International Journal of Human Ecology

대한가정학회 (The Korean Home Economics Association)
권호 표지

Retardation of Degradation in Accelerated Aging of Cotton Cellulose Using Borohydride Reduction

  • Kim, Hye-Kyung (Dept. of Organic Materials and Fiber Engineering, Soongsil University) ;
  • Choi, Hyung-Min (Dept. of Clothing, Wonkwang University)
  • 발행 : 2007.06.30
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Degradation of cellulose during prolonged exposure in atmospheric conditions has been recognized as one of main problems in preserving cellulose-made products. The purpose of this research was therefore to study effects of borohydride reduction in improving both the color and strength retention of cotton fabrics artificially aged at temperatures ranging from $100^{\circ}C$ to $150^{\circ}C$. Results indicated that the fabrics treated with either sodium or tetramethylammonium borohydrides (TMA) were degraded at rates about one-half that of water-washed cotton. These results were consistent over the temperature range. Calculation of the activation energy (Ea) by different methods showed $Ea\;=\;25.5{\pm}\;1.5\;Kcal$, in keeping with measurements made by others at lower temperatures. The TMA-treatment was effective in minimizing discoloration of the fabrics with pre-baking, but not of the un-prebaked fabrics.

키워드

참고문헌

  1. Block, I. (1982). The effect of an alkaline rinse on the aging of cellulosic textiles. Journal of the American Institute for Conservation, 22, 25-36 https://doi.org/10.2307/3179716
  2. Block, I. (1984). Temperature and humidity effects in the accelerated aging of cellulosic textiles. Preprint of the 7th Triennial Meeting of the ICOM Committee for Conservation (pp.10-14). Copenhagen
  3. Cao, Y. -Q., Dai, Z., Chen, B. H., & Liu, R. (2005). Sodium borohydride reduction of ketones, aldehydes and imines using PET 400 as catalyst without solvent. Journal of Chemical Technology Biot, 80(7), 834-836 https://doi.org/10.1002/jctb.1297
  4. Castellan, A., Nourmamode, A., Fornier de Violet, Ph., Colobo, N., & Jaeger, C. (1992). Photoyellowing of milled wood lignin and peroxide-bleached milled wood lignin in solid 2-hydroxypropylcellulose films after sodium borohydride reduction and catalytic hydrogenation in solution. Journal of Wood Chemistry and Technology, 12(1), 1-18 https://doi.org/10.1080/02773819208545047
  5. Graminski, E. L., Parks, E. J., & Toth, E. E. (1979). The effect of temperature and moisture on the accelerated aging of paper, R. K Eby (Eds.), Durability of Macromolecular Materials, American Chemical Society Symposium Series No. 95 (pp.24-32). Washington, D.C.: ACS
  6. Hackney, S. & Hedley, G. (1984). Linen canvas artificially aged. Preprint of the 7th Triennial Meeting of the ICOM Committee for Conservation (pp.16-21). Copenhagen
  7. Head, F. S. H. (1955). The reduction of the aldehyde groups in periodate oxycelluloses by sodium borohydride. Journal of the Textile Institute Transaction, 46, T400-T406
  8. Jellinek, H. H. G. (1978). Aspects of Degradation and Stabilization of Polymers. Amsterdam: Elsevier Scientific Publishing Company
  9. Kerr, N., Hersh, S. P, Tucker, P. A., & Berry, G. M. (1979). Reinforcing degradation textiles: effect of deacidification on fabric deterioration. R. K Eby (Eds.), Durability of Macromolecular Materials, ACS Symposium Series No. 95 (pp.357-369). Washington, D.C.: ACS
  10. Kolar J. (1998). Aging and stabilization of alkaline paper. Journal of Pulp and Paper Science, 24(3), 89-94
  11. Kongruang, S., Hao, M. J., Breton, C. I. G.,.& Penner, M. H. (2004). Quantitative analyses of cellulose-reducing ends. Applied Biochemistry and Biotechnology-Part A Enzyme Engineering and Biotechnology, 113-116
  12. Kongruang, S., Hao, M. J., Breton, C. I. G.,.& Penner, M. H. (2004). Quantitative analyses of cellulose-reducing ends. Applied Biochemistry and Biotechnology-Part A Enzyme Engineering and Biotechnology, 213-231
  13. Kongruang, S. & Penner, M. H. (2004). Borohydride reactivity of cellulose reducing ends. Carbohydrate Polymers, 58(2), 131-138 https://doi.org/10.1016/j.carbpol.2004.06.012
  14. Richards, H. R. (1984). Thermal degradation of fabrics and yarns. Journal of the Textile Institute, 75, 28-36 https://doi.org/10.1080/00405008408658458
  15. Tang, L. (1981). Washing and deacidification of paper in the same operation. J. C. Williams (Eds.), Preservation of Paper and Textiles of Historic and Artistic Value II, American Chemical Society No. 193 (pp.6386). Washington, D. C.: ACS
  16. Zeynizadeh, B. & Behyar, T. (2005). Wet THF as a suitable solvent for a mild and convenient reduction of carbonyl compounds with $NaBH_4$. Bulletin of the Chemical Society of Japan, 78(2), 307-315. https://doi.org/10.1246/bcsj.78.307