Korean Journal of Crystallography (한국결정학회지)

Korean Crystallographic Association (한국결정학회)
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Two-dimensional Cu Coordination Polymer: [$Cu_2Cl_2$(4,4'-dipyen)]

2차원 구리 배위 고분자: [$Cu_2Cl_2$(4,4'-dipyen)]

  • Huh, Hyun-Sue (Department of Chemistry (BK21), Sungkyunkwan University, Natural Science Campus) ;
  • Lee, Soon-W. (Department of Chemistry (BK21), Sungkyunkwan University, Natural Science Campus)
  • Published : 2007.12.31
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Abstract

Under hydrothermal conditions, a 2-dimensional copper(I) coordination polymer [$Cu_2Cl_2$(4,4'-dipyen)] (1) was prepared from [$Cu(OAc)_2]{\cdot}H_2O$, 4,4'-dipyen, and KCl. In polymer 1, copper atoms are linked by the 4,4'-dipyen ligands approximately along the b-axis and are also linked by the chloro ligands approximately along the a-axis to form a 2-D layer, a network of rectangles.

수열 반응 조건 하에서, [$Cu(OAc)_2]{\cdot}H_2O$, 4,4-dipyen, 그리고 KCl로부터 2차원 구리 배위 고분자 [$Cu_2Cl_2$(4,4'-dipyen)] (1)이 합성되었다. 고분자 1 내에서, 구리 원자들이 4,4-dipyen 리간드들로 대략 b-축 방향으로 연결되고, 또한 Cl 리간드들로 대략 a-축 방향으로 연결되어 직사각형 그물 망 형태의 2차원 층이 형성된다.

