한국식품위생안전성학회지 (Journal of Food Hygiene and Safety)

  • 제22권2호
  • /
  • Pages.88-92
  • /
  • 2007
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  • 1229-1153(pISSN)
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  • 2465-9223(eISSN)
한국식품위생안전성학회 (The Korean Society of Food Hygiene and Safety)
권호 표지

국내 유통 종이팩 포장재 중 Isopropylthioxanthone(ITX) 분석

Analysis of ITX from Commercial Carton Packs in Korean Market

  • 엄미옥 (식품의약품안전청 식품본부) ;
  • 윤혜정 (식품의약품안전청 식품본부) ;
  • 최현철 (식품의약품안전청 식품본부) ;
  • 전대훈 (식품의약품안전청 식품본부) ;
  • 김형일 (식품의약품안전청 식품본부) ;
  • 성준현 (식품의약품안전청 식품본부) ;
  • 박나영 (식품의약품안전청 식품본부) ;
  • 이은준 (식품의약품안전청 식품본부) ;
  • 성덕화 (식품의약품안전청 식품본부) ;
  • 이영자 (식품의약품안전청 식품본부)
  • Eom, Mi-Ok (Center for Food Evaluation, Korea Food and Drug Administration) ;
  • Yoon, Hae-Jung (Center for Food Evaluation, Korea Food and Drug Administration) ;
  • Choi, Hyun-Cheol (Center for Food Evaluation, Korea Food and Drug Administration) ;
  • Jeon, Dae-Hoon (Center for Food Evaluation, Korea Food and Drug Administration) ;
  • Kim, Hyung-Il (Center for Food Evaluation, Korea Food and Drug Administration) ;
  • Sung, Jun-Hyun (Center for Food Evaluation, Korea Food and Drug Administration) ;
  • Park, Na-Young (Center for Food Evaluation, Korea Food and Drug Administration) ;
  • Lee, Eun-Joon (Center for Food Evaluation, Korea Food and Drug Administration) ;
  • Sung, Duk-Hwa (Center for Food Evaluation, Korea Food and Drug Administration) ;
  • Lee, Young-Ja (Center for Food Evaluation, Korea Food and Drug Administration)
  • 발행 : 2007.06.30
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초록

식품용 종이포장재 등에 사용될 수 있는 UV 잉크 인쇄방식에는 광개시제를 이용한 경화방식 또는 전자빔을 이용한 경화방식이 주로 사용된다. 최근 유럽에서 종이팩 포장재의 광개시제로 사용될 수 있는 Isopropylthioxanthone (ITX)에 대한 검출사례가 보고 된 바 있으나, 국내에서는 종이팩 포장재 중 ITX에 대한 모니터링연구가 전무한 상태이므로 제외국 연구동향에 신속히 대응할 수 있는 ITX 분석방법을 확립하고, 확립된 분석방법을 적용하여 국내 유통 종이팩으로 포장된 식품 중 ITX 잔류량에 관한 모니터링을 실시하였다. HPLC/FLD를 이용한 ITX의 분석방법을 확립하였으며, 이때 확립된 분석방법에 대한 상대표준편차 1.09% 이내의 재현성, 상관계수 0.9991 이상의 직선성, 검출한계 0.02 ppb 및 정량한계는 0.1 ppb였다. 또한, 확립된 분석방법을 적용하여 국내 유통 중인 우유, 주스 등 종이팩으로 포장된 제품 87종을 대상으로 ITX 잔류량을 모니터링 한 결과, 모든 식품에서 ITX는 검출되지 않았다.

Isopropylthioxanthone(ITX) is used as a photoinitiator In UV-cured inks, triggering the radical polymerization of the acrylic component of such inks and thus causing the liquid ink film to cure. Recently ITX was detected in carton packed food in Italy. In order to cope with risk issues of overseas and acquire monitoring data on ITX, we have established the method using HPLC/FLD for ITX analysis after reviewing parameters of the analytical methods. Limit of detection (LOD) and limit of quantification (LOQ) were 0.02 ppb and 0.1 ppb, and linearity and RSD (%) were 0.9991 and 1.09, respectively. We have investigated ITX levels migrated to food on 87 commercial products packed in carton and ITX was not detected any food. Therefore it is supposed that UV-cured ink containing ITX as photoinitiator is not currently used in printing of carton pack in Korea.

