A study on the change of air lead concentrations in lead-acid battery plants

축전지 사업장에서 공기 중 납 농도의 변화에 관한 연구

  • Choi, Seung-Hyun (Institute of Environmental and Occupational Medicine, Soonchunhyang University) ;
  • Kim, Nam-Soo (Institute of Environmental and Occupational Medicine, Soonchunhyang University) ;
  • Kim, Jin-Ho (Institute of Environmental and Occupational Medicine, Soonchunhyang University) ;
  • Cho, Kwang-Sung (Institute of Environmental and Occupational Medicine, Soonchunhyang University) ;
  • Ham, Jung-O (Department of Occupational Medicine, Soonchunhyang University Hospital, Cheonan) ;
  • Ahn, Kyu-Dong (Institute of Environmental and Occupational Medicine, Soonchunhyang University) ;
  • Lee, Byung-Kook (Institute of Environmental and Occupational Medicine, Soonchunhyang University)
  • 최승현 (순천향대학교 환경산업의학연구소) ;
  • 김남수 (순천향대학교 환경산업의학연구소) ;
  • 김진호 (순천향대학교 환경산업의학연구소) ;
  • 조광성 (순천향대학교 환경산업의학연구소) ;
  • 함정오 (순천향대학교천안병원 산업의학과) ;
  • 안규동 (순천향대학교 환경산업의학연구소) ;
  • 이병국 (순천향대학교 환경산업의학연구소)
  • Received : 2007.09.12
  • Accepted : 2007.11.05
  • Published : 2007.12.31

Abstract

To provide necessary information for future environmental monitoring of storage batteries in Korea, authors analyzed environmental monitoring dataset of air lead concentration of 12 storage battery industries measured during 1989-2006. We calculated geometric mean and standard deviation with minimum and maximum value of each year dataset. Air lead concentration data were analyzed according to year of measurement, type of grid manufacturing method (grid casting type or expander type), size of industries and type of operation (casting, lead powder & pasting, assembly and others). The geometric mean and standard deviation of all lead industries for overall 18 years were $72{\mu}g/m^3$ and 3.65 with minimum of $6{\mu}g/m^3$ and maximum of $7,956{\mu}g/m^3$. The geometric mean air lead concentrations of years between 1989-1999 were above the Korean PEL($50{\mu}g/m^3$), whereas those of years after year 2000 were below the Korean PEL showing 50% of it. The geometric mean concentration of air lead was significantly lower in expander method battery industries than that of grid method battery industries and was lower in large sized battery industries than small & medium sized ones throughout the whole 18 years period. The distributions of over PEL($50{\mu}g/m^3$) were decreased by the years of environmental monitoring and those were lower in expander method battery industries than grid method battery industries. The significant reduction of mean air lead concentration during last 10 years may be induced partly due to more active environmental engineering control and new introduction of new operation in grid method battery industries, but may be also influenced by non-engineering method such as reduction of operation hours or reduction of exposure time during actual environmental measurement by industrial hygienist which is not concrete evidence, but just circumstantial evidence.

Keywords

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