Keywords

References

  1. Swiergers, G. F. and Malefetse, T. J., Chem. Rev., 100, 3483 (2000) https://doi.org/10.1021/cr990110s
  2. Moulton, B. and Zaworotko, M. J., Chem. Rev., 101, 1629 (2001) https://doi.org/10.1021/cr9900432
  3. Eddaoudi, M., Moler, D. B., Li, H., Chen, B., Reineke, T. M., O'Keeffe, M. and Yaghi, O. M., Acc. Chem. Res., 319, 34 (2001)
  4. Eddaoudi, M., Kim, J., Rosi, N., Vodak, D., Wachter, J., O'Keeffe, M. and Yaghi, O. M., Science, 295, 469 (2002) https://doi.org/10.1126/science.1067208
  5. Janiak, C., Dalton Trans., 2781 (2003)
  6. Kesanli, B. and Lin, W., Coord. Chem. Rev., 246, 305 (2003) https://doi.org/10.1016/j.cct.2003.08.004
  7. Barnett, S. A. and Chanmpness, N. R., Coord. Chem. Rev., 246, 145 (2003) https://doi.org/10.1016/S0010-8545(03)00121-8
  8. Rowsell, J. L. C. and Yaghi, O. M., Micropor. Mesopor. Mater., 73, 3 (2004) https://doi.org/10.1016/j.micromeso.2004.03.034
  9. Ockwig, N. W., Friedrichs, O. D., O'Keeffe, M. and Yaghi, O. M., Acc. Chem. Res., 38, 176 (2005) https://doi.org/10.1021/ar020022l
  10. Robin, A. Y. and Fromm, K. M., Coord. Chem. Rev., 250, 2127 (2006) https://doi.org/10.1016/j.ccr.2006.02.013
  11. Chae, H. K., Kim, J., Friedrichs, O. D., O'Keeffe, M. and Yaghi, O. M., Angew. Chem. Int. Ed., 42, 3907 (2003) https://doi.org/10.1002/anie.200351546
  12. Chae, H. K., Siverio-Perez, D. Y., Kim, J., Go, Y. B., Eddaoudi, M., Matzger, A. J., O'Keeffe, M. and O. M., Yaghi, Nature, 427, 523 (2004)
  13. Chen, B., Ockwig, N. W., Fronczek, F. R., Contreas, D. S. and Yaghi, O. M., Inorg. Chem., 44, 181 (2005) https://doi.org/10.1021/ic048612y
  14. Rosi, N. L., Kim, J., Eddaoudi, M., Chen, B., O'Keeffe, M. and Yaghi, O. M., J. Am. Chem. Soc., 127, 1504 (2005) https://doi.org/10.1021/ja045123o
  15. Sudik, A. C., Millward, A. R., Ockwig, N. W., Cote, A. P., Kim, J. and Yaghi, O. M., J. Am. Chem. Soc., 127, 7110 (2005) https://doi.org/10.1021/ja042802q
  16. Baeg, J.-Y. and Lee, S. W., Inorg. Chem. Commun., 6, 313 (2003)
  17. Lee, Y. K. and Lee, S. W., Bull. Korean Chem. Soc., 24, 7 (2003)
  18. Kim, H. J., Lee, Y. K., Park, K., Son, J. H., Kwon, Y.-U. and Lee, S. W., Inorg. Chim. Acta, 353, 151 (2003)
  19. Lee, H. K., Min, D., Cho, B.-Y. and Lee, S. W., Bull. Korean Chem. Soc., 25, 1955 (2004)
  20. Choi, E.-Y., Park, K., Yang, C.-M., Kim, H. J., Son, J.-H., Lee, S. W., Lee, Y. H., Min, D. and Kwon, Y.-U., Chem. Eur. J., 10, 5535 (2004)
  21. Dong, Y.-B., Smith, M. D. and zur Loye, H.-C., Inorg. Chem., 39, 4927 (2000)
  22. Hou, H., Fan, Y., Zhang, L., Du, C. and Zhu, Y., Inorg. Chem. Commun., 4, 168 (2001) https://doi.org/10.1016/S1387-7003(01)00150-2
  23. Curtin, D. M., Dong, Y.-B., Smith, M. D., Barclay, T. and zur Loye, H.-C., Inorg. Chem., 40, 2825 (2001)
  24. Zaman, M. B., Smith, M. D. and zur Loye, H.-C., Chem. Mater., 13, 3534 (2001)
  25. Patra, G. K. and Goldberg, I., J. Chem. Soc., Dalton Trans., 1051 (2002)
  26. Huang, Z., Song, H.-B., Du, M., Chen, S.-T. and Bu, X.-H., Inorg. Chem., 43, 931 (2004)
  27. Gong, Y.-Q., Wang, R.-H., Zhou, Y.-F., Lin, Z.-Z. and Hong, M.-C., J. Mol. Struct., 751, 121 (2005)
  28. Chen, C.-L., Goforth, A. M., Smith, M. D., Su, C.-Y. and zur Loye, H.-C., Inorg. Chem., 44, 8762 (2005)
  29. Kim, H. N., Lee, H. K. and Lee, S. W., Bull. Korean Chem. Soc., 26, 6 (2005)
  30. Min, D., Cho, Y.-B., Lee, H. K. and Lee, S. W., Inorg. Chim. Acta, 359, 577, (2006)
  31. Cho, Y.-B., Min, D., Lee, H. K. and Lee, S. W., Cryst. Growth Des., 6, 342 (2006)
  32. Kim, S. H., Huh, H. S. and Lee, S. W., J. Mol. Struct., 841, 78 (2007) https://doi.org/10.1016/j.molstruc.2006.11.065
  33. Bruker, SHELXTL, Structure Determination Software Programs, Bruker Analytical X-ray Instruments Inc., Madison, Wisconsin, USA (1997)
  34. Lu, J. Y., Cabrera, B. R., Wang, R.-J. and Li, J., Inorg. Chem., 38, 4608 (1999)
  35. Yaghi, O. M. and Li, G., Angew. Chem. Int. Ed., 34, 207 (1995) https://doi.org/10.1002/anie.199502071