키워드

참고문헌

  1. http://europa.eu.int/comm/food/food/rapidalert/index_en.htm
  2. http://www.efsa.eu.int/press_room/press_release/ 1258_en.html
  3. http://www.epa.gov/dfe/pubs/flexo/flexosum/index.htm
  4. Treaty of Amsterdam Article 152, Official Journal of the European Union C340 (1997)
  5. Cho, J.D. and Hong, J.W. : UV-initiated free radical and cationic photopolymerizations of acrylate/epoxide and acrylate/ vinyl ether hybrid systems with and without photosensitizer. J. Appl. Polym. Sci. 93, 1473-1483 (2004) https://doi.org/10.1002/app.20597
  6. Dossot, S., Obeid, H., Allonas, X., Jacques, P., Fouassier, J.P. and Merlin, A. : Photopolymerization of acrylates in the presence of phenolic derivatives: role of the photoinitionitiating system. J. Appl. Polym. Sci. 92, 1154-1164 (2004) https://doi.org/10.1002/app.20100
  7. Opinion of the Scientific Panel of Food Additives, Flavorings, Processing Aids and Materials in contact with Food on a request from the commission on related to 2-isopropylthioxanthone (ITX) and 2-ethylhexyl 1-4-dimethylaminobenzoate (EHDAB) in food contact materials. EFSA J. 293, 1-15 (2005)
  8. http://www.umweltjournal.de/fp/archiv/AfA_recycling/ 10537.php
  9. Papilloud, S. and Baudraz, D. : Analysis of food packaging UV inks for chemicals with potential to migrate into food simulants. Food Additives and Contaminants, 19, 168-175 (2002) https://doi.org/10.1080/02652030110084800
  10. Johns, S.M., Jickells, S.M., Read, W.A. and Castle, L. : Studies on Functional Barriers to Migration. 3. Migration of Benzophenone and Model Ink Components from Cartonboard to Food during Frozen Storage and Microwave Heating. Packaging Technology and Science, 13, 99-104 (2000) https://doi.org/10.1002/1099-1522(200005)13:3<99::AID-PTS499>3.0.CO;2-K
  11. Castle, L., Damant, A.P., Honeybone, C.A., Johns, S.M. Jickells, S.M., Sharman, M. and Gilbert, J. : Migration studies from paper and board food packaging materials. Part 2. Survey for residues of dialkylamino benzophenone UV-cure ink photoinitiators. Food Additives and Contaminants, 14, 45-52 (1997) https://doi.org/10.1080/02652039709374496
  12. Morlock, G. and Schwack W. : Determination of isopropylthioxanthone (ITX) in milk, yoghurt and fat by HPTLC-FLD, HPTLC-ESI/MS and HPTLC-DART/MS. Anal. Bioanal. Chem. 385, 586-595 (2006) https://doi.org/10.1007/s00216-006-0430-5
  13. Sagratini, G., Manes, J., Giardina, D., and Pico, Y. : Determination of Isopropyl Thioxanthone (ITX) in fruit juices by pressurized liquid extraction and liquid chromatographymass spectrometry. J. Agric. Food Chem. 54, 7947-7952 (2006) https://doi.org/10.1021/jf0615956
  14. Allen, N. : Photoinitiators for UV and visible curing of coatings; mechanismas and properties. J. Photochemistry and photobiology A : Chemistry 100, 101-107 (1996) https://doi.org/10.1016/S1010-6030(96)04426-7
  15. Krull, I. and Swartz, M. : Determining limits of detection and quantitation. LCGC 16, 464-465 (1998)
  16. Sun, C., Chan, S.H., Lu, D., Lee, H.M.W. and Bloodworth, B.C. : Determination of isopropyl-9H-thioxanthen-9-one in packaged beverages by solid-phase extraction clean-up and liquid chromatography with tandem mass spectrometry detection. J. Chromatography A 1143, 162-167 (2007) https://doi.org/10.1016/j.chroma.2007.01.014