Alkali-Swollen Morphology of Native Cellulose Fibers

  • Kim, Nam-Hun (Dept. of Wood Science & Engineering, College of Forest Sciences, Kangwon National University)
  • Received : 2006.06.08
  • Accepted : 2006.07.13
  • Published : 2007.03.25

Abstract

The behavior of ramie fibers and some wood elements in the early stage of alkali swelling was examined. When the fibers were treated with alkali solution, they significantly shrank in length and swelled in wall thickness. Ramie fibers showed a shrinkage averaging 23% in length and a swelling averaging 92% in width in 100 seconds treating time. Dimensional changes showed different fashion in each element of woods. The tracheids of latewood especially in Pinus densiflora and Larix kaempferi woods swelled intensively and showed balloon swelling, but in the case of Cryptomeria japonica, it was hardly observed. The swelling morphology of libriform fibers was similar to that of tracheids. The walls of vessel elements and parenchyma cells also swelled considerably in thickness but, no balloon swelling was found in both elements. The differences of swelling in different elements can be interpreted in terms of the differences of organization and/or chemical components of the cell walls.

Keywords

References

  1. Baily, I. W. and T. Kerr . 1935. The visib le structure of the secondary wall and its significance in physic al and chem ical investigat ions of tracheary cells and fibers. Journal of the Arnold Arboretum 16(3): 273-300 (with plates 140-149)
  2. Dinand, E., M. Vignon, H. Channzy , and L. Heux . 2002. Mercerization of prim ary wall cellulose and its imp licat ion for conversion of ce llulose 1 $\rightarrow$ cellulose II. Cellulose 9: 7-18 https://doi.org/10.1023/A:1015877021688
  3. Hosoi , H., K. Katahara, and N. Migita . 1958. Researches on the swell ing of fibers. III. Mokuzai Gakkaishi 4(2): 60-6 6
  4. Kim, N. H. 2005. An investigation of mercerization in decayed oak wood by a white rot fungus (Lentinula edodes). Journal of Wood Science 51: 290-29 https://doi.org/10.1007/s10086-004-0650-2
  5. Kim, N. H. and D. Y. Kim. 2003. Mercerizarion of wood: Formation and reversibility of Na-cellulose I in reaction wood. Mokchae Konghak 31(6): 1-7
  6. Kim, N. H., J. Sugiyama, and T. Okano. 1989. The beha vior of cellu lose fiber s in the early stage of alkalineswelling. Mokuzai Gakkaishi Vol. 35(5): 387-391
  7. Kolpak , F. J. and J. Blackwell. 1978 . Mercerization of cellulose: 2. The morphology of merceriz ed cotton cellulose. Polymer 19: 132-135 https://doi.org/10.1016/0032-3861(78)90028-9
  8. Nishiyama, Y. and T. Okano. 1998. Morphological changes of ramie fiber during mercerization. Journal of Wood Science 44 : 310-313 https://doi.org/10.1007/BF00581312
  9. Nishiyama , Y., S. Kuga, and T. Okano. 2000. Mechanism of mercerization revealed by X-ray diffraction. Journal of Wood Science 46: 452-457 https://doi.org/10.1007/BF00765803
  10. Revol , J. F. and D. A. I. Goring. 1981. On the mechanism of the mercerization of cellulose in wood. Journal of Applied Polymer Science 26: 1275-1282 https://doi.org/10.1002/app.1981.070260419
  11. Rollins M. L. and V. W. Tripp. 1954. Optical and electron microscopic studies of cotton fiber structure. Textile Research Journal 24 : 345-357 https://doi.org/10.1177/004051755402400407
  12. Saito, G. 1939. Das verhalten der zellulose in alkalilosungen, Kolloid-Beihefte 49 : 365-453
  13. Wardrop, A. B. and H. E. Dadswell. 1950. The swelling behavior of conifer tracheids and the concept of a skin substance . Australian Pulp and Paper Industry Technical Association Proceedings 4: 198-221
  14. Warwicker, J. O. 1971. Swelling. Cellulose and cellulose derivatives. Bikales, N. M. and L. Segal, eds., Wiley and Sons Inc .: 325-379
  15. Warwicker, J. O ., R. Jeffries, R. L. Colbran, and R. N. Robinson. 1966. A review of the literature on the effect of caustic soda and oth er swelling agent s on the fine structure of cotton. Shirley Institute Pamphlet No.93. St Ann's Press: 55-70
  16. Zeronian, S. H. 1985. Intracrystalline swelling of cellulose . Cellulose Cehmistry and Its Applications. Nevell, T. P. and Zeronian, S. H., eds. Ellis Horwood Ltd .: 159-180