Abstract
In this study, terpolymer of vinylidene fluoride (VDF), trifluoroethylene (TrFE), and chlorotrifluoroethylene (CTFE) were prepared by suspension polymerization using di-tertiary-butyl peroxide (DTBP) as an initiator. The structural characteristics including microstructure and chain conformation of the polymers have been carefully elucidated as a function of the chemical composition using NMR, FT-IR. The intensity of absorption bands of the $\beta$-phase gradually decreases and the $\gamma$-phase increases with the increment of CTFE mol%. The analysis results of DSC shows that the Curie phase transition temperature ($T_c$) of the terpolymer gradually shifts to ambient temperature and trace becomes smaller and broader with the increment of CTFE mol%. Also, activation energies of the samples were calculated by Freeman-Carroll method.
이 논문에서는 vinylidene fluoride(VDF), trifluoroethylene(TrFE), chlorotrifluoroethylene(CTFE)을 사용하여 3성분계 고분자를 합성하였으며, 저온 개시제 di-tertiary-butylperoxide(DTBP)를 사용하여 현탁중합하였다. NMR, FT-IR을 통해 3성분계 고분자 사슬의 미세구조, 사슬형태의 변화에 대해 알 수 있었다. CTFE mol%가 증가할수록 $\beta$ 상태는 점차적으로 감소하고 $\gamma$ 상태는 증가하는 것을 알 수 있었다. DSC 분석결과, CTFE mol%가 증가할수록 상전이 온도($T_c$)는 상온으로 낮아지며 그 곡선은 점차 작아지고 넓게 퍼지는 현상을 확인하였다. 활성화 에너지는 Freeman-Carroll법에 의해 계산되었다.