고분자 나노복합재료의 가공조건 및 물성 최적화

Optimization of Processing Conditions and Mechanical Properties in Polymer Nanocomposite

  • 발행 : 2007.11.01

초록

Nanocomposites are used as a new class of polymer system and many researchers have been interested in the clay nanocomposite because of its good mechanical properties, heat resistance, flame retardancy, and barrier property. Modified layered silicates as fillers are dispersed at a nanometer-level within a polymer matrix and then new extraordinary properties are observed. In this study, polypropylene/clay nanocomposites were prepared in a twin screw extruder by the melt compounding method. In order to increase the compatibility of PP with the clay, the MAPP was used as a compatibilizer. And organic modified clays were used as a nanometric filler during the melt extrusion. Through the analysis of SAXS, WAXS, the dispersion of clay was investigated. These nanocomposites compared with a neat polypropylene/talc composite have high modulus, low toughness, and reduced shrinkage at the stable dispersion.

키워드

참고문헌

  1. S. D. Burnside and E. P. Giannelis, 'Nanostructure and Properties of Polysiloxane-layerd Silicate Nanocomposites,' J. Polym. Sci., Polym. Phys., Vol.38, No.12, pp.1595-1599, 2000 https://doi.org/10.1002/(SICI)1099-0488(20000615)38:12<1595::AID-POLB40>3.0.CO;2-U
  2. M. B. Go and J. K. Kim, 'Preparation Technology of Organic-Inorganic Nanocomposite by Clay Dispersion,' Polymer Science and Technology, Vol.10, No.4, pp.451-459, 1999
  3. T. J. Pinnavaia and G. W. Beall, Polymer-clay Nanocomposite, John Wiley & Sons Ltd., New York, p.111, 2000
  4. J. M. Garcs, D. J. Moll, J. B.icerano, R. Fibiger, and D. G. Mcleod, 'Polymeric Nanocomposites for Automotive Applications,' Adv. Mater., Vol.12, No.23, pp.1835-1840, 2000 https://doi.org/10.1002/1521-4095(200012)12:23<1835::AID-ADMA1835>3.0.CO;2-T
  5. C. K. Narula, J. E. Allision, D. R. Bauer and H. S. Gandhi, 'Materials Chemistry Issues Related to Advanced Materials Applications in the Automotive Industry,' Chem. Mater., Vol.8, pp.984-988, 1996 https://doi.org/10.1021/cm950588m
  6. E. P. Giannelis, 'Polymer Layered Silicate Nanocomposites,' Adv. Mater., Vol.8, No.1, pp.29-37, 1996 https://doi.org/10.1002/adma.19960080104
  7. M. Kawasumi, N. Hasegawa, M. Kata, A. Usuki, and A. Okada, 'Preparation and Mechanical Properties of Polypropylene-clay Hybrids,' Macromolecules, Vol.30, pp.6333-8340, 1997 https://doi.org/10.1021/ma961786h
  8. M. Kato, A. Usuki, and A. Okada, 'Synthesis of Polypropylene Oligomer-clay Intercalation Compounds,' J. Appl. Polym. Sci., Vol.66, No.9, pp.1781-1789, 1997 https://doi.org/10.1002/(SICI)1097-4628(19971128)66:9<1781::AID-APP17>3.0.CO;2-Y
  9. M. Kawasumi, N. Hasegawa, M. Kata, A. Usuki, and A. Okada, 'Preparation and Mechanical Properties of Polypropylene-clay Hybrids Using a Maleic Anhydride-modified Polypropylene Oligomer,' J. Appl. Polym. Sci., Vol.67, No.7, pp.87-91, 1998 https://doi.org/10.1002/(SICI)1097-4628(19980103)67:1<87::AID-APP10>3.0.CO;2-2
  10. A. Usuki, M. Kato, A. Okada and T. Kurauchi, 'Synthesis of Polypropylene-clay Hybrid,' J. Appl. Polym. Sci., Vol.63, No.4, pp.137-141, 1997 https://doi.org/10.1002/(SICI)1097-4628(19970103)63:1<137::AID-APP15>3.0.CO;2-2
  11. L. E. Nielsen and R. F. Landel, Mechanical Properties of Polymers and Composites, Marcel Dekker, Germany, pp.358-361, 1994
  12. M. J. Solomon, A. S. Almusallam, K. F. Seefelddt, A. Somwangthanaroj and P. Varadan, 'Rheology of Polypropylene/Clay Hybrid Materials,' Macromolecules, Vol.34, No.6, pp.1864- 1870, 2001 https://doi.org/10.1021/ma001122e
  13. M. Lyu, 'A Study on the Performance Improvement in the Intake System of a Largesized Commercial Bus,' Transactions of KSAE, Vol.13, No.2, pp.16-21, 2005