COD Fraction in Semi-Continuous Food Waste Acid Fermenter

반연속식 음식물쓰레기 산발효조에서 COD 분율

  • Lee, Jae Woo (Department of Environmental Engineering, Korea University) ;
  • Park, Ki Young (Department of Civil and Environmental System Engineering, Konkuk University) ;
  • Kim, Hee Jun (Department of Civil, Urban and Geosystem Engineering, Seoul National University) ;
  • Chung, Tai Hak (Department of Civil, Urban and Geosystem Engineering, Seoul National University)
  • 이재우 (고려대학교 환경시스템공학과) ;
  • 박기영 (건국대학교 사회환경시스템공학과) ;
  • 김희준 (서울대학교 건설환경공학부) ;
  • 정태학 (서울대학교 건설환경공학부)
  • Received : 2007.11.01
  • Accepted : 2007.11.13
  • Published : 2007.11.30

Abstract

In this study, degradation of carbohydrates and composition of fermentative products were investigated in semi-continuous acid fermenter varying hydraulic retention time (HRT). Rice soup was used as a sole substrate for the acid fermentation. Solubilization efficiency of the substrate was higher than 70% for all HRT, however the gas conversion was ignorable implying that most of organic contents in the influent remained in the form of volatile fatty acids (VFAs) and ethanol after acid fermentation. The VFAs were the predominant product and the VFAs conversion increased as the HRT decreased. The VFAs conversion reached the maximum value at 12 hr HRT accounting for 70% of the influent COD. Similar to VFAs, ethanol conversion was increased with the decrease of HRT and the maximum ethanol conversion efficiency was 8% at the HRT of 12 hr. Composition of VFAs was markedly dependent on HRT. As HRT increased, the composition of acetic acid was increased as a product of acetogenesis from butyrate, valerate and ethanol. This study demonstrated that HRT affected acid fermentation of a carbohydrate containing organic wastes producing VFAs and ethanol which could be effectively used to compensate the lack of carbon in wastewater for biological nutrient removal.

Keywords

References

  1. 김희준, 김성흥, 최영균, 효소전처리가 음식물쓰레기의 산발효에 미치는 영향, 한국보건환경학회지, 31(4), pp. 294-300 (2005)
  2. 신항식, 채소룡, 남세용, 강석태, 백병천, 하수처리에서 음식물 산발효액이 영양염류제 거에 미치는 영향, 대한환경공학회지, 24, pp. 1023-1031 (2002)
  3. 환경부, 2005 전국폐기물 발생 및 처리현황 (2006)
  4. APHA, AWWA and WEF, Standard Methods f or the examination of water and wastewater, 19th edn., Washington D. C. (1996)
  5. Argelier, S., Delgenes, J.-Ph. and Moletta, R., Design of acidogenic reactors for the anaerobic treatment of the organic fraction of solid food waste, Bioprocess Engineering, 18, pp. 309-315 (1998) https://doi.org/10.1007/s004490050448
  6. Danesh, S. and Oleszkiewicz, J. A., Volatile fatty acid production and uptake in biological nutrient removal systems with process separation, Water Environ. Res., 69(6), pp. 1106-1111 (1997) https://doi.org/10.2175/106143097X125830
  7. Dinopoulou, G., Rudd, T. and Lester, J. N., Anaerobic Acidogenesis of a Complex Wastewater: 1, The Influence of Operational Parameters on Reactor Performance, Biotechnol. Bioeng., 31, pp. 958-968 (1988) https://doi.org/10.1002/bit.260310908
  8. Elefsiniotis, P. and Oldham, W. K., Effect of HRT on acidogenic digestion of primary sludge, J. Environmental Engineering, 120(3), pp. 645-660 (1994) https://doi.org/10.1061/(ASCE)0733-9372(1994)120:3(645)
  9. Han, S. K., Kim, S. H. and Shin, H. S., UASB treatment of wastewater with VFA and alcohol generated during hydrogen fermentation of food waste, Process Biochemistry, 40, pp. 2897-2905 (2005) https://doi.org/10.1016/j.procbio.2005.01.005
  10. Hanaki, K., Matsuo, T., Nagase, M. and Tabata, Y., Evaluation of effectiveness of two-phase anaerobic digestion process degrading complex substrate, Water Sci. Technol., 19, pp. 311-322 (1987) https://doi.org/10.2166/wst.1987.0211
  11. Henze, M., Capability of biological nitrogen removal processes from wastewater, Water Sci. Technol, 23, pp. 669-679 (1991) https://doi.org/10.2166/wst.1991.0517
  12. Lee, J. W., Yoo, U. J. and Chung, T. H., Evaluation of organic wastes as a carbon source for improvement of BNR efficiency, Proceeding 99 Asian WaterQual, Taipei, Taiwan, pp. 487-492 (1999)
  13. Lim, S. J., Choi, D. W., Lee, W. G., Kwon, S. and Chang, H. N., Volatile fatty acids production from food wastes and its application to biological nutrient removal, Bioprocess and Biosystem Engineering, 22, pp. 543-545 (2000) https://doi.org/10.1007/s004499900109
  14. Maharaj, I. and Elefsiniotis, P., The role of HRT and low temperature on the acid-phase anaerobic digestion of municipal and industrial wastewater, Bioresource Technology, 76, pp. 191-197 (2001) https://doi.org/10.1016/S0960-8524(00)00128-0