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Synthesis of Barium Titanate Spherical Particles by Sol-Gel Method

졸-겔 법에 의한 구형 미분체 Barium Titanate의 제조

  • Kim, Yong-Ryul (Department of Chemical Engineerign, Daejin University)
  • 김용렬 (대진대학교 공과대학 화학공학과)
  • Published : 2007.09.30

Abstract

$BaTiO_3$ powders were prepared by sol-gel method from different concentration of KOH aqueous solution and Ba/Ti molar ratio. Particle shape, size and crystal structure of prepared $BaTiO_3$ powders were analyzed by SEM, XRD, and FT-IR. As the result of KOH concentration changing, spherical particles were obtained by condition more than 3 M and particle size decreased as concentration increasing. Different appearance showed between dried and sintered powders against changing of Ba/Ti molar ratio. In case of dried powders, the crystallinity decreased as molar ratio increasing. On the other hand, increased as molar ratio increasing in case of sintered powders.

Keywords

References

  1. C. Miot, C. Proust, and E. Husson, Dense ceramics of $BaTiO_3$ produced from powders prepared by a chemical process, J. Euro. Ceramic Soc., 15, 1163 (1995) https://doi.org/10.1016/0955-2219(95)00090-9
  2. M. Oledzka, N. E. Brese, and R. E. Rirnan, Hydrothermal Synthesis of $BaTiO_3$ on a Titanium-Loaded Polymer Support, Chem. Mater., 11, 1931 (1999) https://doi.org/10.1021/cm990169f
  3. S. K. Lee, G. J. Choi, U. Y. Hwang, K. K. Koo, and T. J. Park, Effect of molar ratio of KOH to Ti-isopropoxide on the formation of $BaTiO_3$ powders by hydrothermal method, Materials Letters, 57, 2201 (2003) https://doi.org/10.1016/S0167-577X(02)01174-6
  4. W. K. Kuo, B. Lo, and Y. C. Ling, Steric stabilization of sol-gel prepared $BaTiO_3$ precursors with nonylphenoxypolyethoxyethanol, Material Chemistry and Physics, 60, 132 (1999) https://doi.org/10.1016/S0254-0584(99)00030-9
  5. E. Burcsu, G. Ravichandran, and K. Bhattacharta, Domain Patterns, Texture and Macroscopic Electro-mechanical Properties of Ferroelectrics, IUTAM Sym. on Mechanics of Martensitic Phase Transformation in Solids. (2001)
  6. W. S. Clabaugh, E. M. Swiggard, and R. J. Gilchrist, Preparation of titanyl oxalate tetrahydrate for conversion to barium titanate of high purity, J. Res. Natl. Bur. Stand., 56, 289 (1956) https://doi.org/10.6028/jres.056.037
  7. K. S. Mazdiyansi, R. T. DaHoff, and J. S. Smith II, Preparation of High-Purity Submicron Barium Titanate Powders, J. Amer. Ceram. Soc., 52, 523 (1969) https://doi.org/10.1111/j.1151-2916.1969.tb09157.x
  8. B. J. Mulder, Preparation of Barium Titanate and Other Ceramic Powders by Coprecipitation of Citrates in an Alcohol, J. Ceram. Bull., 49, 990 (1970)
  9. H. P. Beck, W. Eiser, and R. Haberkorn, Pitfalls in the synthesis of nanoscaled perovskite type compounds. Part I: Influence of different sol-gel preparation methods and characterization of nanoscaled $BaTiO_3$, J. Eur. Ceramic Soc., 21, 687 (2001) https://doi.org/10.1016/S0955-2219(00)00270-3
  10. O. A. Harizanov, Formation and crystallization of an acetate-acetylacetonate derived sol-gel $BaTiO_3$, Materials Letters., 34, 345 (1998) https://doi.org/10.1016/S0167-577X(97)00199-7
  11. P. B. Dunbar III, Esterification Kinetics in Titanium Isopropoxide-Acetic Acid Solutions, J. Mat. Sci., 35, 367 (2000) https://doi.org/10.1023/A:1004770007284
  12. Y. R. Kim, and K. S. Yang, Preparation of Nano-sized $BaTiO_3$ Powders by Sol-Gel Process, J. Kor. Oil Chem. Soc., 20(4), 346 (2003)