Journal of the Korean Wood Science and Technology

The Korean Society of Wood Science & Technology (한국목재공학회)
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Phenolic Compounds from the Inner Bark of Paulownia coreana

  • Si, Chuan-Ling (College of Material Science and Chemical Engineering, Tianjin University of Science and Technology) ;
  • Bae, Young-Soo (College of Forest Sciences, Kangwon National University)
  • Received : 2007.07.03
  • Accepted : 2007.08.01
  • Published : 2007.09.25
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Abstract

Paulownia coreana inner bark was collected, extracted in 70% acetone, concentrated under reduced pressure and sequentially fractionated using n-hexane, $CH_2Cl_2$, EtOAc and $H_2O$, then freeze dried to give brown powders. A portion of the EtOAc soluble powder was chromatographed on a Sephadex LH-20 column using a serious of aqueous methanol and ethanol-hexane mixture as eluting solvents. Two phenolic acid, $\rho$-courmaric acid and caffeic acid, two isomeric phenylethanoid glycosides, verbascoside and iso-verbascoside, and one epimeric phenylpropanoid glycoside, cistanoside F, were isolated and their structures were elucidated by spectroscopic analysis such as NMR and MS.

Keywords

References

  1. Ayan, S., I. Sadlam, and A. Sivaciodlu. 2003. Paulownia Sieb.&Zucc: A new exotic genus for multi-purpose uses in Kastaonu-Turkey, Decision support for multiple purpose forestry (April 23 -25, Vienna-Austria)
  2. Han, P., Y. J. Cui, H. Z. Guo, and D. A. Guo. 2004. Chemical constituents of Buddlejae officinalis and their bioactivities. Chinese Traditional and Herbal Drugs. 35(10): 1086-1990
  3. Harborne, J. B. and T. J. Mabry. 1982. The f1avonoids: advances in research, Chapman and Hall Ltd., London, UK. p. 35-37
  4. Jiangsu New Medical College. 1977. The Chinese Medicine Dictionary. Shanghai People's Publishing House. p. 1456
  5. Kim, T. J. 1996. Korean resources plants (IV), Seoul National University Press. pp. 76-77
  6. Kobayashi, H., H. Karasawa, T. Miyase, and S. Fukushima. 1985. Studies on the constituents of cistanchis herba. V. Isolation and structures of two new phenylpropanoid glycosides, cistano-sides E and F. Chem. Pharm. Bull. 33(4): 1452-1457 https://doi.org/10.1248/cpb.33.1452
  7. Li, Y. M., S. H. Jiang, W. Y. Gao, and D. Y. Zhu. 2000. Phenylpropanoid glycosides from Scrophularia ningpoensis. Phytochemstry. 54: 923-925 https://doi.org/10.1016/S0031-9422(00)00171-0
  8. Nishibe, S., M. Sasahara, J. Ying, Y. C. Lu, and T. Tanaka. 1993. Phenylethanoid glycosides from Plantago depressa. Phytochemistry. 32: 975-977 https://doi.org/10.1016/0031-9422(93)85238-M
  9. Otsuka, H., N. Kashima, T. Hayashi, N. Kubo, K. Yamasaki, and W. G. Padolina. 1992. Premnaodorosides A, Band C, iridoid glucoside diesters of an acyclic monoterpenediol from leaves of Premna odorata. Phytochemistry. 31: 3129-3133 https://doi.org/10.1016/0031-9422(92)83459-C
  10. Si, C. L., J. K. Kim, D. J. Kwon, and Y. S. Bae. 2005. Phenolic compounds from the leaves of Paulownia coreana Uyeki. J. For. Sci., Kangwon Nat'l Univ. 21: 16-23
  11. Si, C. L., J. K. Kim, D. J. Kwon, and Y. S. Bae. 2006a. Phenylpropanoid glycosides of Paulownia coreana Uyeki. Mokchae Konghak. 34(2): 78-82
  12. Si, C. L., J. K. Kim, D. J. Kwon, and Y. S. Bae. 2006b. Phenolic compounds from the fruits of Paulownia coreana Uyeki. Mokchae Konghak. 34(1): 79-85
  13. Wu, J., J. S. Huang, Q. Xiao, S. Zhang, Z. H. Xiao, Q. X. Li, L. J. Long, and L. M. Huang. 2004. Spectral assignments and reference data: Complete assignments of $^1H$ and $^{13}C$ NMR data for 10 phenyphenylethanoid glycosides. Magnetic Resonance in Chemistry. 42: 659-662 https://doi.org/10.1002/mrc.1393