한국화재소방학회논문지 (Fire Science and Engineering)

  • 제21권4호
  • /
  • Pages.32-37
  • /
  • 2007
  • /
  • 2765-060X(pISSN)
  • /
  • 2765-088X(eISSN)
한국화재소방학회 (Korean Institute of Fire Science and Engineering)
권호 표지

클리브랜드 개방식 장치를 이용한 2-propanol+acid류 계의 하부 인화점 측정 및 예측

The Measurement and Estimation of Lower Flash Point for 2-Propanol+Acid Systems Using Cleveland Open Cup Apparatus

  • 하동명 (세명대학교 보건안전공학과) ;
  • 이성진 (세명대학교 임상병리학과)
  • 발행 : 2007.12.27
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

인화점의 정보를 확보하는 것은 화재 및 폭발의 예방을 위해 대단히 중요하다. 본 연구에서는 2-propanol+acetic acid 계와 2-propanol+n-propionic acid 계의 하부 인화점을 클리브랜드 개방식 장치를 이용하여 측정하였다. 실험값은 Raoult의 법칙, Wilson 식과 NRTL 식에 의해 계산된 값과 비교하였다. 그 결과, Wilson 식과 NRTL 식에 의한 예측값이 Raoult의 법칙에 의한 예측값 보다 실험값에 더욱 근접하였다. 또한, NRTL 식의 실험값에 대한 모사성이 Wilson 식의 그것 보다 우수하였다.

An accurate knowledge of the flash point is important in developing appropriate preventive and control measures in industrial fire protection. The lower flash points for the 2-propanol+acetic acid and 2-propanol+-n-propionic acid systems were measured by Cleveland open cup apparatus. The experimental data were compared with the values calculated by the Raoult's law, the Wilson equation and the NRTL(non random two liquids) equation. The calculated values based on the Wilson and NRTL equations were found to be better than those based on the Raoult's law. And the predictive curve of the flash point prediction model, based on NRTL equation described the experimentally-derived data were more effective than the case of the Wilson equation.

키워드

참고문헌

  1. R.C. Lance, A.J. Barnard, and J.E. Hooymanm, 'Measurement of Flash Points : Apparatus, Methodology, Applications', J. of Hazardous Materials, Vol.3, pp.107-119(1979) https://doi.org/10.1016/0304-3894(79)85008-6
  2. American Society for Testing Materials, Annual Book of ASTM Standards(1999)
  3. D.M. Ha, Y.C. Choi, and S.J. Lee, 'The Lower Flash Point of the n-Butanol+n-Decane System', J. of Korean Institute of Fire & Eng., Vol.17, No.2, pp.50-55(2003)
  4. D.M. Ha, Y.C. Choi, J.G. Han, S.J. Lee, and S.K. Lee, 'Measurement and Estimation of the Lower Flash Points of Binary Systems Containing Nonflammable Component by Closed Cup Tester', Proceedings of the Sixth Asia-Oceania Symposium of Fire Science and Technology, pp.394-399, Daegu, Korea(2004)
  5. H.J. Liaw, C.L. Tang, and J.S. Lai, 'A Model for Predicting the Flash Point of Ternary Flammable solution of Liquid', Combustion and Flame, Vol.138, pp.308-319(2004) https://doi.org/10.1016/j.combustflame.2004.06.002
  6. L. Catoire, S. Paulmier, and V. Nauder, 'Experimental Determination and Estimation of Closed Cup Flash Points of Mixtures of Flammable Solvent', Process Safety Progress, Vol.25, No.1, pp.33-39 (2006) https://doi.org/10.1002/prs.10112
  7. J.G. Walsham, 'Prediction of Flash Points for Solvent Mixtures', Advan. Chem. Ser. Publ. 73 Ser. 124, American Chemical Society, Washington, DC, pp.56-59(1973)
  8. W.H. Ellis, 'Solvent Flash Points -Expected and Unexpected-', J. of Coating Technology, Vol.48, pp.44-57(1976)
  9. D.M. Ha, 'Measurement and Prediction of the Lower Flash Point for n-Propanol+n-Decane System Using the Tag Open-Cup Tester', J. of the Korean Society of Safety Vol.20, No.2, pp.162-168(2005)
  10. D.M. Ha, S.J. Lee, and Y.H. Song, 'Measurement and Prediction of the Flash Point for the Flammable Binary Mixtures using Tag Open-Cup Apparatus', Korean Chem. Eng. Res., Vol.43, No.1, pp.181-185 (2005)
  11. D.M. Ha and S.J. Lee, 'The Measurement and Prediction of the Flash Points for the Water+2- Propanol System Open-Cup Apparatus', J. of Korean Institute of Fire & Eng., Vol.21, No.2, pp. 48-53(2007)
  12. H. Le Chatelier, 'Esimation of Firedamp by Flammability limits', Ann. Minmes, Vol.19, p.388 (1891)
  13. C.R. Reid, J.M. Prausnitz, and P.E. Poling, 'The Properties of Gases and Liquids', 4th Edition., p.102, McGraw-Hill, New York(1998)
  14. J. Gmehing, U. Onken, and W. Arlt, 'Vapor-Liquid Equilibrium Data Collection', Vol.1, Part1-Part7, DECHEMA(1980)
  15. D.M. Ha and S.J. Lee, 'The Measurement and Estimation of Lower Flash Points for the n- Propanol+Acetic Acid and n-Propanol+n-Propionic acid Systems', J. of the Korean Society of Safety, Vol.22, No.4, pp.37-42(2007)