  7. Bugoyne, T. W. and Hites, R. A. : Effects of Temperature and Wind Direction on the Atrmspheric Concentrations of ${\alpha}$-Endosulfan, Environ. Sci. Technol., 27, 910-914, 1993 https://doi.org/10.1021/es00042a013
  8. Bidleman, T. F. and Olney, C. E. : Long-range Transport of Toxaphene Insecticide in the Atmosphere of the Western North Atlantic, Nature, 257, 475-477, 1975 https://doi.org/10.1038/257475a0
  9. Oehem, M and Ottar, B. The Long-range Transport of Polychlorinated Hydrocarbons to the Arctic, Geophysical Research Letters, 11, 1133-1136, 1984 https://doi.org/10.1029/GL011i011p01133
  10. Larsson, P. and Okla, L. : Atmospheric Transport of Chlorinated Hydrocarbons to Sweden in 1985 Compared to 1973, Atmospheric Environment, 23, 1699-1711, 1989 https://doi.org/10.1016/0004-6981(89)90055-3
  11. Lee, R. G. M., Hung, H., Mackay, D., Jones, K. C. : Environ. Sci. Technol., 32, 172-2179, 1998 https://doi.org/10.1021/es983446c
  12. Wania, F., Haugen, J. E., Lei, Y. D., and Mackay, D. : Temperature Dependence of Atrmspheric Concentration of Semivolatile Organic Compounds, Environ. Sci. Technol., 32, 1013-1021, 1998 https://doi.org/10.1021/es970856c
  13. Strachan, W. M. I., and Eisenreich, S. I. : Mass Balance of Toxic Chemicals in the Greak Lakes: the Role of Atmospheric Deposition: International Joint Commission: Windsor, Ontario, 1-113, 1988
  14. Falconer, R. L. and Harner, T. : Comparison of the octanol-air partition coefficient and liquid-phase vapor pressure as descriptors for particle/gas partitioning using laboratory and field data for PCBs and PCNs, Atmospheric Environment, 34, 4043-4046, 2000 https://doi.org/10.1016/S1352-2310(00)00164-3
  15. Welsch-Pausch, K., McLachlan, M. S., and Umlauf, G. : Determination of the Principal Pathways of Polychlorinated Dibenzo-p-Dioxins and Dibenzofurans to Lolium Muliflorum (Welsh Rye grass), Environ. Sci. Technol., 29, 1090-1098, 1995 https://doi.org/10.1021/es00004a031
  16. McDow, S. R., Huntzicker, J. J. : Effect of Composition and State of Organic Compounds on Polycyclic Aromatic Hydrocarbons Decay in Atmosphere Aerosols, Atmospheric Environment, 24, 2563-2572, 1990 https://doi.org/10.1016/0960-1686(90)90134-9
  17. Hart, K. M., Isabelle, L. M., Pankow, J. F. : High-Volume Air Sampler for Particle and Gas Sampling. 1. Design and Gas Sampling Performance, Environ. Sci. Technol., 26. 1048-1052, 1992 https://doi.org/10.1021/es00029a027
  18. Hart, K. M., Pankow, J. F. : High-Volume AirSampler for Particle and Gas Sampling. 2. Use of Backup Filter to Correct for the Adsorption of Gas-Phase Polycyclic Aromatic Hydrocarbons to the Front Filter, Environ. Sci. Technol., 28. 655-661, 1994 https://doi.org/10.1021/es00053a019
  19. Katz, M., Chan, C. : Comparative distribution of eight polycyclic aromatic hydrocarbons in airborne particulates collected by conventic:nal high-volume sampling and by size fractionation, Environ. Sci. Technol., 14. 838-843, 1980 https://doi.org/10.1021/es60167a010
  20. Zhang, X., McMurry, P. H. : Theoretical Analysis of Evaporative Losses of Adsorbed of Absorbed Species during Atmospheric Aerosol Sampling, Environ. Sci. Technol., 25, 456-459, 1991 https://doi.org/10.1021/es00015a012
  21. Simcik, M. F., Zhang, H., Franz, Th. P., Eisenreich, St. J. : Gas-Particle Partitioning of PCBs and PAHs in the Chicago Urban and Adjacent Coastal Atmosphere: State of Equilibrium, Environ. Sci. Technol., 32, 251-257, 1998 https://doi.org/10.1021/es970557n