한국환경과학회지 (Journal of Environmental Science International)

  • 제16권12호
  • /
  • Pages.1463-1468
  • /
  • 2007
  • /
  • 1225-4517(pISSN)
  • /
  • 2287-3503(eISSN)
한국환경과학회 (The Korean Environmental Sciences Society)
권호 표지
DOI QR코드

DOI QR Code

토양 훈증제 1,3-Dichloropene의 물 및 토양 중 분해

Transformation for 1,3-Dichloropene of Soil Fumigant in Water and Soil

  • 김정호 (대구한의대학교 소방방재환경학과)
  • Kim, Jung-Ho (Department of safety & Environmental Prevention, Daegu Haanny University)
  • 발행 : 2007.12.31
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Emission of methyl bromide(MeBr) of soil fumigant was implicated in stratospheric ozone depletion. To determine the environmental fate for 1,3-dichloropene(1,3-D) of alternatives fumigants for MeBr, this paper researched the transformation for 1,3-D in water and soil. Half lives of cis-1,3-D in water with first-order kinetics are 9.9day and 1.7day at $25^{\circ}C\;and\;40^{\circ}C$, half lives of trans-1,3-D are 8.6day and 1.5day at $25^{\circ}C\;and\;40^{\circ}C$, respectively. Transformation for 1,3-D in water at high temperature faster then at low temperature. Hydrolysis for 1,3-D in water are unaffected at $pH\;2.5{\sim}pH\;10.0$, but hydrolysis for 1,3-D at pH 11.5 higher then at $pH\;2.5{\sim}pH\;10.0$. Half lives of cis-1,3-D in soil are 11.5day and 7.7day at 3% and 10% of soil moisture, half lives of trans-1,3-D are 9.9day and 6.9day at 3% and 10% of soil moisture, respectively. Transformation for 1,3-D in water increased with increasing soil moisture. Transformation for trans-1,3-D isomer are more rapid then cis-1,3-D isomer in water and soil. This research has identified that transformation for 1,3-dichloropropene are affected by temperature, pH, soil moisture, and isomer of cis and trans in water and soil.

키워드

참고문헌

  1. Anonymous, 2000, Protection of stratospheric ozone: Incorporation of Clean Air Act amendments for restrictions in Class I, Group VI controlled substances, Federal Register, 65, 70795-70804
  2. Arvieu J.C., 1983, Some physico-chemical aspects of methyl bromide behaviour in soil, Acta Hortic., 152, 267-274
  3. Gao S., Trout T. J., 2007, Surface seals reduce 1,3-dichloropropene and chloropicrin emissions in field tests, J. Environ. Qual., 36, 110-119 https://doi.org/10.2134/jeq2006.0107
  4. Ou L.-T., Thomas J. E., Allen Jr. L. H., Vu J.C., 2007, Emission and distribution of methyl bromide in field beds applied at two rates and covered with two types of plastic mulches, J. Environ. Sci. Health Part B, 42, 15-20 https://doi.org/10.1080/03601230601017676
  5. Park M.-K., Kim J. H., Dungan R. S., 2004, Sorption of fumigant 1,3-dichloropropene on soil, J. Environ. Sci. Health Part B, 39, 603*612 https://doi.org/10.1081/PFC-200026821
  6. Aspelin A. L., Grube A. H., 1999, Pesticide Industry Sales and Usage: 1996 and 1997 Market Estimates, The U.S. Environmental Protection Agency, Washington, DC, Publication No. 733-R-99-001
  7. 농약공업협회, 2007, 농약사용지침서
  8. Ma Q. L., Gan J., Papiernik S. K., Becker J. O., Yates S.R., 2001, Degradation of soil fumigants as affected by initial concentration and temperature, J. Environ. Qual. 30, 1278-1286 https://doi.org/10.2134/jeq2001.3041278x
  9. Kim J.-H., Gan J., Farmer W. J., Yates S. R., Papiernik S. K., Dungan R. S., 2003, Organic matter effect on phase partition of 1,3-dichloropropene in soil, J. Agric. Food Chem., 51, 165-169 https://doi.org/10.1021/jf025798f
  10. 박병준, 최주현, 이병무, 임건재, 김찬섭, 박경훈, 1998, 몇가지 수중 환경요인에 의한 iprobenfos, isoprothiolane 및 diazinon의 분해속도, 한국농약과학회지, 2(2), 39-44
  11. Ou L.-T., 1998, Enhanced degradation of the volatile fumigant nematicides 1,3-D and methyl bromide in soil, J. Nemato., 30, 56-64
  12. Kim J.-H., Papiernik S. K., Farmer W. J., Gan J., Yates S.R., 2003, Effect of formulation on the behavior of 1,3-dichloropropene in soil, J. Environ. Qual., 32(6), 2223-2229 https://doi.org/10.2134/jeq2003.2223
  13. 김정호, 2006, 물과 토양에서 훈중제의 동시분석법 확립, 한국환경독성학회지, 21(4), 365-373
  14. McCall P. J., 1987, Hydrolysis of 1,3-dichloropropene in dilute aqueous solution, Pestic. Sci., 19, 235-242 https://doi.org/10.1002/ps.2780190309
  15. Tomlin C., 1997, The Pesticide Manual, 11th Ed. British Crop Prote
  16. Roberts T. R., Stoydin G., 1976, The degradation of (Z)- and (E)-dichloropropenes and 1,2-dichloropropane in soil, Pestic. Sci., 7, 325-335 https://doi.org/10.1002/ps.2780070402
  17. Schwarzenbach R. P., Gschwend P. M., Imboden D. M., 1993, Nonreductive chemical reactions involving nucleophilic species, p. 359-368, In R.P. Schwarzenbach et al. (ed.) Environmental organic chemistry, John Wiley & Sons, New York
  18. Ibekewe A. M., Papiernik S. K., Gan J., Yates S. R., Crowley D. E., Yang C.-H., 2001, Microcosm enrichment of 1,3-dichloropropene - degrading soil microbial communities in a compost-amended soil, J. App. Microbiology, 91, 668-676 https://doi.org/10.1046/j.1365-2672.2001.01431.x
  19. Dungan R. S., Gan J., Yates S. R., 2001, Effect of temperature, organic amendment rate and moisture content on the degradation of 1,3-dichloropropene in soil, Pest Manag. Sci., 57, 1107-1113 https://doi.org/10.1002/ps.400
  20. Gan J., Yates S. R., Anderson M. A., Spencer W. F., Ernst F. F., Yates M. V., 1994, Effect of soil properties on degradation and sorption of methyl bromide in soil, Chemosphere, 29(12), 2685-2700 https://doi.org/10.1016/0045-6535(94)90067-1