Eu Doping Effect on $CaAl_2O_4:Eu^{2+}$ Phosphor Material

  • Bartwal, Kunwar Singh (Energy Materials Research Center, Korea Research Institute of Chemical Technology) ;
  • Ryu, Ho-Jin (Energy Materials Research Center, Korea Research Institute of Chemical Technology)
  • Published : 2007.06.30

Abstract

High brightness and long persistent luminescence phosphor $CaAl_2O_4:Eu^{2+}$ was prepared with varying $Eu^{2+}$ concentration by solid state reaction technique. Synthesized materials were investigated by powder X-ray diffractometer (XRD), SEM, TEM, photoluminescence excitation and emission spectra. Broad band UV excited luminescence of the $CaAl_2O_4:Eu^{2+}$ was observed in the blue region (${\lambda}_{max}\;=\;440\;nm$) due to transitions from the $4f^65d^1$ to the $4f^7$ configuration of the $Eu^{2+}$ ion. The decay time of the persistence indicated that the persistent luminescence phosphor has bright phosphorescence and maintains a long duration. These materials have great potential for outdoor night time displays.

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