Electrolyte Effect on the Particle Characteristics Prepared by Soap-Free Emulsion Polymerization

  • Han, Seung-Tak (Department of Chemical Engineering, Inha University) ;
  • Lee, Kang-Seok (Department of Chemical Engineering, Inha University) ;
  • Shim, Sang-Eun (Department of Chemical Engineering, Inha University) ;
  • Saikia, Prakash J. (Department of Chemical Engineering, Inha University) ;
  • Choe, Soon-Ja (Department of Chemical Engineering, Inha University) ;
  • Cheong, In-Woo (Department of Applied Chemistry, Kyungpook National University)
  • Published : 2007.08.31

Abstract

Monodisperse micron-sized polystyrene (PS) spheres were successfully obtained using a single stage soap-free emulsion method in aqueous media mixed with ethanol (co-solvent) containing NaCI as the electrolyte. The optimum conditions for preparing the monodisperse PS microspheres, using soap-free emulsion polymerization in a water/ethanol mixture with an electrolyte, were studied. The presence of the co-solvent and electrolyte controlled the particle dispersion stability during the polymerization. The microspheres formed using PS, with a weight-average diameter of $2.6{\mu}m$, coefficient of variation of 5.3% and zeta potential of -15.1 eV, were successfully obtained in the presence of 0.1 wt% NaCI, 10 wt% monomer, 0.1 wt% initiator and 95/5 (g/g) of a water/ethanol mixture reacted at $70^{\circ}C$ for 24 h.

Keywords

References

  1. J. Ugelstad, J. Polym. Sci., Polym. Symp., 72, 225 (1985)
  2. K. O. Christopher, J. Polym. Sci., Polym. Lett. Ed., 23, 103 (1985) https://doi.org/10.1002/pol.1985.130230209
  3. K. P. Lok and C. K. Ober, Can. J. Chem., 63, 209 (1985)
  4. J. G. Park, J. W. Kim, S. G. Oh, and K. D. Suh, J. Appl. Polym. Sci., 87, 420 (2003) https://doi.org/10.1002/app.11656
  5. T. Isao, Y. Yutaka, N. Atsuo, and G. Yasushi, US Patent, 5,001,542 (1991)
  6. Y. Almong, S. Reich, and M. Levy, Br. Polym. J., 14, 131 (1982) https://doi.org/10.1002/pi.4980140103
  7. C. K. Ober, K. P. Lok, and M. L. Hair, J. Polym. Sci., Polym. Lett. Ed., 23, 103 (1985) https://doi.org/10.1002/pol.1985.130230209
  8. M. Okubo, M. Shiozaki, M. Tsujihiro, and Y. Tsukada, Colloid Polym. Sci., 269, 222 (1991)
  9. J. Ugelstad, K. H. Kaggerud, F. K. Hansen, and A. Berge, Makromol. Chem., 180, 737 (1979)
  10. S. Gu and M. Konno, J. Chem. Eng. Japan, 30, 742 (1997)
  11. J. H. Kim, M. Chainey, M. S. El-Aasser, and J. W. Vanderhoff, J. Polym. Sci., Polym. Chem., Ed., 30, 171 (1992)
  12. T. D. S. Grant, G. A. Vandezande, and A. Rudin, Eur. Polym. J., 30, 179 (1994)
  13. M. Konno, Y. Terunuma, and S. Saito, J. Chem. Eng. Japan, 24, 429 (1991)
  14. Z. Song and G. W. Poehlein, J. Polym. Sci., Polym. Chem. Ed., 28, 2359 (1990)
  15. A. M. Homola, M. Inoue, and A. A. Robertson, J. Appl. Polym. Sci., 19, 3077 (1975)
  16. S. Gu, T. Mogi, and K. Konno, J. Colloid Interf. Sci., 207, 113 (1998)
  17. S. Gu, T. Mogi, and K. Konno, Colloid Surf. A, 153, 209 (1999)
  18. J. Zhang, Z. Chen, Z. Wang, W. Zhang, and N. Ming, Mater. Lett., 57, 4466 (2003)
  19. S. E. Shim, Y. J. Cha, J. M. Byun, and S. Choe, J. Appl. Polym. Sci., 71, 2259 (1999) https://doi.org/10.1002/(SICI)1097-4628(19990207)71:6<999::AID-APP15>3.0.CO;2-C
  20. A. Klein, C. H. Kuist, and V. T. J. Stannett, Polym. Sci., Polym. Chem. Ed., 11, 2111 (1978)
  21. J. W. Goodwin, R. H. Ottewill, R. Pelton, G. Vianello, and D. E. Tates, Br. Polym. J., 10, 137 (1978) https://doi.org/10.1002/pi.4980100208
  22. A. M. Homola, M. Inoue, and A. A. Robertson, J. Appl. Polym. Sci., 19, 3077 (1975)
  23. Z. Liu and H. Xiao, Polymer, 41, 7023 (2003)
  24. K. P. Lok and C. K. Ober, Can. J. Chem., 63, 209 (1985)
  25. A. B. Moustafa and A. Abdel-hakim, J. Appl. Polym. Sci., 66, 711 (1997)
  26. A. S. Dunn and Z. F. M. Said, Polymer, 23, 1172 (1982)